ストロンチウムオキシド 化学特性,用途語,生産方法
解説
酸化ストロンチウムSrO(103.62).ストロンチアともいう.ストロンチウムの炭酸塩,水酸化物,硝酸塩を強熱して得られる.無色の粉末.融点2430 ℃,沸点約3000 ℃.密度4.7 g cm-3.水に溶かすとはげしく反応して水酸化ストロンチウムを生じる.脱水剤,花火(赤色),顔料,せっけん,グリース,電子材料,ストロンチウム塩の製造,医薬品の製造原料などに用いられる.
説明
Strontium Oxide, SrO, is a metal oxide usually produced by the reaction of strontium with oxygen. It can also be prepared by the decomposition of heated strontium carbonate, hydroxide, or nitrate and is used in manufacturing other strontium salts, in pigments, soaps and greases, and as a drying agent. It is commonly used in the glass, ceramics, and electronic industries and has other specific uses, such as fuel cells and sputtering target material. If burn strontium under general conditions with air, strontium oxide and strontium nitride will form. Strontium oxide was once required by law as the material used on old TV face-plates to block harmful X-ray emissions. BaO and SrO were reported for the transesterification of palm oil for the production of biodiesel. The reaction was conducted under ultrasound conditions to ensure the effective production of biodiesel.
化学的特性
white to grayish white; reacts with water, forming Sr(OH)2, with evolution of heat; enthalpy of fusion 75.00kJ/mol [MER06] [CRC10]
物理的性質
Strontium oxide
or strontia, SrO, is formed when Sr metal reacts with
oxygen:
2Sr+ O2→2SrO
Burning strontium in air results in a mixture of strontium
oxide and strontium nitride. It also forms from the
decomposition of strontium carbonate SrCO3. It is
a strongly basic oxide. It reacts
with moisture forming the hydroxide and with carbon
dioxide in the air to form the carbonate.
使用
SrO is also used in medicine, pyrotechnics, pigments, greases, soaps, and as a chemical intermediate. It is also produced as high-purity strontium oxide rotatable sputtering targets with the highest possible density and smallest possible average grain sizes for use in semiconductor, photovoltaic, and coating applications by chemical vapor deposition and physical vapor deposition and optical applications.One of the reasons why rare metals are restrained from wide use in production is their high cost.
参考文献
W. Gerlach, Z. Physik, 9, 184 (1922), DOI: 10.1007/BF01326966.
ストロンチウムオキシド 上流と下流の製品情報
原材料
準備製品