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フルオランテン

フルオランテン 化学構造式
206-44-0
CAS番号.
206-44-0
化学名:
フルオランテン
别名:
フルオランテン;イドリル;1,2-ベンゾアセナフテン;1,8-[1,2]ベンゼノナフタレン;フルオランテン標準品;フルオランテン (50ΜG/ML トルエン溶液);フルオランテン STANDARD;フルオランテン 溶液;フルオランテン Standard, 100 µg/mL in MeOH;フルオランテン Standard, 5.0 mg/mL in MeOH;フルオランテン, 0.5 mg/mL in Acetonitrile;フルオランテン, 1000 µg/mL in MeOH
英語化学名:
Fluoranthene
英語别名:
Idryl;Fluoranthen;FLUORANTHENE;fluoanthrene;Fluoranthrene;Fluoroanthene;Fluoranthene>Benzo[jk]flurene;Fluoranthene,93%;BENZO(J,K)FLUORENE
CBNumber:
CB3123401
化学式:
C16H10
分子量:
202.25
MOL File:
206-44-0.mol

フルオランテン 物理性質

融点 :
109 °C
沸点 :
384 °C(lit.)
比重(密度) :
1.252
屈折率 :
1.0996
闪点 :
-18 °C
貯蔵温度 :
APPROX 4°C
外見 :
Crystalline Powder, Crystals and/or Chunks
色:
Yellow or yellow-green to gray-beige
水溶解度 :
insoluble
BRN :
1907918
Henry's Law Constant:
5.53, 8.59, 13.0, 19.3, and 26.8(x 10-6 atm?m3/mol) at 4.1, 11.0, 18.0, 25.0, and 31.0 °C, respectively (Bamford et al., 1998)
安定性::
Stable. Incompatible with strong oxidizing agents.
CAS データベース:
206-44-0(CAS DataBase Reference)
IARC:
3 (Vol. Sup 7, 92) 2010
NISTの化学物質情報:
Fluoranthene(206-44-0)
EPAの化学物質情報:
Fluoranthene (206-44-0)
安全性情報
  • リスクと安全性に関する声明
  • 危険有害性情報のコード(GHS)
主な危険性  Xn,N,F,T
Rフレーズ  22-36/37/38-40-67-65-50/53-38-11-39/23/24/25-23/24/25-52/53-50
Sフレーズ  37/39-26-36/37-24/25-23-62-61-60-45-16-7
RIDADR  UN 1593 6.1/PG 3
WGK Germany  2
RTECS 番号 LL4025000
HSコード  29029090
有毒物質データの 206-44-0(Hazardous Substances Data)
毒性 LC50 (24-h) for Daphnia magna 1,300 mg/L (LeBlanc, 1980), Cyprinodon variegatus >560 ppm (H Acute oral LD50 for rats 2,000 mg/kg (quoted, RTECS, 1985).
化審法 (4)-2
絵表示(GHS)
注意喚起語 Danger
危険有害性情報
コード 危険有害性情報 危険有害性クラス 区分 注意喚起語 シンボル P コード
H225 引火性の高い液体および蒸気 引火性液体 2 危険 P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H302 飲み込むと有害 急性毒性、経口 4 警告 P264, P270, P301+P312, P330, P501
H315 皮膚刺激 皮膚腐食性/刺激性 2 警告 P264, P280, P302+P352, P321,P332+P313, P362
H319 強い眼刺激 眼に対する重篤な損傷性/眼刺激 性 2A 警告 P264, P280, P305+P351+P338,P337+P313P
H335 呼吸器への刺激のおそれ 特定標的臓器毒性、単回暴露; 気道刺激性 3 警告
H336 眠気やめまいのおそれ 特定標的臓器毒性、単回暴露; 麻酔作用 3 警告 P261, P271, P304+P340, P312,P403+P233, P405, P501
H351 発がんのおそれの疑い 発がん性 2 警告 P201, P202, P281, P308+P313, P405,P501
H370 臓器の障害 特定標的臓器有害性、単回暴露 1 危険 P260, P264, P270, P307+P311, P321,P405, P501
H373 長期にわたる、または反復暴露により臓器の障 害のおそれ 特定標的臓器有害性、単回暴露 2 警告 P260, P314, P501
H410 長期的影響により水生生物に非常に強い毒性 水生環境有害性、慢性毒性 1 警告 P273, P391, P501
H412 長期的影響により水生生物に有害 水生環境有害性、慢性毒性 3 P273, P501
注意書き
P210 熱/火花/裸火/高温のもののような着火源から遠ざ けること。-禁煙。
P260 粉じん/煙/ガス/ミスト/蒸気/スプレーを吸入しないこ と。
P261 粉じん/煙/ガス/ミスト/蒸気/スプレーの吸入を避ける こと。
P264 取扱い後は皮膚をよく洗うこと。
P264 取扱い後は手や顔をよく洗うこと。
P270 この製品を使用する時に、飲食または喫煙をしないこ と。
P273 環境への放出を避けること。
P280 保護手袋/保護衣/保護眼鏡/保護面を着用するこ と。
P281 指定された個人用保護具を使用すること。
P301+P310 飲み込んだ場合:直ちに医師に連絡すること。
P305+P351+P338 眼に入った場合:水で数分間注意深く洗うこと。次にコ ンタクトレンズを着用していて容易に外せる場合は外す こと。その後も洗浄を続けること。
P311 医師に連絡すること。
P501 内容物/容器を...に廃棄すること。

フルオランテン 価格 もっと(40)

メーカー 製品番号 製品説明 CAS番号 包装 価格 更新時間 購入
富士フイルム和光純薬株式会社(wako) W01ACSAPP-9-108 フルオランテン Standard
Fluoranthene Standard, 100 ug/mL in MeOH
206-44-0 1mL ¥5600 2020-09-21 購入
富士フイルム和光純薬株式会社(wako) W01ACSAPP-9-108-10X フルオランテン
Fluoranthene, 1000 ug/mL in MeOH
206-44-0 1mL ¥5600 2020-09-21 購入
東京化成工業 F0016 フルオランテン >98.0%(GC)
Fluoranthene >98.0%(GC)
206-44-0 100g ¥6500 2018-12-04 購入
東京化成工業 F0016 フルオランテン >98.0%(GC)
Fluoranthene >98.0%(GC)
206-44-0 25g ¥2200 2018-12-04 購入
関東化学株式会社(KANTO) 11917-1A フルオランテン
Fluoranthene
206-44-0 25g ¥4100 2020-09-21 購入

フルオランテン MSDS


Benzo[j,k]fluorene

フルオランテン 化学特性,用途語,生産方法

外観

白色〜うすい黄色, 結晶〜結晶性粉末

溶解性

エタノール及びアセトンに溶けやすく、水にほとんど溶けない。エタノール、エーテル、クロロホルム、二硫化炭素、ベンゼン、酢酸に可溶。

用途

染料中間体。

用途

環境(大気)分析用標準品。

化学的特性

Fluoranthene is a polycyclic hydrocarbon and a colorless crystalline solid.

使用

Fluoranthene is a component of polynuclear aromatic hydrocarbons, also known as polycyclic aromatic hydrocarbons, and is usually bound to small particulate matter present in urban air, industrial and natural combustion emissions, and cigarette smoke.

定義

ChEBI: An ortho- and peri-fused polycyclic arene consisting of a naphthalene and benzene unit connected by a five-membered ring.

Synthesis Reference(s)

Journal of the American Chemical Society, 72, p. 4786, 1950 DOI: 10.1021/ja01166a124
Tetrahedron Letters, 33, p. 1675, 1992

一般的な説明

Light yellow fine crystals.

空気と水の反応

Insoluble in water.

反応プロフィール

Vigorous reactions, sometimes amounting to explosions, can result from the contact between aromatic hydrocarbons, such as Fluoranthene, and strong oxidizing agents. They can react exothermically with bases and with diazo compounds. Substitution at the benzene nucleus occurs by halogenation (acid catalyst), nitration, sulfonation, and the Friedel-Crafts reaction.

危険性

Questionable carcinogen.

健康ハザード

Fluoranthene exhibited mild oral and dermaltoxicity in animals. The acute toxicity is lowerthan that of phenanthrene. An oral LD50 valuein rats is reported as 2000 mg/kg. It may causeskin tumor at the site of application. However,any carcinogenic action from this compoundin animals is unknown..

健康ハザード

ACUTE/CHRONIC HAZARDS: When heated to decomposition Fluoranthene emits acrid smoke and fumes.

火災危険

Flash point data for Fluoranthene are not available. Fluoranthene is probably combustible.

安全性プロファイル

Poison by intravenous route. Moderately toxic by ingestion and skin contact. Questionable carcinogen with experimental tumorigenic data. Human mutation data reported. Combustible when exposed to heat or flame. When heated to decomposition it emits acrid smoke and irritating fumes.

職業ばく露

Fluoranthene, a PAH, is produced from the pyrolytic processing of organic raw materials, such as coal and petroleum at high temperatures. It is also known to occur naturally as a product of plant biosynthesis. Fluoranthene is ubiquitous in the environment and has been detected in United States air; in foreign and domestic drink ing waters and in food-stuffs. It is also contained in ciga rette smoke. Individuals living in areas which are heavily industrialized; and in which large amounts of fossil fuels are burned, would be expected to have greatest exposure from ambient sources of fluoranthene. In addition, certain occupations e.g., coke oven workers, steelworkers, roofers, automobile mechanics) would also be expected to have elevated levels of exposure relative to the general popula tion. Exposure to fluoranthene will be considerably increased among tobacco smokers or those who are exposed to smokers in closed environments (i.e., indoors).

Source

Detected in 8 diesel fuels at concentrations ranging from 0.060 to 13 mg/L with a mean value of 0.113 mg/L (Westerholm and Li, 1994); in a distilled water-soluble fraction of used motor oil at a concentration range of 1.3 to 1.5 μg/L (Chen et al., 1994). Lee et al. (1992) reported concentration ranges 1.50-125 mg/L and ND-0.5 μg/L in diesel fuel and the corresponding aqueous phase (distilled water), respectively (Lee et al., 1992). Schauer et al. (1999) reported fluoranthene in a diesel-powered medium-duty truck exhaust at an emission rate of 53.0 μg/km. Identified in Kuwait and South Louisiana crude oils at concentrations of 2.9 and 5.0 ppm, respectively (Pancirov and Brown, 1975).
California Phase II reformulated gasoline contained fluoranthene at a concentration of 1.15 g/kg. Gas-phase tailpipe emission rates from gasoline-powered automobiles with and without catalytic converters were approximately 4.25 and 160 μg/km, respectively (Schauer et al., 2002).
Detected in groundwater beneath a former coal gasification plant in Seattle, WA at a concentration of 50 μg/L (ASTR, 1995). The concentration of fluoranthene in coal tar and the maximum concentration reported in groundwater at a mid-Atlantic coal tar site were 6,500 and 0.015 mg/L, respectively (Mackay and Gschwend, 2001). Based on laboratory analysis of 7 coal tar samples, fluoranthene concentrations ranged from 1,500 to 13,000 ppm (EPRI, 1990).Lehmann et al. (1984) reported fluoranthene concentrations of 64.7 mg/g in a commercial anthracene oil and 17,400 to 30,900 mg/kg in three high-temperature coal tars. Identified in hightemperature coal tar pitches used in roofing operations at concentrations ranging from 5,200 to 38,800 mg/kg (Arrendale and Rogers, 1981).
Fluoranthene was detected in soot generated from underventilated combustion of natural gas doped with toluene (3 mole %) (Tolocka and Miller, 1995). Fluoranthene was also detected in 9 commercially available creosote samples at concentrations ranging from 55,000 to 120,000 mg/kg (Kohler et al., 2000).
Detected in asphalt fumes at an average concentration of 20.48 ng/m3 (Wang et al., 2001). An impurity in commercial available pyrene (Marciniak, 2002).
Schauer et al. (2001) measured organic compound emission rates for volatile organic compounds, gas-phase semi-volatile organic compounds, and particle-phase organic compounds from the residential (fireplace) combustion of pine, oak, and eucalyptus. The respective gas-phase and particle-phase emission rates of fluoranthene were 3.05 and 3.95 mg/kg of pine burned, 3.61 and 1.20 mg/kg of oak burned, and 3.75 and 0.509 mg/kg of eucalyptus burned.

Solubility in organics

In benzene expressed as mole fraction: 0.2174 at 44.8 °C, 0.3011 at 56.0 °C, 0.3826 at 64.4 °C, 0.5331 at 77.2 °C (shake flask-gravimetric, McLaughlin and Zainal, 1959)
In millimole fraction at 25 °C: 14.76 in n-hexane, 18.70 in n-heptane, 22.60 in n-octane, 26.42 in n-nonane, 30.15 in n-decane, 50.46 in n-hexadecane, 18.07 in cyclohexane, 21.79 in methylcyclohexane, 30.11 in cyclooctane, 11.62 in 2,2,4-trimethylpentane, 24.82 in tert-butyl-cyclohexane, 51.77 in dibutyl ether, 47.55 in methyl tert-butyl ether, 2.67 in methanol, 5.44 in ethanol, 6.70 in 1-propanol, 4.75 in 2-propanol, 9.96 in 1-butanol, 7.02 in 2-butanol, 4.95 in 2- methyl-1-propanol, 14.46 in 1-pentanol, 19.86 1-hexanol, 25.24 in 1-heptanol, 31.25 in 1- octanol, 10.21 in 2-pentanol, 8.62 in 3-methyl-1-butanol, 9.70 in 2-methyl-2-butanol, 17.72 in cyclopentanol, 17.82 in 2-ethyl-1-hexanol, 11.72 in 2-methyl-1-pentanol, 0.948 in 4-methyl-2- pentanol (Hernández and Acree, 1998)

輸送方法

UN1325 Flammable solids, organic, n.o.s., Hazard Class: 4.1; Labels: 4.1-Flammable solid.UN3077 Environmentally hazardous substances, solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required.

純化方法

Fluoranthene (benzo[j,k]fluorene) M 202.3, m 110-111o, b 384o/760mm. Purify it by chromatography of CCl4 solutions on alumina, with *benzene as eluent. Crystallise it from EtOH, MeOH or *benzene. Also purify it by zone melting. [Gorman et al. J Am Chem Soc 107 4404 1985, Beilstein 5 I 344, 5 IV 2463.]

不和合性

Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explo sions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. Compound can react exo thermically with bases and with diazo compounds. Substitution at the benzene nucleus occurs by halogenation (acid catalyst), nitration, sulfonation, and the Friedel Crafts reaction.

廃棄物の処理

Dissolve or mix the material with a combustible solvent and burn in a chemical incinera tor equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed. Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≥100 kg/mo) must con form with EPA regulations governing storage, transportation, treatment, and waste disposal.

フルオランテン 上流と下流の製品情報

原材料

準備製品


フルオランテン 生産企業

Global( 177)Suppliers
名前 電話番号 ファックス番号 電子メール 国籍 製品カタログ 優位度
Springchem New Material Technology Co.,Limited
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Henan DaKen Chemical CO.,LTD.
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Henan Tianfu Chemical Co.,Ltd.
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career henan chemical co
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Haihang Industry Co.,Ltd
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Hubei xin bonus chemical co. LTD
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SIMAGCHEM CORP
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206-44-0(フルオランテン)キーワード:


  • 206-44-0
  • 1,2-(1,8-Naphthalene)benzene
  • 1,2-(1,8-naphthalenediyl)-benzen
  • Fluoranthen
  • 1,2-Benzacenapthene
  • 1,8-[1,2]Benzenonaphthalene
  • Fluoranthene,93%
  • Benzo[jk]flurene
  • Fluoranthene, 98% 25GR
  • Fluoranthene,Benzo[j,k]fluorene
  • Fluoranthene 1g [206-44-0]
  • Fluoranthene 500mg [206-44-0]
  • Fluoranthene in methanol
  • FLUORANTHENE
  • BENZO(J,K)FLUORENE
  • 1,2-(1,8-naphthylene)-benzen
  • 1,2-(1,8-Naphthylene)benzene
  • Benzene, 1,2-(1,8-naphthalenediyl)-
  • Benzene, 1,2-(1,8-naphthylene)-
  • benzene,1,2-(1,8-naphthylene)-
  • Benzo[jk]fluorene, idryl
  • Fluoranthrene
  • Idryl
  • Rcra waste number U120
  • rcrawastenumberu120
  • Fluoranthene (purity)
  • Fluoroanthene
  • fluoanthrene
  • FLUORANTHENE, 1X1ML, CH2CL2, 200UG/ML
  • FLUORANTHENE, 5000MG, NEAT
  • 46416, Fluoranthene (purity)
  • フルオランテン
  • イドリル
  • 1,2-ベンゾアセナフテン
  • 1,8-[1,2]ベンゼノナフタレン
  • フルオランテン標準品
  • フルオランテン (50ΜG/ML トルエン溶液)
  • フルオランテン STANDARD
  • フルオランテン 溶液
  • フルオランテン Standard, 100 µg/mL in MeOH
  • フルオランテン Standard, 5.0 mg/mL in MeOH
  • フルオランテン, 0.5 mg/mL in Acetonitrile
  • フルオランテン, 1000 µg/mL in MeOH
  • 発色剤および関連製品
  • 機能性材料
  • 増感剤
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