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1-メチルチオ-N-(メチルカルバモイルオキシ)-1-エタンイミン

1-メチルチオ-N-(メチルカルバモイルオキシ)-1-エタンイミン 化学構造式
16752-77-5
CAS番号.
16752-77-5
化学名:
1-メチルチオ-N-(メチルカルバモイルオキシ)-1-エタンイミン
别名:
ヌドリン;ランナート;メトミル;ランネート45;S-メチル-N-(メチルカルバモイルオキシ)チオアセトイミダート;ランネート;メソミル;N-[(メチルカルバモイル)オキシ]エタンイミドチオ酸メチル;デュポン1179;1-メチルチオ-N-(メチルカルバモイルオキシ)-1-エタンイミン;殺虫剤-1179;メソミル標準品;S-メチル-N-[(メチルカルバモイル)-オキシ]-チオアセトイミデート;S-メチル-N-(メチルカルバモイルオキシ)チオアセチミデート (別名 メソミル);S-メチル-N-(メチルカルバモイルオキシ)チオアセトイミダート (メソミル);6-メチル-4-オキサ-7-チア-2,5-ジアザオクタ-5-エン-3-オン;S-メチル-N-(メチルカルバモイルオキシ)チオアセチミデート (別名メソミル);CS_N-12399-100MG_メソミル;メソミル (LANNランネートANDARD;メソミル STANDARD
英語化学名:
Methomyl
英語别名:
KUIK;DUNET;lanox;NUDRIN;Flytek;in1179;Kipsin;LANNATE;IN 1179;Metomil
CBNumber:
CB1259124
化学式:
C5H10N2O2S
分子量:
162.21
MOL File:
16752-77-5.mol

1-メチルチオ-N-(メチルカルバモイルオキシ)-1-エタンイミン 物理性質

融点 :
78°C
沸点 :
144°C
比重(密度) :
d424 1.2946
屈折率 :
1.6430 (estimate)
貯蔵温度 :
0-6°C
外見 :
solid
水溶解度 :
Soluble. 5.8 g/100 mL
Merck :
13,6012
BRN :
3081564
暴露限界値:
NIOSH REL: TWA 2.5 mg/m3; ACGIH TLV: TWA 2.5 mg/m3.
安定性::
Stable. Incompatible with strong bases, strong oxidizing agents.
InChIKey:
UHXUZOCRWCRNSJ-QPJJXVBHSA-N
CAS データベース:
16752-77-5(CAS DataBase Reference)
NISTの化学物質情報:
Methomyl(16752-77-5)
EPAの化学物質情報:
Ethanimidothioic acid, N-[[(methylamino)carbonyl] oxy]-, methyl ester(16752-77-5)
安全性情報
  • リスクと安全性に関する声明
  • 危険有害性情報のコード(GHS)
主な危険性  T+;N,N,T+,Xn,F,Xi
Rフレーズ  28-50/53-36-20/21/22-11-36/37/38
Sフレーズ  1/2-22-36/37-60-61-45-16-36-26-28
RIDADR  UN 2757
WGK Germany  3
RTECS 番号 AK2975000
国連危険物分類  6.1(a)
容器等級  II
HSコード  29309090
有毒物質データの 16752-77-5(Hazardous Substances Data)
毒性 LD50 orally in male rats: 17 mg/kg (Kaplan, Sherman)
安衛法 57,57-2
PRTR法 第1種指定化学物質
毒劇物取締法 II
絵表示(GHS)
注意喚起語 Danger
危険有害性情報
コード 危険有害性情報 危険有害性クラス 区分 注意喚起語 シンボル P コード
H300 飲み込むと生命に危険 急性毒性、経口 1, 2 危険 P264, P270, P301+P310, P321, P330,P405, P501
H410 長期的影響により水生生物に非常に強い毒性 水生環境有害性、慢性毒性 1 警告 P273, P391, P501
注意書き
P273 環境への放出を避けること。
P391 漏出物を回収すること。
P501 内容物/容器を...に廃棄すること。

1-メチルチオ-N-(メチルカルバモイルオキシ)-1-エタンイミン 価格 もっと(13)

メーカー 製品番号 製品説明 CAS番号 包装 価格 更新時間 購入
富士フイルム和光純薬株式会社(wako) W01ACSM-531-04 メソミル
Methomyl, 0.1 mg/mL in Acetonitrile
16752-77-5 1mL ¥4400 2018-12-26 購入
富士フイルム和光純薬株式会社(wako) W01ACSAS-E0784 メソミル (Lannランネートandard
Methomyl (Lannate) Standard, 1000 ug/mL in Acetonitrile
16752-77-5 1mL ¥11800 2018-12-26 購入
関東化学株式会社(KANTO) 49802-60 メソミル標準品
Methomyl standard
16752-77-5 100mg ¥9000 2018-12-13 購入
Sigma-Aldrich Japan 36159 メソミル PESTANAL?, analytical standard
Methomyl PESTANAL?, analytical standard
16752-77-5 100mg ¥8400 2018-12-25 購入
林純薬工業株式会社 99036159 メソミル
Methomyl
16752-77-5 100mg ¥8400 2018-12-15 購入

1-メチルチオ-N-(メチルカルバモイルオキシ)-1-エタンイミン 化学特性,用途語,生産方法

外観

白色, 結晶~結晶性粉末

溶解性

水、エタノール及びアセトンに溶ける。

用途

農薬(殺虫剤)

説明

Acetamide acid (methomyl) is a carbamate broad-spectrum insecticide. Methomyl is classified as a restricted use pesticide (RUP). It is a crystalline solid with a slight sulphurous odour and very soluble in methanol, acetone, ethanol, and isopropanol. It decomposes with heat and releases hazardous gases/vapours, such as sulphur oxides, methyl isocyanate, and HCN. Acetamide acid (methomyl) is used both as a contact insecticide and as a systemic insecticide. It is used as an acaricide to control ticks and spiders; as fly bait; for foliar treatment of vegetable, fruit, field crops, cotton, and commercial ornamentals; and in and around poultry houses and dairies.

化学的特性

Acetamidic acid (methomyl) is carbamate broad-spectrum insecticide. Methomyl is clas- sifi ed as a restricted use pesticide (RUP). It is a crystalline solid with a slight sulfurous odor, very soluble in methanol, acetone, ethanol, and isopropanol. It decomposes with heat and releases hazardous gases/vapors, such as sulfur oxides, methylisocyanate, and HCN. Acetamidic acid (methomyl) is used both as a contact insecticide and as a systemic insecticide. It is used as an acaricide to control ticks, spiders, as fl y bait, for foliar treatment of vegetable, fruit and fi eld crops, cotton, commercial ornamentals, and in and around poultry houses and dairies.

化学的特性

Methomyl is a white crystalline solid with a slight sulfurous odor. A noncombustible solid, that may be dissolved in flammable liquids that may alter physical properties listed here.

使用

Insecticide, nematocide.

使用

Insecticide.

定義

ChEBI: A carbamate ester obtained by the formal condensation of methylcarbamic acid with the hydroxy group of 1-(methylsulfanyl)acetaldoxime.

一般的な説明

White crystalline solid with slight sulfurous smell. Used as a nematocide, and an insecticide on vegetables, tobacco, cotton, alfalfa, soy beans, and corn.

空気と水の反応

Water soluble.

反応プロフィール

Methomyl is a carbamate ester. Carbamates are chemically similar to, but more reactive than amides. Like amides they form polymers such as polyurethane resins. Carbamates are incompatible with strong acids and bases, and especially incompatible with strong reducing agents such as hydrides. Flammable gaseous hydrogen is produced by the combination of active metals or nitrides with carbamates. Strongly oxidizing acids, peroxides, and hydroperoxides are incompatible with carbamates.

危険性

Toxic by ingestion. Acetyl cholinesterase inhibitor, male reproductive damage, and hematologic effects. Questionable carcinogen.

健康ハザード

Acetamidic acid (methomyl) is potentially a highly poisonous material in humans. Exposures to acetamidic acid (methomyl) cause adverse health effects. It is highly toxic and causes inhibition of cholinesterase activity. The symptoms of toxicity include, but are not limited to, weakness, lack of appetite, blurred vision, pupillary constriction, cor- neal injury, headache, nausea, abdominal cramps, burning sensation, coughing, wheez- ing, laryngitis, shortness of breath, and vomiting. It may be harmful if absorbed through the skin of the mucous membranes and upper upper respiratory tract and cause chest discomfort, constriction of pupils, sweating, muscle tremors, and decreased pulse. After severe poisoning, occupational workers show symptoms of twitching, giddiness, confu- sion, muscle incoordination, heart irregularities, loss of refl exes, slurred speech, paralysis of the muscles of the respiratory system, and death. The target organs of methomyl toxic- ity include nerves, cardiovascular system, liver, and kidneys.

健康ハザード

Methomyl has high oral toxicity, moderate inhalation toxicity and low skin toxicity. The probable oral lethal dose for humans is between 7 drops and 1 teaspoon for a 150 pound adult. Death is due to respiratory arrest.

健康ハザード

Extremely toxic by oral route; moderatelytoxic by inhalation; exhibits acute, delayed,and chronic effects; cholinesterase inhibitor;symptoms are those of phosphate — or carbamate esters — the major signs of whichare increased salivation, lacrimation, spontaneous urination, blurred vision, pinpointpupils, tremor, twitching of muscle and lossof coordination; confusion, convulsions, andcoma may occur as well; other signs ofpoisoning include nausea, vomiting, cramps,diarrhea, slow heart rate, shortness of breath,and pulmonary edema (U.S. EPA 1988);death may result from respiratory arrest(Gosselin et al. 1984); the probable lethaldose from ingestion in adult human could be0.5–2 g; oral lethal dose in dog 30 mg/kg,and monkey 40 mg/kg; toxic effects fromskin absorption low; listed as extremely hazardous substance by the U.S. EPA.
LD50 oral (mouse): 10 mg/kg
LD50 oral (rat): 17 mg/kg
LD50 inhalation (rat): 77 ppm
Tsai et al. (2003) have reported a caseof outbreak of food poisoning at a seafoodrestaurant in Taiwan. High levels of methomyl were found in leafy-vegetables stir-friedwith crab claws (380 ppm) and fried mussels (1113 ppm). The median latency frombeginning eating to first symptoms was5-minutes. The clinical symptoms were general weakness, ataxia, dizziness, vomiting,sweating, floating sensation, headache, dyspnea, and blurred vision..

火災危険

When heated to decomposition, Methomyl emits very toxic fumes of nitrogen oxides and sulfur oxides. Do not subject liquid formulations to temperatures below 32F.

农业用途

Insecticide, Acaricide: Methomyl is a broad-spectrum insecticide that is particularly effective against organophosphorus-resistant pests. It is used as an acaricide to control ticks and spiders. It is used for foliar treatment of vegetable, fruit and field crops, tobacco, cotton, commercial ornamentals, and in and around poultry houses and dairies. It is also used as a fly bait. Methomyl is effective as a “contact insecticide,” because it kills target insects upon direct contact, and also as a “systemic insecticide” because of its capability to cause overall “systemic” poisoning in target insects, after it is absorbed and transported throughout the pests that feed on treated plants. It is capable of being absorbed by plants without being “phytotoxic” or harmful, to the plant. A U.S. EPA restricted Use Pesticide (RUP).

製品名

ACINATE®; AGRINATE®; CIMETLE®; DuPont TM 1179®; FRAM FLY KILL®; FLYTEK®; IMPROVED BLUE MALRIN SUGAR BAIT®; IMPROVED GOLDEN MALRIN BAIT®; INSECTICIDE 1179®; KIPSIN®; KUIK®; LANNATE®; LANNOX®; LANOX 90®; LANOX 216®; METHOMEX®; METHOMYL® 20SC; MEMILENE®; METHAVIN®; NU-BAIT II®; NUDRIN®; PILLARMATE®; RENTOKILL®; RENTOKIL FRAM FLY BAIT®; RIDECT®; SD 14999®; SOREX GOLDEN FLY BAIT®; WL 18236®

接触アレルゲン

Methomyl is a pesticide agent, a carbamate insecticide with anticholinesterase activity. This mixture of two stereoisomers is used as a foliar spray to control field crops, in stables and poultry houses, and in glasshouses on ornamentals and vegetables, or in flypapers. Cases were reported in chrysanthemum growers and in two women working in a plant nursery

安全性プロファイル

Poison by ingestion, inhalation, and subcutaneous routes. Mildly toxic by skin contact. Wen heated to decomposition it emits very toxic fumes of NOx and SOx.

職業ばく露

Methomyl is a broad-spectrum insecticide used as insecticide in many vegetables, field crops; certain fruit crops; and ornamentals.
Incompatibilities: Keep away from strong bases, strong oxidizers. Heat causes decomposition forming toxic and irritating fumes including nitrogen oxides; sulfur oxides; hydrogen cyanide; methylisocyanate

環境運命予測

Biological. From the first-order biotic and abiotic rate constants of methomyl in estuarine water and sediment/water systems, the estimated biodegradation half-lives were 75–165 and 39–134 days, respectively (Walker et al., 1988).
Soil. Harvey and Pease (1973) reported that methomyl dissipated rapidly in fine sand and loamy sand soils. One month following application to a Delaware soil, 1.8% of the applied dosage was recovered and after 1 year, methomyl was not detected. T
Groundwater. According to the U.S. EPA (1986) methomyl has a high potential to leach to groundwater.
Plant. The reported half-lives of methomyl on cotton plants, mint plants and Bermuda grass were 0.4–8.5, 0.8–1.2 and 2.5 days, respectively (Willis and McDowell, 1987).
Chemical/Physical. Emits toxic fumes of nitrogen and sulfur oxides when heated to decomposition (Sax and Lewis, 1987; Lewis, 1990).

貯蔵

Acetamidic acid (methomyl) should be kept stored in a sealed container in a cool (below 0 ° C), dry, area with adequate ventilation. The chemical should be kept away from incompatible chemical substances, strong oxidizing agents, strong bases, other pesticides, and food or feed.

輸送方法

UN2757 Carbamate pesticides, solid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials. UN2811 Toxic solids, organic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required

廃棄物の処理

Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≥100 kg/mo) must conform to EPA regulations governing storage, transportation, treatment, and waste disposal. Alkaline hydrolysis leads to complete degradation to nontoxic products. May be dissolved in water and sprayed into a furnace with effluent gas scrubbing also. In accordance with 40CFR165, follow recommendations for the disposal of pesticides and pesticide containers. Must be disposed properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office.

予防処置

Occupational workers should avoid contact of acetamidic acid (methomyl) with the skin, eyes, or clothing, and avoid exposures to vapor or mist. Workers should be careful when storing and/or disposing of acetamidic acid, avoid the dust contaminating water, food, or feed by storage or disposal. Workers should use respiratory protection: Government approved respirator. Hand Protection: Compatible chemical-resistant gloves. Eye Protection: Chemical safety goggles.chemical safety goggles.

1-メチルチオ-N-(メチルカルバモイルオキシ)-1-エタンイミン 上流と下流の製品情報

原材料

準備製品


1-メチルチオ-N-(メチルカルバモイルオキシ)-1-エタンイミン 生産企業

Global( 0)Suppliers
名前 電話番号 ファックス番号 電子メール 国籍 製品カタログ 優位度

16752-77-5(1-メチルチオ-N-(メチルカルバモイルオキシ)-1-エタンイミン)キーワード:


  • 16752-77-5
  • 1-(METHYLTHIO)-ETHYLIDENEAMINOMETHYLCARBAMATE
  • 2-Methylthio-acetaldehyd-O-(methylcarbamoyl)-oxime
  • 2-methylthio-propionaldehyd-o-(methylcarbamoyl)oxim
  • 2-methylthio-propionaldehyd-o-(methylcarbamoyl)-oxim
  • 3-Thiabutan-2-one, O-(methylcarbamoyl)oxime
  • 3-thiabutan-2-one,o-(methylcarbamoyl)oxime
  • 5-methylN-(methylcarbamoyloxy)thioacetimidate
  • Acetimidic acid, N-[(methylcarbamoyl)oxy]thio-, methyl ester
  • Acetimidic acid, thio-N-((methylcarbamoyl)oxy)-, methyl ester
  • Acetimidothioic acid, methyl-, N-(methylcarbamoyl) ester
  • dpx-x1179-412
  • Du Pont Insecticide 1179
  • dupontinsecticide1179
  • ENT 27,341
  • methomyl00
  • Methyl (1E)-N-([(methylamino)carbonyl]oxy)ethanimidothioate
  • Methyl N-(((methylamino)carbonyl)oxy)ethanimidothioate
  • Methyl N-[(Methylcarbamoyl)oxy]thioacetimidate
  • Methyl O-(methylcarbamoyl)thiolacethohydroxamate
  • Methyl O-(methylcarbamoyl)thiolacetohydroxamate
  • Methyl O-(methylcarbamyl)thiolacetohydroxamate
  • methyl-acetimidothioicacin-(methylcarbamoyl)ester
  • methyln-(((methylamino)carbonyl)oxy)ethanimidothioate
  • methyln-((methylamino)carbonyl)oxy)ethanimido)thioate
  • methyl-n-((methylcarbamoyl)oxy)thioacetimidate
  • methyln-((methylcarbamoyl)oxy)thioacetimidate
  • S-Methyl-n-[(methylamino carboxyl)-oxygen]thio acetamide
  • METHOMYL PESTANAL
  • METHOMYL, 1GM, NEAT
  • METHOMYL, 250MG, NEAT
  • ヌドリン
  • ランナート
  • メトミル
  • ランネート45
  • S-メチル-N-(メチルカルバモイルオキシ)チオアセトイミダート
  • ランネート
  • メソミル
  • N-[(メチルカルバモイル)オキシ]エタンイミドチオ酸メチル
  • デュポン1179
  • 1-メチルチオ-N-(メチルカルバモイルオキシ)-1-エタンイミン
  • 殺虫剤-1179
  • メソミル標準品
  • S-メチル-N-[(メチルカルバモイル)-オキシ]-チオアセトイミデート
  • S-メチル-N-(メチルカルバモイルオキシ)チオアセチミデート (別名 メソミル)
  • S-メチル-N-(メチルカルバモイルオキシ)チオアセトイミダート (メソミル)
  • 6-メチル-4-オキサ-7-チア-2,5-ジアザオクタ-5-エン-3-オン
  • S-メチル-N-(メチルカルバモイルオキシ)チオアセチミデート (別名メソミル)
  • CS_N-12399-100MG_メソミル
  • メソミル (LANNランネートANDARD
  • メソミル STANDARD
  • メソミル標準物質
  • メソミル (Lannランネートandard, 1000 µg/mL in Acetonitrile
  • メソミル Standard, 0.1 mg/mL in Acetonitrile
  • メソミル Standard, 100 µg/mL in MeOH
  • メソミル, 0.1 mg/mL in Acetonitrile
  • メソミル, 100 µg/mL in MeOH
  • メソミル, 1000 µg/mL in AcCN
  • カーバメート系殺虫剤
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