ChemicalBook >> CAS DataBase List >>5-(2-Chloro-4-(trifluoro-methyl)phenoxy)-2-nitro-benzoic acid sodium salt

5-(2-Chloro-4-(trifluoro-methyl)phenoxy)-2-nitro-benzoic acid sodium salt

CAS No.
62476-59-9
Chemical Name:
5-(2-Chloro-4-(trifluoro-methyl)phenoxy)-2-nitro-benzoic acid sodium salt
Synonyms
Blazer;tackle 2as;LS 80.1213;Scifluorfen;Aciuorfen sodiuM;Sodium acifluorfen;ACIFLUORFEN SODIUM;ACIFLUORFENSODIUMSALT;Acifluorfen Sodium (Patented-No-Supply);SODIUM5-(2-CHLORO-A,A,A-TRIFLUORO-P-TOLYLOXY)-2-NITROBENZOA
CBNumber:
CB8455648
Molecular Formula:
C14H6ClF3NNaO5
Molecular Weight:
383.64
MDL Number:
MFCD00137378
MOL File:
62476-59-9.mol
MSDS File:
SDS
Last updated:2023-05-04 15:12:42

5-(2-Chloro-4-(trifluoro-methyl)phenoxy)-2-nitro-benzoic acid sodium salt Properties

Melting point 124-125°C
Boiling point >100 °C
Density 1.26 g/cm3(Temp: 23 °C)
form solid
FDA UNII 6H07I1G902
Proposition 65 List Acifluorfen Sodium
EPA Substance Registry System Acifluorfen, sodium salt (62476-59-9)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS07,GHS09,GHS05
Signal word  Danger
Hazard statements  H318-H410-H302-H315
Precautionary statements  P264-P270-P301+P312-P330-P501-P264-P280-P302+P352-P321-P332+P313-P362-P280-P305+P351+P338-P310-P273-P391-P501
HS Code  29252900

5-(2-Chloro-4-(trifluoro-methyl)phenoxy)-2-nitro-benzoic acid sodium salt price

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Biosynth Carbosynth FA148801 Acifluorfensodium 62476-59-9 10mg $66 2021-12-16 Buy
Biosynth Carbosynth FA148801 Acifluorfensodium 62476-59-9 25mg $131 2021-12-16 Buy
AK Scientific O566 Acifluorfensodium 62476-59-9 25mg $226 2021-12-16 Buy
Biosynth Carbosynth FA148801 Acifluorfensodium 62476-59-9 50mg $228 2021-12-16 Buy
Biosynth Carbosynth FA148801 Acifluorfensodium 62476-59-9 100mg $396 2021-12-16 Buy
Product number Packaging Price Buy
FA148801 10mg $66 Buy
FA148801 25mg $131 Buy
O566 25mg $226 Buy
FA148801 50mg $228 Buy
FA148801 100mg $396 Buy

5-(2-Chloro-4-(trifluoro-methyl)phenoxy)-2-nitro-benzoic acid sodium salt Chemical Properties,Uses,Production

Description

Sodium acifluorfen was first registered in the United States in 1980 as the herbicide Blazer, by the Rohm and Haas Company. In 1987, the BASF Corporation purchased the registration and supporting data. In 2003, the US Environmental Protection Agency (EPA) conducted an assessment to determine if pesticide products containing the active ingredient sodium acifluorfen were eligible for pesticide reregistration. Results of the US EPA assessment were explained in the Reregistration Eligibility Decision (RED) of sodium acifluorfen. The RED document determined pesticides with the active ingredient of sodium acifluorfen were eligible for reregistration provided certain stipulations listed in the RED document were met, which included additional label requirements to limit the potential for drift. Under the Federal Insecticide, Fungicide, and Rodenticide Act (FIFRA) Section 3, all new pesticides used in the United States must be registered by the Administrator of the US EPA. There are 12 registrations for sodium acifluorfen.

Chemical Properties

A diphenyl ether, is a combustible, off-white, light tan or brown solid.

Uses

Sodium acifluorfen is a member of a diphenyl ether group of light-dependent peroxidizing herbicides. Sodium acifluorfen is also a member of the nitrophenyl ether class of herbicides. This class of herbicides can cause rapid disruption of cell membranes in plants. Acifluorfen penetrates into the cytoplasm and causes the formation of peroxides and free electrons (requires light), ultimately destroying the cell membrane. Destruction of the cell membrane prevents translocation to other regions of the plant. In the environment, sodium acifluorfen degrades to acifluorfen (or acifluorfen acid). Additionally, acifluorfen acid is a degradation product of lactofen, another herbicide used on agricultural crops and in forestry. Sodium acifluorfen can be used alone or formulated with similar herbicides. Various formulation types include liquid, ready-to-use, and soluble concentrates. Agricultural crop applications are conducted by aircraft and by broadcast and band treatment using ground equipment. A trigger spray bottle for spot treatment is used by both agricultural and residential applicators. Sodium acifluorfen is primarily used on agricultural crops as a nonselective herbicide for pre- and postemergent control of annual broadleaf weeds and grasses. From 2001 to 2007, the annual US agricultural consumption of sodium acifluorfen was estimated at 300 000 pounds. An estimated 200 000 pounds of the agricultural consumption was applied to soybean crops. Sodium acifluorfen is also used on the agricultural crops peanuts, rice, peas, and strawberries. Sodium acifluorfen is registered for residential use; however, it is limited to spot treatment with ready-to-use formulations. Residential application of sodium acifluorfen is minor compared to agricultural, since it is a nonselective herbicide that kills both weeds and grasses.

General Description

White powder. Melting point 255- 257°F (124-125°C). Irritates skin and eyes. Used as a herbicide.

Air & Water Reactions

Water soluble.

Potential Exposure

A potential danger to those involved in the manufacture, formulation and application of this selective preemergence and postemergence herbicide used to control weeds and grass in soybean and peanut crops

Environmental Fate

Acifluorfen inhibits the enzyme protoporphyrinogen oxidase, which catalyzes the dehydrogenation of protoporphyrinogen IX to protoporphyrin IX. In the presence of light, accumulated protoporphyrin can generate highly reactive oxygen species and induce membrane lipid peroxidation. The peroxidation of the lipid can result in a chain reaction and cause fragmentation and destruction of the lipid. The consequence of lipid peroxidation for a cell is loss of the membrane function. The primary target organs for sodium acifluorfen are the liver and kidneys. However, there are limited data that suggest cells can synthesize cytochrome P450 for detoxification of sodium acifluorfen. Further study is needed to confirm this.

Shipping

UN2588 Pesticides, solid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required. UN3077 Environmentally hazardous substancessolid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required

Toxicity evaluation

Sodium acifluorfen is directly released into the environment as a pre/postemergent herbicide. In the environment, sodium acifluorfen dissociates to acifluorfen. Sodium acifluorfen has an estimated Henry’s law constant of 6.03 × 10-11 atmm3 mol-1 derived from a vapor pressure of 1.33 ×105mm Hg. Sodium acifluorfen has a water solubility of 62.07 g 100 ml1 (at 20°C) and an octanol/water partition coefficient of 1.55. Additionally, sodium acifluorfen has a pKa of 3.86, indicating it will exist in the anion form at pH values from 5 to 9. Acifluorfen has an estimated vapor pressure of 1.5×10-8mm Hg, Koc values from 44 to 684, and an estimated pKa of 2.07.
The pKa of sodium acifluorfen indicates the compound will exist in an anion form in the environment. Compared to their neutral counterparts, anion forms do not strongly adsorb to soils containing organic carbon and clay. Anions do not volatilize, therefore it is highly unlikely that acifluorfen will volatilize from dry or moist soil conditions. Additionally, volatilization of sodium acifluorfen from water surfaces is also highly unlikely. The estimated vapor pressure of acifluorfen indicates that it will exist in both the vapor and particulate phases in the ambient air. Based on the Koc value range of 44–684, acifluorfen has a very high to low mobility in soil. Adsorption and desorption are strongly correlated to site-specific soil parameters such as pH and mineral content.

Incompatibilities

Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. Avoid contact with all sources of ignition.

Waste Disposal

In accordance with 40CFR165, follow recommendations for the disposal of pesticides and pesticide containers.

5-(2-Chloro-4-(trifluoro-methyl)phenoxy)-2-nitro-benzoic acid sodium salt Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 40)Suppliers
Supplier Tel Email Country ProdList Advantage
career henan chemical co
+86-0371-86658258 sales@coreychem.com China 29914 58
Hubei Jusheng Technology Co.,Ltd.
18871490254 linda@hubeijusheng.com CHINA 28180 58
Chongqing Chemdad Co., Ltd
+86-023-61398051 +8613650506873 sales@chemdad.com China 39916 58
CONIER CHEM AND PHARMA LIMITED
+8618523575427 sales@conier.com China 49390 58
TargetMol Chemicals Inc.
+1-781-999-5354 support@targetmol.com United States 19973 58
Aceschem Inc.
+1-817863-6948 +1-(817)863-6948 sales@aceschem.com United States 19639 58
Amadis Chemical Company Limited
571-89925085 sales@amadischem.com China 131981 58
TianJin Alta Scientific Co., Ltd. 022-65378550-8551 contact@altascientific.com China 2773 58
Alta Scientific Co., Ltd. 022-6537-8550 15522853686 sales@altasci.com.cn China 4515 55
Guangdong wengjiang Chemical Reagent Co., Ltd. 0751-2886750 13927877953 3005811397@qq.com China 13374 58

Related articles

  • Use of Sodium acifluorfen
  • Sodium acifluorfen was first registered in the United States in 1980 as the herbicide Blazer, by the Rohm and Haas Company. In....
  • Oct 20,2021

View Lastest Price from 5-(2-Chloro-4-(trifluoro-methyl)phenoxy)-2-nitro-benzoic acid sodium salt manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Acifluorfen sodium pictures 2019-07-06 Acifluorfen sodium
62476-59-9
US $1.00 / kg 1g 99% 100KG Career Henan Chemical Co
Blazer Acifluorfen Sodium (Patented-No-Supply) ACIFLUORFENSODIUMSALT 5-(2-chloro-4-(trifluoromethyl)phenoxy)-2-nitro-benzoic aci sodium salt SODIUM5-(2-CHLORO-A,A,A-TRIFLUORO-P-TOLYLOXY)-2-NITROBENZOA Scifluorfen 5-(2-CHLORO-4-(TRIFLUOROMETHYL)PHENOXY)-2-NITROBENZOATESODIUM Aciuorfen sodiuM Benzoic acid, 5-[2-chloro-4-(trifluoromethyl)phenoxy]-2-nitro-, sodium salt Sodium acifluorfen SODIUM 5-(2-CHLORO-ALPHA,ALPHA,ALPHA-TRIFLUORO-P-TOLYLOXY)-2-NITROBENZOATE sodium 5-[2-chloro-4-(trifluoromethyl)phenoxy]-2-nitrobenzoate tackle 2as 5-(2-chloro-4-(trifluoro-methyl)phenoxy)-2-nitro-benzoic acid sodium salt ACIFLUORFEN SODIUM LS 80.1213 62476-59-9 C14H6ClF3NNaO5 C14H7ClF3NO5Na