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Trifluoromethanesulfonic acid difluoromethyl ester

Trifluoromethanesulfonic acid difluoromethyl ester structure

CAS No.: 1885-46-7

Chemical Name:: Trifluoromethanesulfonic acid difluoromethyl ester

Synonyms: Difluoromethyl triflate;Difluoromethyl triflate 95%;Difluoromethyl trifluoromethanesulfonate;Difluoromethyl trifluoromethanesulfonate 95%;Trifluoromethanesulfonic acid difluoromethyl ester;Methanesulfonic acid, 1,1,1-trifluoro-, difluoromethyl ester

CBNumber:: CB82755645

Molecular Formula:: C2HF5O3S

Molecular Weight:: 200.08

MDL Number:: MFCD28054469

MOL File:: 1885-46-7.mol

MSDS File:: SDS

Last updated:2024-04-15 18:41:30

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Trifluoromethanesulfonic acid difluoromethyl ester Properties

Boiling point	48.5-49 °C
Density	1.584 g/mL at 25 °C
Flash point	57℃
storage temp.	2-8°C
form	liquid
color	Clear, colourless

SAFETY

Risk and Safety Statements

Symbol(GHS)	GHS02,GHS05,GHS07
Signal word	Danger
Hazard statements	H226-H302-H314
Precautionary statements	P210-P233-P280-P301+P312-P303+P361+P353-P305+P351+P338
Hazard Codes	C,Xn
Risk Statements	22-34
Safety Statements	26-36/37/39-45
RIDADR	UN 2920 3(8) / PGII
WGK Germany	3
HS Code	2905190098

Trifluoromethanesulfonic acid difluoromethyl ester price More Price(14)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	792764	Difluoromethyl triflate 95%	1885-46-7	1ml	$90.6	2024-03-01	Buy
Sigma-Aldrich	792764	Difluoromethyl triflate 95%	1885-46-7	5ml	$642	2024-03-01	Buy
TRC	D610240	Difluoromethyltrifluoromethanesulfonate	1885-46-7	1g	$220	2021-12-16	Buy
SynQuest Laboratories	6164-3-45	Difluoromethyl trifluoromethanesulfonate	1885-46-7	5G	$225	2021-12-16	Buy
American Custom Chemicals Corporation	HCH0417324	DIFLUOROMETHYL TRIFLUOROMETHANESULFONATE 95.00%	1885-46-7	5MG	$501.07	2021-12-16	Buy

Product number	Packaging	Price	Buy
792764	1ml	$90.6	Buy
792764	5ml	$642	Buy
D610240	1g	$220	Buy
6164-3-45	5G	$225	Buy
HCH0417324	5MG	$501.07	Buy

Trifluoromethanesulfonic acid difluoromethyl ester Chemical Properties,Uses,Production

Uses

Difluoromethyl triflate (TfO-CHF₂) can be used as a reagent:

In difluoromethylation reaction.
To prepare difluoromethoxylated heterocycles by reacting with hydroxylated N-based heterocycles.
To synthesize trifluoromethylated arenes by treating with diaryliodonium salts in the presence of copper and tetrabutylammonium difluorotriphenylsilicate (TBAT).

It allows for a simple method toward the preparation of difluoromethyl ethers and thioethers under basic conditions from alcohols and thiols. Difluoromethyl phenols can also be obtained in a single pot from boronic acids and C-H activation of arenes.

General Description

Difluoromethyl triflate (HCF₂OTf) is an easy to handle, air-stable and non-ozone-depleting liquid reagent for difluoromethylation. It can be prepared by reacting trifluoromethyltrimethylsilane (TMSCF₃) and triflic acid in the presence of titanium tetrachloride (TiCl₄).

Trifluoromethanesulfonic acid difluoromethyl ester synthesis

Synthesis of Trifluoromethanesulfonic acid difluoromethyl ester from Trifluoromethanesulfonic acid and (Trifluoromethyl)trimethylsilane

Trifluoromethanesulfonic acid difluoromethyl ester Preparation Products And Raw materials

Raw materials

3,3-Difluoro-3H-diazirine (Trifluoromethyl)trimethylsilane Trifluoromethanesulfonic acid (Difluoromethyl)trimethylsilane

Preparation Products

1,4-Bis(trifluoromethyl)-benzene 4-(TRIFLUOROMETHYL)DIPHENYL ETHER Dibenzothiophene Trifluoromethane Trimethylfluorosilane

3-(Difluoromethoxy)pyridine

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Trifluoromethanesulfonic acid difluoromethyl ester Suppliers

Global( 47)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Zibo Hangyu Biotechnology Development Co., Ltd	+86-0533-2185556 +8617865335152	Mandy@hangyubiotech.com	China	11013	58
Shenzhen Nexconn Pharmatechs Ltd	+86-755-89396905 +86-15013857715	admin@nexconn.com	China	10248	58
Zhengzhou Alfa Chemical Co.,Ltd	+8618530059196	sale04@alfachem.cn	China	12468	58
Shanghai Gubang New Materail Technology Co. LTD	21-51317962 +8618721305404	16728589@qq.com	CHINA	272	58
Labnetwork lnc.	+86-27-50766799 +8618062016861	contact@labnetwork.com	China	19994	58
Hangzhou MolCore BioPharmatech Co.,Ltd.	+86-057181025280; +8617767106207	sales@molcore.com	China	49739	58
LEAPCHEM CO., LTD.	+86-852-30606658	market18@leapchem.com	China	43348	58
Aladdin Scientific	+1-833-552-7181	sales@aladdinsci.com	United States	57511	58
Henan Aochuang Chemical Co.,Ltd.	+86-0371-63689365 +8618638391208	sales@aochuangchem.com	China	9425	58
SHANG FLUORO	021-021-65170832 15601903708	qinba_1@163.com	China	306	60

Supplier	Advantage
Zibo Hangyu Biotechnology Development Co., Ltd	58
Shenzhen Nexconn Pharmatechs Ltd	58
Zhengzhou Alfa Chemical Co.,Ltd	58
Shanghai Gubang New Materail Technology Co. LTD	58
Labnetwork lnc.	58
Hangzhou MolCore BioPharmatech Co.,Ltd.	58
LEAPCHEM CO., LTD.	58
Aladdin Scientific	58
Henan Aochuang Chemical Co.,Ltd.	58
SHANG FLUORO	60

View Lastest Price from Trifluoromethanesulfonic acid difluoromethyl ester manufacturers

Image	Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
	2024-04-15	Trifluoromethanesulfonic acid difluoromethyl ester 1885-46-7	US $0.10-0.10 / kg	0.005kg	99.99%	20 tons	Zibo Hangyu Biotechnology Development Co., Ltd
	2022-10-10	Trifluoromethanesulfonic acid difluoromethyl ester 1885-46-7	US $0.00-0.00 / kg	1kg	98%	1Ton	Henan Aochuang Chemical Co.,Ltd.

Trifluoromethanesulfonic acid difluoromethyl ester
1885-46-7
US $0.10-0.10 / kg
99.99%
Zibo Hangyu Biotechnology Development Co., Ltd

Trifluoromethanesulfonic acid difluoromethyl ester
1885-46-7
US $0.00-0.00 / kg
98%
Henan Aochuang Chemical Co.,Ltd.

1885-46-7(Trifluoromethanesulfonic acid difluoromethyl ester)Related Search:

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TRIFLUOROACETALDEHYDE HYDRATE

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Trifluoromethanesulfonic acid difluoromethyl ester Difluoromethyl triflate 95% Difluoromethyl triflate Difluoromethyl trifluoromethanesulfonate Difluoromethyl trifluoromethanesulfonate 95% Methanesulfonic acid, 1,1,1-trifluoro-, difluoromethyl ester 1885-46-7 C2HF5O3S