ChemicalBook
Chinese Japanese Germany Korea

Fluoranthene

Fluoranthene
Fluoranthene structure
CAS No.
206-44-0
Chemical Name:
Fluoranthene
Synonyms
Idryl;Fluoranthen;FLUORANTHENE;fluoanthrene;Fluoranthrene;Fluoroanthene;Fluoranthene>Benzo[jk]flurene;Fluoranthene,93%;BENZO(J,K)FLUORENE
CBNumber:
CB3123401
Molecular Formula:
C16H10
Formula Weight:
202.25
MOL File:
206-44-0.mol

Fluoranthene Properties

Melting point:
105-110 °C (lit.)
Boiling point:
384 °C (lit.)
Density 
1.252
refractive index 
1.0996
Flash point:
-18 °C
storage temp. 
APPROX 4°C
form 
Crystalline Powder, Crystals and/or Chunks
color 
Yellow or yellow-green to gray-beige
Water Solubility 
insoluble
BRN 
1907918
Henry's Law Constant
5.53, 8.59, 13.0, 19.3, and 26.8(x 10-6 atm?m3/mol) at 4.1, 11.0, 18.0, 25.0, and 31.0 °C, respectively (Bamford et al., 1998)
Stability:
Stable. Incompatible with strong oxidizing agents.
CAS DataBase Reference
206-44-0(CAS DataBase Reference)
EWG's Food Scores
2
FDA UNII
360UOL779Z
IARC
3 (Vol. Sup 7, 92) 2010
NIST Chemistry Reference
Fluoranthene(206-44-0)
EPA Substance Registry System
Fluoranthene (206-44-0)
SAFETY
  • Risk and Safety Statements
Symbol(GHS) 
GHS02,GHS06,GHS08,GHS09,GHS07
Signal word  Danger
Hazard statements  H225-H301+H311+H331-H370-H410-H315-H319-H335-H336-H351-H373-H412-H302
Precautionary statements  P210-P260-P273-P280-P301+P310-P311-P261-P281-P305+P351+P338-P501-P264-P270-P301+P312+P330
Hazard Codes  Xn,N,F,T
Risk Statements  22-36/37/38-40-67-65-50/53-38-11-39/23/24/25-23/24/25-52/53-50
Safety Statements  37/39-26-36/37-24/25-23-62-61-60-45-16-7
RIDADR  UN 1593 6.1/PG 3
WGK Germany  2
RTECS  LL4025000
HS Code  29029090
Toxicity LC50 (24-h) for Daphnia magna 1,300 mg/L (LeBlanc, 1980), Cyprinodon variegatus >560 ppm (H Acute oral LD50 for rats 2,000 mg/kg (quoted, RTECS, 1985).

Fluoranthene price More Price(13)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 40037 Fluoranthene solution ANSI compliant 206-44-0 1EA $28.5 2018-11-13 Buy
Sigma-Aldrich 48535 Fluoranthene analytical standard 206-44-0 5000 mg $48.7 2021-03-22 Buy
Sigma-Aldrich 11474 Fluoranthene certified reference material, TraceCERT 206-44-0 100mg $98.3 2021-03-22 Buy
TCI Chemical F0016 Fluoranthene >98.0%(GC) 206-44-0 25g $33 2021-03-22 Buy
TCI Chemical F0016 Fluoranthene >98.0%(GC) 206-44-0 100g $88 2021-03-22 Buy

Fluoranthene Chemical Properties,Uses,Production

Chemical Properties

Fluoranthene is a polycyclic hydrocarbon and a colorless crystalline solid.

Uses

Fluoranthene is a component of polynuclear aromatic hydrocarbons, also known as polycyclic aromatic hydrocarbons, and is usually bound to small particulate matter present in urban air, industrial and natural combustion emissions, and cigarette smoke.

Definition

ChEBI: An ortho- and peri-fused polycyclic arene consisting of a naphthalene and benzene unit connected by a five-membered ring.

Synthesis Reference(s)

Journal of the American Chemical Society, 72, p. 4786, 1950 DOI: 10.1021/ja01166a124
Tetrahedron Letters, 33, p. 1675, 1992 DOI: 10.1016/S0040-4039(00)91703-9

General Description

Light yellow fine crystals.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

Vigorous reactions, sometimes amounting to explosions, can result from the contact between aromatic hydrocarbons, such as Fluoranthene, and strong oxidizing agents. They can react exothermically with bases and with diazo compounds. Substitution at the benzene nucleus occurs by halogenation (acid catalyst), nitration, sulfonation, and the Friedel-Crafts reaction.

Hazard

Questionable carcinogen.

Health Hazard

ACUTE/CHRONIC HAZARDS: When heated to decomposition Fluoranthene emits acrid smoke and fumes.

Health Hazard

Fluoranthene exhibited mild oral and dermaltoxicity in animals. The acute toxicity is lowerthan that of phenanthrene. An oral LD50 valuein rats is reported as 2000 mg/kg. It may causeskin tumor at the site of application. However,any carcinogenic action from this compoundin animals is unknown..

Fire Hazard

Flash point data for Fluoranthene are not available. Fluoranthene is probably combustible.

Safety Profile

Poison by intravenous route. Moderately toxic by ingestion and skin contact. Questionable carcinogen with experimental tumorigenic data. Human mutation data reported. Combustible when exposed to heat or flame. When heated to decomposition it emits acrid smoke and irritating fumes.

Potential Exposure

Fluoranthene, a PAH, is produced from the pyrolytic processing of organic raw materials, such as coal and petroleum at high temperatures. It is also known to occur naturally as a product of plant biosynthesis. Fluoranthene is ubiquitous in the environment and has been detected in United States air; in foreign and domestic drink ing waters and in food-stuffs. It is also contained in ciga rette smoke. Individuals living in areas which are heavily industrialized; and in which large amounts of fossil fuels are burned, would be expected to have greatest exposure from ambient sources of fluoranthene. In addition, certain occupations e.g., coke oven workers, steelworkers, roofers, automobile mechanics) would also be expected to have elevated levels of exposure relative to the general popula tion. Exposure to fluoranthene will be considerably increased among tobacco smokers or those who are exposed to smokers in closed environments (i.e., indoors).

Source

Detected in 8 diesel fuels at concentrations ranging from 0.060 to 13 mg/L with a mean value of 0.113 mg/L (Westerholm and Li, 1994); in a distilled water-soluble fraction of used motor oil at a concentration range of 1.3 to 1.5 μg/L (Chen et al., 1994). Lee et al. (1992) reported concentration ranges 1.50-125 mg/L and ND-0.5 μg/L in diesel fuel and the corresponding aqueous phase (distilled water), respectively (Lee et al., 1992). Schauer et al. (1999) reported fluoranthene in a diesel-powered medium-duty truck exhaust at an emission rate of 53.0 μg/km. Identified in Kuwait and South Louisiana crude oils at concentrations of 2.9 and 5.0 ppm, respectively (Pancirov and Brown, 1975).
California Phase II reformulated gasoline contained fluoranthene at a concentration of 1.15 g/kg. Gas-phase tailpipe emission rates from gasoline-powered automobiles with and without catalytic converters were approximately 4.25 and 160 μg/km, respectively (Schauer et al., 2002).
Detected in groundwater beneath a former coal gasification plant in Seattle, WA at a concentration of 50 μg/L (ASTR, 1995). The concentration of fluoranthene in coal tar and the maximum concentration reported in groundwater at a mid-Atlantic coal tar site were 6,500 and 0.015 mg/L, respectively (Mackay and Gschwend, 2001). Based on laboratory analysis of 7 coal tar samples, fluoranthene concentrations ranged from 1,500 to 13,000 ppm (EPRI, 1990).Lehmann et al. (1984) reported fluoranthene concentrations of 64.7 mg/g in a commercial anthracene oil and 17,400 to 30,900 mg/kg in three high-temperature coal tars. Identified in hightemperature coal tar pitches used in roofing operations at concentrations ranging from 5,200 to 38,800 mg/kg (Arrendale and Rogers, 1981).
Fluoranthene was detected in soot generated from underventilated combustion of natural gas doped with toluene (3 mole %) (Tolocka and Miller, 1995). Fluoranthene was also detected in 9 commercially available creosote samples at concentrations ranging from 55,000 to 120,000 mg/kg (Kohler et al., 2000).
Detected in asphalt fumes at an average concentration of 20.48 ng/m3 (Wang et al., 2001). An impurity in commercial available pyrene (Marciniak, 2002).
Schauer et al. (2001) measured organic compound emission rates for volatile organic compounds, gas-phase semi-volatile organic compounds, and particle-phase organic compounds from the residential (fireplace) combustion of pine, oak, and eucalyptus. The respective gas-phase and particle-phase emission rates of fluoranthene were 3.05 and 3.95 mg/kg of pine burned, 3.61 and 1.20 mg/kg of oak burned, and 3.75 and 0.509 mg/kg of eucalyptus burned.

Solubility in organics

In benzene expressed as mole fraction: 0.2174 at 44.8 °C, 0.3011 at 56.0 °C, 0.3826 at 64.4 °C, 0.5331 at 77.2 °C (shake flask-gravimetric, McLaughlin and Zainal, 1959)
In millimole fraction at 25 °C: 14.76 in n-hexane, 18.70 in n-heptane, 22.60 in n-octane, 26.42 in n-nonane, 30.15 in n-decane, 50.46 in n-hexadecane, 18.07 in cyclohexane, 21.79 in methylcyclohexane, 30.11 in cyclooctane, 11.62 in 2,2,4-trimethylpentane, 24.82 in tert-butyl-cyclohexane, 51.77 in dibutyl ether, 47.55 in methyl tert-butyl ether, 2.67 in methanol, 5.44 in ethanol, 6.70 in 1-propanol, 4.75 in 2-propanol, 9.96 in 1-butanol, 7.02 in 2-butanol, 4.95 in 2- methyl-1-propanol, 14.46 in 1-pentanol, 19.86 1-hexanol, 25.24 in 1-heptanol, 31.25 in 1- octanol, 10.21 in 2-pentanol, 8.62 in 3-methyl-1-butanol, 9.70 in 2-methyl-2-butanol, 17.72 in cyclopentanol, 17.82 in 2-ethyl-1-hexanol, 11.72 in 2-methyl-1-pentanol, 0.948 in 4-methyl-2- pentanol (Hernández and Acree, 1998)

Shipping

UN1325 Flammable solids, organic, n.o.s., Hazard Class: 4.1; Labels: 4.1-Flammable solid.UN3077 Environmentally hazardous substances, solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required.

Purification Methods

Fluoranthene (benzo[j,k]fluorene) M 202.3, m 110-111o, b 384o/760mm. Purify it by chromatography of CCl4 solutions on alumina, with *benzene as eluent. Crystallise it from EtOH, MeOH or *benzene. Also purify it by zone melting. [Gorman et al. J Am Chem Soc 107 4404 1985, Beilstein 5 I 344, 5 IV 2463.]

Incompatibilities

Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explo sions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. Compound can react exo thermically with bases and with diazo compounds. Substitution at the benzene nucleus occurs by halogenation (acid catalyst), nitration, sulfonation, and the Friedel Crafts reaction.

Waste Disposal

Dissolve or mix the material with a combustible solvent and burn in a chemical incinera tor equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed. Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≥100 kg/mo) must con form with EPA regulations governing storage, transportation, treatment, and waste disposal.

Fluoranthene Preparation Products And Raw materials

Raw materials

Preparation Products


Fluoranthene Suppliers

Global( 188)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
Springchem New Material Technology Co.,Limited
+8613917661608 +86-021-62885108
info@spring-chem.com China 2064 57
Henan DaKen Chemical CO.,LTD.
+86-371-66670886
info@dakenchem.com China 20903 58
Henan Tianfu Chemical Co.,Ltd.
0371-55170693
0371-55170693 info@tianfuchem.com CHINA 22607 55
career henan chemical co
+86-371-86658258
sales@coreychem.com CHINA 29954 58
Xiamen AmoyChem Co., Ltd
+86 592-605 1114
sales@amoychem.com CHINA 6369 58
Hubei xin bonus chemical co. LTD
86-13657291602
027-59338440 linda@hubeijusheng.com CHINA 23035 58
Shandong chuangyingchemical Co., Ltd.
18853181302
sale@chuangyingchem.com CHINA 5917 58
Chongqing Chemdad Co., Ltd
+86-13650506873
sales@chemdad.com CHINA 37282 58
Zhuozhou Wenxi import and Export Co., Ltd
+8613111626072 (WhatsApp)
Wechat: +8613111626072 Wickr me: waynehu zzwenxi@126.com CHINA 13187 58
Zhengzhou Alfa Chemical Co.,Ltd
+8613343822234 +86-0371-55052911
sales5@alfachem.cn;sales9@alfachem.cn;sale1@alfachem.cn China 11995 58

View Lastest Price from Fluoranthene manufacturers

Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2021-07-13 Fluoranthen
206-44-0
US $15.00-10.00 / KG 1KG 99%+ HPLC Monthly supply of 1 ton Zhuozhou Wenxi import and Export Co., Ltd
2021-07-09 Fluoranthen
206-44-0
US $15.00-10.00 / KG 1KG 99%+ HPLC Monthly supply of 1 ton Zhuozhou Wenxi import and Export Co., Ltd
2019-07-06 Fluoranthene
206-44-0
US $1.00 / KG 1KG 98% 1 career henan chemical co

Fluoranthene Spectrum


206-44-0(Fluoranthene)Related Search:


Copyright 2017 © ChemicalBook. All rights reserved