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1,1,2-Trichlorotrifluoroethane

1,1,2-Trichlorotrifluoroethane
1,1,2-Trichlorotrifluoroethane
CAS No.
76-13-1
Chemical Name:
1,1,2-Trichlorotrifluoroethane
Synonyms
P113;R113;f113;tctfe;FREON;STAT2;F 113;FC-113;ISGF-3;FC 133
CBNumber:
CB8738958
Molecular Formula:
C2Cl3F3
Formula Weight:
187.38
MOL File:
76-13-1.mol

1,1,2-Trichlorotrifluoroethane Properties

Melting point:
−35 °C(lit.)
Boiling point:
47-48 °C(lit.)
Density 
1.57 g/mL at 25 °C(lit.)
vapor density 
6.5 (vs air)
vapor pressure 
5.5 psi ( 20 °C)
refractive index 
n20/D 1.358(lit.)
Flash point:
195°C
storage temp. 
2-8°C
solubility 
0.17g/l
Water Solubility 
0.02 g/100 mL. Slightly soluble
Stability:
Stable. Non-flammable. Incompatible with alkali metals, chemically active metals, magnesium, zinc, aluminium.
CAS DataBase Reference
76-13-1(CAS DataBase Reference)
NIST Chemistry Reference
Ethane, 1,1,2-trichloro-1,2,2-trifluoro-(76-13-1)
EPA Substance Registry System
Ethane, 1,1,2-trichloro-1,2,2-trifluoro- (76-13-1)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
Hazard Codes  N,Xi,T,F
Risk Statements  52/53-59-39/23/24/25-23/24/25-51/53-11
Safety Statements  59-61-45-36/37-16
RIDADR  UN 3082 9/PG 3
WGK Germany  2
RTECS  KJ4000000
Hazard Note  Irritant
Hazardous Substances Data 76-13-1(Hazardous Substances Data)
Symbol(GHS):
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H370 Causes damage to organs Specific target organ toxicity, single exposure Category 1 Danger P260, P264, P270, P307+P311, P321,P405, P501
H411 Toxic to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 2
H420 Harms public health and the environment by destroying ozone in the upper atmosphere Hazardous to the ozone layer Category 1 Warning P502
Precautionary statements:
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P311 Call a POISON CENTER or doctor/physician.
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

1,1,2-Trichlorotrifluoroethane price More Price(3)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 4S7944 1,1,2-Trichloro-1,2,2-trifluoroethane analytical standard, 2000 μg/mL in methanol 76-13-1 4s7944 $59.2 2018-11-23 Buy
Sigma-Aldrich TX1167 1,1,2-Trichlorotrifluoroethane 76-13-1 4 $3810 2018-11-20 Buy
Sigma-Aldrich T1985000 Trichlorotrifluoroethane European Pharmacopoeia (EP) Reference Standard 76-13-1 t1985000 $179 2018-11-23 Buy

1,1,2-Trichlorotrifluoroethane Chemical Properties,Uses,Production

Chemical Properties

colourless liquid or gas

Chemical Properties

TTE is a colorless liquid. Carbon tetrachloride-like odor at high concentrations. A gas above 48℃.

Uses

Dry-cleaning solvent, fire extinguishers, to make chlorotrifluoroethylene, blowing agent, polymer intermediate, solvent drying, drying electronic parts and precision equipment.

General Description

Colorless liquid with a sweet, ether-like odor. Sinks in water.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

1,1,2-Trichlorotrifluoroethane yields violent reactions with Al, Ba, Li, Sm, Na/K alloy and Ti . May react exothermically with aluminum.

Health Hazard

Inhalation causes irritation of the nose, throat, and lungs. High concentrations may cause death by respiratory failure or asphyxiation. May produce superficial skin burns or defatting type dermatitis and may irritate the eyes.

Safety Profile

Mildly toxic by ingestion and inhalation. Affects the central nervous system in humans. A sktn irritant. Combustible when exposed to heat or flame. Incompatible with Al, Ba, Li, Sm, NaK alloy, Ti. See also CHLORINATED HYDROCARBONS, ALIPHATIC; and FLUORIDES.

Potential Exposure

TTE is used as a solvent and refrigerant; it is used in fire extinguishers; as a blowing agent and as an intermediate in the production of chlorotrifluoroethylene monomer by reaction with zinc.

First aid

If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 minutes, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medical attention. Give large quantities of water and induce vomiting. Do not make an unconscious person vomit. If frostbite has occurred, seek medical attention immediately; do NOT rub the affected areas or flush them with water. In order to prevent further tissue damage, do NOT attempt to remove frozen clothing from frostbitten areas. If frostbite has NOT occurred, immediately and thoroughly wash contaminated skin with soap and water.

Shipping

UN3082 Environmentally hazardous substances, liquid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required.

Purification Methods

Wash it with water, then with weak alkali. Dry it with CaCl2 or H2SO4 and distil it. [Locke et al. J Am Chem Soc 56 1726 1934, Beilstein 1 III 157, 1 IV 142.]

Incompatibilities

Violent reaction with chemically active metals (such as powdered aluminum; beryllium, magnesium and zinc); calcium. Contact with alloys containing more than 2% magnesium causes decomposition, releasing hydrogen chloride, hydrogen fluoride; and carbon monoxide. May react exothermically with aluminum.

Waste Disposal

Incineration, preferably after mixing with another combustible fuel. Care must be exercised to assure complete combustion to prevent the formation of phosgene. An acid scrubber is necessary to remove the halo acids produced.

1,1,2-Trichlorotrifluoroethane Preparation Products And Raw materials

Raw materials

Preparation Products


1,1,2-Trichlorotrifluoroethane Suppliers

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