2,4,6,8-Tetravinyl-2,4,6,8-tetramethylcyclotetrasiloxane
- CAS No.
- 2554-06-5
- Chemical Name:
- 2,4,6,8-Tetravinyl-2,4,6,8-tetramethylcyclotetrasiloxane
- Synonyms
- 2,4,6,8-TETRAMETHYL-2,4,6,8-TETRAVINYLCYCLOTETRASILOXANE;Tetravinyltetramethylcyclotetrasiloxane;DK706;2,4,6,8-TETRAM;Vinyl ring body;Vinylmethylcyclosiloxane;METHYLVINYLCYCLOSILOXANE;tetravinyl-tetramethylcyclo-tetrasiloxane;s-tetramethyltetravinylcyclotetrasiloxane;Tetravinyl tetramethylcyelo tetrasiloxane
- CBNumber:
- CB9446902
- Molecular Formula:
- C12H24O4Si4
- Molecular Weight:
- 344.66
- MDL Number:
- MFCD00040293
- MOL File:
- 2554-06-5.mol
Melting point | −44 °C (dec.)(lit.) |
---|---|
Boiling point | 111-112 °C10 mm Hg(lit.) |
Density | 0.997 g/mL at 25 °C(lit.) |
vapor pressure | 93.5Pa at 25℃ |
refractive index |
n |
Flash point | 210 °F |
storage temp. | Keep in dark place,Sealed in dry,Room Temperature |
solubility | Miscible with most organic solvents. |
form | liquid |
Specific Gravity | 0.998 |
color | Colorless to Almost colorless |
Viscosity | 6.3mm2/s |
Water Solubility | 7μg/L at 23℃ |
Hydrolytic Sensitivity | 4: no reaction with water under neutral conditions |
BRN | 1807272 |
LogP | 6.47 |
CAS DataBase Reference | 2554-06-5(CAS DataBase Reference) |
Indirect Additives used in Food Contact Substances | TETRAMETHYLTETRAVINYLCYCLOTETRASILOXANE |
EWG's Food Scores | 1 |
FDA UNII | 3NT606T1VK |
NIST Chemistry Reference | 2,4,6,8-Tetravinyl-2,4,6,8-tetramethylcyclotetrasiloxane(2554-06-5) |
EPA Substance Registry System | Cyclotetrasiloxane, 2,4,6,8-tetraethenyl-2,4,6,8-tetramethyl- (2554-06-5) |
2,4,6,8-Tetravinyl-2,4,6,8-tetramethylcyclotetrasiloxane price More Price(28)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich | 396281 | 2,4,6,8-Tetramethyl-2,4,6,8-tetravinylcyclotetrasiloxane | 2554-06-5 | 10ml | $46 | 2024-03-01 | Buy |
Sigma-Aldrich | 396281 | 2,4,6,8-Tetramethyl-2,4,6,8-tetravinylcyclotetrasiloxane | 2554-06-5 | 50ml | $131 | 2024-03-01 | Buy |
TCI Chemical | T2523 | 2,4,6,8-Tetramethyl-2,4,6,8-tetravinylcyclotetrasiloxane >97.0%(GC) | 2554-06-5 | 5g | $16 | 2024-03-01 | Buy |
TCI Chemical | T2523 | 2,4,6,8-Tetramethyl-2,4,6,8-tetravinylcyclotetrasiloxane >97.0%(GC) | 2554-06-5 | 25g | $35 | 2024-03-01 | Buy |
Alfa Aesar | L16645 | 2,4,6,8-Tetramethyl-2,4,6,8-tetravinylcyclotetrasiloxane, 97% | 2554-06-5 | 50g | $78.4 | 2024-03-01 | Buy |
2,4,6,8-Tetravinyl-2,4,6,8-tetramethylcyclotetrasiloxane Chemical Properties,Uses,Production
Chemical Properties
Colorless transparent liquid
Physical properties
bp 224–224.5 °C.
Uses
2,4,6,8-Tetramethyl-2,4,6,8-tetravinylcyclotetrasiloxane is used as an intermediate in organic synthesis. It is used in the preparation of 4-vinyl-benzoic acid ethyl ester. Further, it is used to prepare styrene derivatives by cross-coupling with aryl bromide in the presence of palladium catalyst.
Uses
2,4,6,8-Tetraethenyl-2,4,6,8-tetramethylcyclotetrasiloxane (1) (D4V) and the trimer, 2,4,6-triethenyl-2,4,6- trimethylcyclotrisiloxane (2) (D3V) are the two commercially available cyclic polyvinylmethylsiloxanes. D4 V is used as a vinyl donor in the palladium-catalyzed vinylation of aryl halides and as a building block in polymer chemistry and dendrimer synthesis. The palladium-catalyzed vinylation of substituted aryl halides using D4 V is a general and mild method for the preparation of a variety of substituted styrenes or dienes.It is widely used as reagent for the vinylation of aryl halides and building block for carbosilane dendrimers.
General Description
In the presence of a Pd catalyst, this reagent cross-couples with aryl bromides to give styrene derivatives.
Hazard
Low toxicity by ingestion and inhalation.
Flammability and Explosibility
Non flammable
Purification Methods
A 7mL sample can be distilled in a small Vigreux column (p 11) at atmospheric pressure without polymerisation or decomposition. It is soluble in cyclohexane. [Kantor et al. J Am Chem Soc 77 1685 1955, Beilstein 4 IV 4184.]
2,4,6,8-Tetravinyl-2,4,6,8-tetramethylcyclotetrasiloxane Preparation Products And Raw materials
Raw materials
Preparation Products
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
Wuhan Kemi-Works Chemical Co., Ltd. | +86-2785736489 +8618171418573 | sales@kemiworks.com | China | 704 | 58 |
Dongguan City Betterly New Materials co.,Ltd | +86-13713468294 +86-13535083564 | waimaobu@betely.com | China | 38 | 58 |
Hebei Mojin Biotechnology Co., Ltd | +8613288715578 | sales@hbmojin.com | China | 12470 | 58 |
Hubei Changfu Chemical Co., Ltd. | +86-027-84396550 +8617721064038 | sales@cfsilanes.com | China | 410 | 58 |
Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 16228 | 58 |
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21687 | 55 |
Shanghai Time Chemicals CO., Ltd. | +86-021-57951555 +8617317452075 | jack.li@time-chemicals.com | China | 1807 | 55 |
ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 32715 | 60 |
Win-Win Chemical CO., Limited | 0086-577-64498589 | sales@win-winchemical.com | CHINA | 998 | 58 |
Hubei Jusheng Technology Co.,Ltd. | 18871490254 | linda@hubeijusheng.com | CHINA | 28180 | 58 |
View Lastest Price from 2,4,6,8-Tetravinyl-2,4,6,8-tetramethylcyclotetrasiloxane manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
---|---|---|---|---|---|---|---|---|
2024-06-13 | 2,4,6,8-Tetramethyl-2,4,6,8-tetravinylcyclotetrasiloxane
2554-06-5
|
US $0.00 / kg | 1kg | 98 | 20 tons | Hubei Changfu Chemical Co., Ltd. | ||
2023-11-16 | 2,4,6,8-Tetravinyl-2,4,6,8-tetramethylcyclotetrasiloxane
2554-06-5
|
US $0.00-0.00 / kg | 1kg | 99% | 50000kg | Hebei Kingfiner Technology Development Co.Ltd | ||
2023-08-21 | 2,4,6,8-Tetravinyl-2,4,6,8-tetramethylcyclotetrasiloxane
2554-06-5
|
US $0.00 / KG | 1KG | 99% | 50000KG/month | Hebei Mojin Biotechnology Co., Ltd |
- 2,4,6,8-Tetramethyl-2,4,6,8-tetravinylcyclotetrasiloxane
2554-06-5
- US $0.00 / kg
- 98
- Hubei Changfu Chemical Co., Ltd.
- 2,4,6,8-Tetravinyl-2,4,6,8-tetramethylcyclotetrasiloxane
2554-06-5
- US $0.00-0.00 / kg
- 99%
- Hebei Kingfiner Technology Development Co.Ltd
- 2,4,6,8-Tetravinyl-2,4,6,8-tetramethylcyclotetrasiloxane
2554-06-5
- US $0.00 / KG
- 99%
- Hebei Mojin Biotechnology Co., Ltd
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