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ジオキソチタン(IV)

ジオキソチタン(IV) 化学構造式
13463-67-7
CAS番号.
13463-67-7
化学名:
ジオキソチタン(IV)
别名:
ジオキソチタン(IV);C.I.ピグメントホワイト6;チタニア;酸化チタン(IV);チタン(IV)ジオキシド;二酸化チタン;酸化チタン;酸化チタン(Ⅳ),アナターゼ型;酸化チタン(Ⅳ),ルチル型;ピグメント ホワイト6;二酸化チタン(Ⅳ);酸化チタン(ナノ粒子);酸化チタン(ナノ粒子以外);酸化チタン, AEROXIDER P25;酸化チタンナノ粒子 RM5711‐A;酸化チタンナノ粒子 RM5712‐A;酸化チタンナノ粒子 RM5713‐A;酸化チタン(IV) PURISS.,MEETS ANALYTICAL SPECIFICATION OF PH. EUR.,BP,USP,99-100.5%;酸化チタン(Ⅳ)(アナターゼ型);酸化チタン(Ⅳ)(ルチル型)
英語化学名:
Titanium dioxide
英語别名:
p25;ro2;TIO2;Ti02;e171;r680;kh360;rayox;RUTILE;kronos
CBNumber:
CB0461627
分子式:
O2Ti
分子量:
79.8658
MOL File:
13463-67-7.mol

ジオキソチタン(IV) 物理性質

融点 :
1840 °C
沸点 :
2900 °C
比重(密度) :
4.26 g/mL at 25 °C(lit.)
屈折率 :
2.61
闪点 :
2500-3000°C
貯蔵温度 :
-20°C
溶解性:
Practically insoluble in water. It does not dissolve in dilute mineral acids but dissolves slowly in hot concentrated sulfuric acid.
外見 :
powder
色:
White to slightly yellow
PH:
7-8 (100g/l, H2O, 20℃)(slurry)
水溶解度 :
insoluble
Merck :
14,9472
CAS データベース:
13463-67-7(CAS DataBase Reference)
NISTの化学物質情報:
Titanium dioxide(13463-67-7)
EPAの化学物質情報:
Titanium oxide (TiO2)(13463-67-7)
安全性情報
  • リスクと安全性に関する声明
  • 危険有害性情報のコード(GHS)
主な危険性  Xn,Xi,C
Rフレーズ  20-36/37/38-20/21/22-38-20/21-10-36/38-22-36-34-40
Sフレーズ  26-36-25-2-36/37-45-36/37/39
RIDADR  UN2920 - class 8 - PG 2 - EHS - basic - Corrosive liquids, flammable, n.o.s., HI: all
WGK Germany  -
RTECS 番号 XR2275000
TSCA  Yes
HSコード  28230000
有毒物質データの 13463-67-7(Hazardous Substances Data)
毒性 LD50 orally in Rabbit: > 10000 mg/kg
絵表示(GHS)
注意喚起語 Danger
危険有害性情報
コード 危険有害性情報 危険有害性クラス 区分 注意喚起語 シンボル P コード
H226 引火性の液体および蒸気 引火性液体 3 警告
H302 飲み込むと有害 急性毒性、経口 4 警告 P264, P270, P301+P312, P330, P501
H304 飲み込んで気道に侵入すると生命に危険のおそ れ 吸引性呼吸器有害性 1 危険
H314 重篤な皮膚の薬傷?眼の損傷 皮膚腐食性/刺激性 1A, B, C 危険 P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H318 重篤な眼の損傷 眼に対する重篤な損傷性/眼刺激 性 1 危険 P280, P305+P351+P338, P310
H335 呼吸器への刺激のおそれ 特定標的臓器毒性、単回暴露; 気道刺激性 3 警告
H351 発がんのおそれの疑い 発がん性 2 警告 P201, P202, P281, P308+P313, P405,P501
H373 長期にわたる、または反復暴露により臓器の障 害のおそれ 特定標的臓器有害性、単回暴露 2 警告 P260, P314, P501
注意書き
P201 使用前に取扱説明書を入手すること。
P202 全ての安全注意を読み理解するまで取り扱わないこ と。
P210 熱/火花/裸火/高温のもののような着火源から遠ざ けること。-禁煙。
P260 粉じん/煙/ガス/ミスト/蒸気/スプレーを吸入しないこ と。
P280 保護手袋/保護衣/保護眼鏡/保護面を着用するこ と。
P301+P310 飲み込んだ場合:直ちに医師に連絡すること。
P305 眼に入った場合:
P305+P351+P338 眼に入った場合:水で数分間注意深く洗うこと。次にコ ンタクトレンズを着用していて容易に外せる場合は外す こと。その後も洗浄を続けること。
P308+P313 暴露または暴露の懸念がある場合:医師の診断/手当てを 受けること。
P370+P378 火災の場合:消火に...を使用すること。
P405 施錠して保管すること。

ジオキソチタン(IV) 価格 もっと(49)

メーカー 製品番号 製品説明 CAS番号 包装 価格 更新時間 購入
富士フイルム和光純薬株式会社(wako) W01ALF010897 Titanium(IV) oxide, Puratronic®, 99.995% (metals basis)
Titanium(IV) oxide, Puratronic?, 99.995% (metals basis)
13463-67-7 10g ¥26100 2018-12-26 購入
富士フイルム和光純薬株式会社(wako) W01ALF010897 Titanium(IV) oxide, Puratronic®, 99.995% (metals basis)
Titanium(IV) oxide, Puratronic?, 99.995% (metals basis)
13463-67-7 50g ¥86100 2018-12-26 購入
関東化学株式会社(KANTO) 21358-3A 酸化チタン
Titanium(IV) oxide, anatase powder
13463-67-7 100g ¥3500 2018-12-13 購入
関東化学株式会社(KANTO) 21358-1A 酸化チタン
Titanium(IV) oxide, anatase powder
13463-67-7 1kg ¥9000 2018-12-13 購入
Sigma-Aldrich Japan 14027 酸化チタン(IV) puriss., meets analytical specification of Ph. Eur., BP, USP, 99-100.5%
Titanium(IV) oxide puriss., meets analytical specification of Ph. Eur., BP, USP, 99-100.5%
13463-67-7 250g ¥8000 2018-12-25 購入

ジオキソチタン(IV) MSDS


Titania

ジオキソチタン(IV) 化学特性,用途語,生産方法

化学的特性

The naturally occurring dioxide exists in three crystal forms: anatase, rutile and brookite. While rutile, the most common form, has an octahedral structure. Anatase and brookite have very distorted octahedra of oxygen atoms surrounding each titanium atom. In such distorted octahedral structures, two oxygen atoms are relatively closer to titanium than the other four oxygen atoms. Anatase is more stable than the rutile form by about 8 to 12 kJ/mol (Cotton, F.A., Wilkinson, G., Murillo, C.A and M Bochmann. 1999. Advanced Inorganic Chemistry, 6th ed, p. 697, New York: John Wiley & Sons) Other physical properties are: density 4.23g/cm3; Mohs hardness 5.8 g/cm3 ( anatase and brookite) and 6.2 g/cm3 ( rutile); index of refraction 2.488 (anatase), 2.583 (brookite) and 2.609 (rutile); melts at 1,843°C; insoluble in water and dilute acids; soluble in concentrated acids.

化学的特性

Ttitanium dioxide is an odorless white powder.

使用

titanium dioxide (TiO2) is one of the 21 FDA-approved sunscreen chemicals with an approved usage level of 2 to 25 percent. When applied, titanium dioxide remains on the skin’s surface, scattering uV light. It is often used in conjunction with other sunscreen chemicals to boost the product’s SPF value, thus reducing the risk of irritation or allergies attributed to excessive usage of chemical sunscreens. Its incorporation into sunscreen formulations, makeup bases, and daytime moisturizers depends on the particular size of titanium dioxide employed. The smaller the particle size, the more unobtrusive Tio2’s application. Large particles, on the other hand, leave a whitish wash or look on the skin. Some companies list “micro” or “ultra” when referring to the size of the titanium dioxide particle. According to some sources, titanium dioxide could be the ideal uVA/uVB protection component given its chemical, cosmetic, and physical characteristics. Titanium dioxide is also used to provide a white color to cosmetic preparations.

使用

Titanium Dioxide is a white pigment that disperses in liquids and possesses great opacifying power. the crystalline modifications of titanium dioxide are rutile and anatase, of which only anatase finds use as a color additive.

使用

Titanium dioxide is an extreme white and bright compound with high index of refraction. In paints it is a white pigment and an opacifying agent.It is in house paints, water paints, lacquers, enamels, paper filling and coating, rubber, plastics, printing ink, synthetic fabrics, floor coverings, and shoe whiteners. Also, it is used in colorants for ceramics and coatings for welding rods. A rutile form of the dioxide is used in synthetic gem stones.

主な応用

Industry Application Role/benefit
Pigment Optical coating for dielectric mirrors and gemstones Brightness and very high refractive index
Paper coating Helps to make paper whiter, brighter and more opaque
Plastics, adhesives and rubber Helps minimize the brittleness, fading and cracking that can occur as a result of light exposure
Food Contact materials and ingredients Prevents premature degradation and enhance the longevity of the product
Paints Gives paint its high gloss and rich depth of color
Ceramic glazes Acts as an opacifier and seeds crystal formation
Cosmetic Sunscreens Active ingredients/high refractive index and strong UV light absorbing capabilities
Daily cosmetics or make-up materials Additive/aids in hiding blemishes and brightening the skin
Toothpastes Additive/helps to whiten tooth
Catalyst Dye-sensitized solar cell Can produce electricity in nanoparticle form
Hydrolysis reaction Catalyzes the photo decomposition of water into hydrogen and oxygen
Automotive, power stations, etc. Helps to removes harmful exhaust gas emissions, such as nitrous oxides, volatile organic compounds, etc.
Detoxification or remediation of wastewater Photocatalytically mineralizes pollutants (to convert into CO2 and H2O) in waste water
Photocatalytic antimicrobial coating Photocatalytic destruction of organic matter
Others Oxygen sensor The electrical resistivity of TiO2 can be correlated to the oxygen content of the atmosphere
Anti-fogging coatings and self-cleaning windows Under exposure to UV light, TiO2 becomes increasingly hydrophilic
Coated ceramic tile Disinfectant and self-cleaning qualities
Treatment of the air in fruit, vegetable and cut flower storage areas Removes ethylene gas to prevent spoilage and prevents internal combustion
Memristor Can be employed for solar energy conversion
Mixed conductor Significant ionic and electronic conduction

使用

Airfloated ilmenite is used for titanium pigment manufacture. Rutile sand is suitable for welding-rod-coating materials, as ceramic colorant, as source of titanium metal. As color in the food industry. Anatase titanium dioxide is used for welding-rod-coatings, acid resistant vitreous enamels, in specification paints, exterior white house paints, acetate rayon, white interior air-dry and baked enamels and lacquers, inks and plastics, for paper filling and coating, in water paints, tanners' leather finishes, shoe whiteners, and ceramics. High opacity and tinting values are claimed for rutile-like pigments.

製造方法

Titanium dioxide is mined from natural deposits. It also is produced from other titanium minerals or prepared in the laboratory. Pigment-grade dioxide is produced from the minerals, rutile and ilmenite. Rutile is converted to pigment grade rutile by chlorination to give titanium tetrachloride, TiCl4. Anhydrous tetrachloride is converted back to purified rutile form by vapor phase oxidation.
Anatase form is obtained by hydrolytic precipitation of titanium(IV) sulfate on heating. The mineral ilmenite is treated with concentrated sulfuric acid. Heating the sulfate solution precipitates hydrous titanium oxide. The precipitate is calcined to expel all water.
Titanium dioxide also can be prepared by heating Ti metal in air or oxygen at elevated temperatures.

主な用途/役割

ポリウレタン系接着剤に使用される。

危険性

Lower respiratory tract irritant. Possible carcinogen.

安全性プロファイル

A nuisance dust. A human skin irritant. Questionable carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data. Violent or incandescent reaction with metals at high temperatures (e.g., aluminum, calcium, magnesium, potassium, sodium, zinc, lithium). See also TITANIUM COMPOUNDS.

職業ばく露

Titanium dioxide is a white pigment used as a pigment in paint; in the rubber, plastics, ceramics, paint, and varnish industries, in dermatological preparations; and is used as a starting material for other titanium compounds; as a gem; in curing concrete; and in coatings for welding rods. It is also used in paper and cardboard manufacture.

応急処置

If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 minutes, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medical attention. Give large quantities of water and induce vomiting. Do not make an unconscious person vomit.

不和合性

Titanium dioxide is incompatible with strong oxidizers and strong acids. Violent or incandescent reactions may occur with metals (e.g., aluminum, calcium, magnesium, potassium, sodium, zinc, and lithium).

廃棄物の処理

Land fill.

用途

塗料?印刷インキ?インクジェットインキ?プラスチックの着色顔料,化粧品?シリコーンゴム?プラスチック繊維?磁気テープ?トナー?セラミックスなどの配合原料 (NITE CHRIP)

定義

本品は、チタンの酸化物であり、次の化学式で表される。

化粧品の成分用途

不透明化剤、褪色防止剤、着色剤、紫外線吸収剤.散乱剤

ジオキソチタン(IV) 上流と下流の製品情報

原材料

準備製品


ジオキソチタン(IV) 生産企業

Global( 287)Suppliers
名前 電話番号 ファックス番号 電子メール 国籍 製品カタログ 優位度
Hebei Huanhao Biotechnology Co., Ltd.
86-0311-83975816
86-0311-83975816 lisa@hbhuanhao.com CHINA 606 58
Shenzhen Sendi Biotechnology Co.Ltd.
0755-23311925 18102838259
0755-23311925 Abel@chembj.com CHINA 3218 55
Henan DaKen Chemical CO.,LTD.
+86-371-55531817
info@dakenchem.com CHINA 22059 58
Aoxuan Biological Technology Co., Ltd.
17073140108
- CHINA 147 55
Henan Tianfu Chemical Co.,Ltd.
0371-55170693
0371-55170693 info@tianfuchem.com CHINA 20795 55
Mainchem Co., Ltd.
+86-0592-6210733
+86-0592-6210733 sales@mainchem.com CHINA 32764 55
Hefei TNJ Chemical Industry Co.,Ltd.
86-0551-65418684 18949823763
86-0551-65418684 info@tnjchem.com China 1582 55
hebei chisure biotechnology co.,ltd
0311 66567340
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career henan chemical co
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Hebei Ruishun Trade Co.,LTD
86-311-66111018
86-311-66111018 Mike@rsbiology.com CHINA 300 58

13463-67-7(ジオキソチタン(IV))キーワード:


  • 13463-67-7
  • HoMbikat catalyst grade (for rearrangeMent reactions)
  • TitaniuM(IV) oxide nanopowder, 21 nM particle size (TEM), >=99.5% trace Metals basis
  • TitaniuM(IV) oxide, Mixture of rutile and anatase nanoparticles, <150 nM particle size (voluMe distribution, DLS), dispersion, 33-37 wt. % in H2O, 99.5% trace Metals basis
  • TitaniuM(IV) oxide, Mixture of rutile and anatase nanopowder, <100 nM particle size (BET), 99.5% trace Metals basis
  • Aeroxide? P25
  • Titania nanofibers
  • Titania nanowires
  • Titanium dioxide nanofibers
  • Titanium dioxide nanowires
  • Titanium(IV) oxide nanofibers
  • Tiona Titanium dioxide
  • 25 kDa α-2-microglobulin-related subunit of MMP-9
  • Lipocalin-2
  • Lipocalin-2 human
  • Oncogene 24p3
  • Titanium Dioxide (2 g)
  • Dioxide R902+
  • Titanium dioxide nanotubes 25 nm average diameter, powder
  • Titanium(IV) oxide contains 1% Mn as dopant, nanopowder, <100 nm particle size (BET), >=97%
  • Titanium(IV) oxide nanopowder, 21 nm primary particle size (TEM), >=99.5% trace metals basis
  • Titanium(IV) oxide nanowires, diam. x L ~10 nm x 10 mum
  • Titanium(IV) oxide nanowires, diam. x L ~100 nm x 10 mum
  • Titanium(IV) oxide puriss., meets analytical specification of Ph. Eur., BP, USP, 99-100.5%
  • Titanium(IV) oxide ReagentPlus(R), >=99%
  • Titanium Dioxide cas no:13463-67-7 high purity factory price TITANIUM DIOXIDE {TiO2} RUTILE email:vivian@xtlandi.com
  • Titanium Dioxide titanium dioxide Tio2
  • Titanium(IV) oxide nanopowder, 99.9%, anatase, particle size: 10 - 25 nm, SSA: 30 m2/g
  • Titanium(IV) oxide nanopowder, 99.9%, particle size: 20 nm, SSA: 30 m2/g
  • Titanium Dioxide Anatase CAS: 13463-67-7
  • TITANIUM DIOXIDE, RUTILE FORM
  • ジオキソチタン(IV)
  • C.I.ピグメントホワイト6
  • チタニア
  • 酸化チタン(IV)
  • チタン(IV)ジオキシド
  • 二酸化チタン
  • 酸化チタン
  • 酸化チタン(Ⅳ),アナターゼ型
  • 酸化チタン(Ⅳ),ルチル型
  • ピグメント ホワイト6
  • 二酸化チタン(Ⅳ)
  • 酸化チタン(ナノ粒子)
  • 酸化チタン(ナノ粒子以外)
  • 酸化チタン, AEROXIDER P25
  • 酸化チタンナノ粒子 RM5711‐A
  • 酸化チタンナノ粒子 RM5712‐A
  • 酸化チタンナノ粒子 RM5713‐A
  • 酸化チタン(IV) PURISS.,MEETS ANALYTICAL SPECIFICATION OF PH. EUR.,BP,USP,99-100.5%
  • 酸化チタン(Ⅳ)(アナターゼ型)
  • 酸化チタン(Ⅳ)(ルチル型)
  • 酸化チタン(IV) .ルチル型
  • TITANIUM(IV) OXIDE, PURATRONIC®, 99.995% (METALS BASIS)
  • 酸化チタン(IV), 80NM
  • 酸化チタン「製造専用」
  • 二酸化チタン、ナノチューブ
  • 酸化チタン(IV)、ルチル型/アナターゼ型混合物
  • 酸化チタン( Ⅳ) アナターゼ型
  • 酸化チタン( Ⅳ) ルチル型
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