プロペン酸3,3,4,4,5,5,6,6,6-ノナフルオロヘキシル

プロペン酸3,3,4,4,5,5,6,6,6-ノナフルオロヘキシル 化学構造式
52591-27-2
CAS番号.
52591-27-2
化学名:
プロペン酸3,3,4,4,5,5,6,6,6-ノナフルオロヘキシル
别名:
3,3,4,4,5,5,6,6,6-ノナフルオロヘキサン-1-イル=アクリラート;アクリル酸2-(ノナフルオロブチル)エチル;アクリル酸3,3,4,4,5,5,6,6,6-ノナフルオロヘキシル;アクリル酸=3,3,4,4,5,5,6,6,6-ノナフルオロヘキシル;プロペン酸3,3,4,4,5,5,6,6,6-ノナフルオロヘキシル;3,3,4,4,5,5,6,6,6-ノナフルオロヘキシルアクリラート;アクリル酸2-(パーフルオロブチル)エチル;アクリル酸1H,1H,2H,2H-ノナフルオロヘキシル;アクリル酸 3,3,4,4,5,5,6,6,6-ノナフルオロヘキシル
英語名:
2-(Perfluorobutyl)ethyl acrylate
英語别名:
TEAc-4;DAIKIN R-1420;Perfluorobutylethyl acrylate;2-(Perfluorobutyl)ethyl acrylate;1H,1H,2H,2H-Nonafluorohexyl acrylate;1H,1H,2H,2H-Perfluorohexyl acrylate 97%;3,3,4,4,5,5,6,6,6-Nonafluorohexylacrylate;3,3,4,4,5,5,6,6,6-Nonafluorohexyl acrylate;Acrylic acid 2-(nonafluorobutyl)ethyl ester;Acrylic Acid 1H,1H,2H,2H-Nonafluorohexyl Ester
CBNumber:
CB9485109
化学式:
C9H7F9O2
分子量:
318.14
MOL File:
52591-27-2.mol
MSDS File:
SDS

プロペン酸3,3,4,4,5,5,6,6,6-ノナフルオロヘキシル 物理性質

沸点 :
164 °C
比重(密度) :
1.414
屈折率 :
1.310
闪点 :
52 °C
貯蔵温度 :
Store at 2-8 ℃
溶解性:
Chloroform (Soluble), Ethyl Acetate (Slightly)
外見 :
clear liquid
色:
Colorless to Light yellow
比重:
1.440
EPAの化学物質情報:
1,1,2,2-Tetrahydroperfluorohexyl acrylate (52591-27-2)
安全性情報
  • リスクと安全性に関する声明
  • 危険有害性情報のコード(GHS)
RIDADR  UN 3272 3/PG III
国連危険物分類  3
容器等級  III
HSコード  2916120090
消防法 危-4-2-III
化審法 (2)-4056
絵表示(GHS) GHS hazard pictogramsGHS hazard pictograms
注意喚起語
危険有害性情報
コード 危険有害性情報 危険有害性クラス 区分 注意喚起語 シンボル P コード
H226 引火性の液体および蒸気 引火性液体 3 警告
H315 皮膚刺激 皮膚腐食性/刺激性 2 警告 GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 強い眼刺激 眼に対する重篤な損傷性/眼刺激 性 2A 警告 GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 呼吸器への刺激のおそれ 特定標的臓器毒性、単回暴露; 気道刺激性 3 警告 GHS hazard pictograms
注意書き
P210 熱/火花/裸火/高温のもののような着火源から遠ざ けること。-禁煙。
P280 保護手袋/保護衣/保護眼鏡/保護面を着用するこ と。

プロペン酸3,3,4,4,5,5,6,6,6-ノナフルオロヘキシル 価格 もっと(16)

メーカー 製品番号 製品説明 CAS番号 包装 価格 更新時間 購入
富士フイルム和光純薬株式会社(wako) W01MAS005258 アクリル酸2-(パーフルオロブチル)エチル
2-(Perfluorobutyl)ethyl acrylate
52591-27-2 1g ¥6400 2024-03-01 購入
富士フイルム和光純薬株式会社(wako) W01COBQI-0829 アクリル酸2-(パーフルオロブチル)エチル
2-(Perfluorobutyl)ethyl acrylate
52591-27-2 5g ¥35000 2024-03-01 購入
富士フイルム和光純薬株式会社(wako) W01COBQI-0829
2-(Perfluorobutyl)ethyl acrylate
52591-27-2 25g×4 ¥292500 2024-03-01 購入
富士フイルム和光純薬株式会社(wako) W01APOPC5906D
3,3,4,4,5,5,6,6,6-Nonafluorohex-1yl acrylate
52591-27-2 1g ¥33600 2024-03-01 購入
富士フイルム和光純薬株式会社(wako) W01APOPC5906D
3,3,4,4,5,5,6,6,6-Nonafluorohex-1yl acrylate
52591-27-2 5g ¥62400 2024-03-01 購入

プロペン酸3,3,4,4,5,5,6,6,6-ノナフルオロヘキシル 化学特性,用途語,生産方法

外観

無色~うすい黄色透明液体

使用

2-(Perfluorobutyl)ethyl Acrylate can be used as an acrylic resin surface modifier with high water repellency and oil repellency for coating agents. It can also be used in a super concentrated emulsion method to prepare a solid sheet polycarboxylic acid water reducing agent.

主な応用

2-(Perfluorobutyl)ethyl acrylate has been used in a wide range of scientific research applications. It has been used to create polymers for biomedical applications, such as drug delivery systems and tissue engineering scaffolds. It has also been used to create polymers for industrial applications, such as coatings and adhesives. In addition, it has been used to create polymers for energy applications, such as fuel cells and solar cells.

合成

説明図
1H,1H,2H,2H-nonafluoro-1-hexanol (52.8 g) as fluoro alcohol and triethylamine (50 g) were dissolved in 500 ml of tetrahydrofuran. A solution of 18.1 g of acryloyl chloride as acid chloride in 100 ml of tetrahydrofuran was dropped in this solution over 2 hours while the mixture was being cooled in ice and stirred. After the completion of the dropping, the resulting white precipitate was filtrated and tetrahydrofuran and triethylamine were removed from the filtrate using a rotary evaporator. NMR measurement revealed that the resulting compound was 1H,1H,2H,2H-nonafluorohexyl acrylate.

Research

Since the bioaccumulation of the degradation products of fluoropolymer with a long Rf side chain (C ≥ 8) has a potential environmental risk, it is necessary to design fluoropolymer coating with a short Rf side chain. Honda et al. studied the effect of α-substituent on the wetting behavior and molecular motion at the surfaces of poly{2-(perfluorobutyl)ethyl acrylate} [PFA-C4], poly{2-(perfluorobutyl)ethyl methacrylate} [PFMA-C4], poly{2-(perfluorobutyl)ethyl α-fluoroacrylate} [PFFA-C4], and poly{2-(perfluorobutyl)ethyl α-chloroacrylate} [PFClA-C4] films. In the case of PFA-Cy with long Rf groups [y ≥ 8], the mobility of the side chains is low at room temperature because of the crystallization of the Rf groups at the surface region[1].

プロペン酸3,3,4,4,5,5,6,6,6-ノナフルオロヘキシル 上流と下流の製品情報

原材料

準備製品


プロペン酸3,3,4,4,5,5,6,6,6-ノナフルオロヘキシル 生産企業

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52591-27-2(プロペン酸3,3,4,4,5,5,6,6,6-ノナフルオロヘキシル)キーワード:


  • 52591-27-2
  • 1H,1H,2H,2H-Nonafluorohexyl Acrylate (stabilized with TBC)
  • 1H,1H,2H,2H-Nonafluorohexyl Acrylate (stabilized with MEHQ)
  • Perfluorobutylethyl acrylate
  • 2-Propenoic acid 3,3,4,4,5,5,6,6,6-nonafluorohexyl ester
  • 3,3,4,4,5,5,6,6,6-Nonafluorohexyl acrylate
  • 3,3,4,4,5,5,6,6,6-Nonafluorohexylacrylate
  • Acrylic acid 2-(nonafluorobutyl)ethyl ester
  • Acrylic acid 3,3,4,4,5,5,6,6,6-nonafluorohexyl ester
  • Propenoic acid 3,3,4,4,5,5,6,6,6-nonafluorohexyl ester
  • 1H,1H,2H,2H-Perfluorohexyl acrylate 97%
  • 2-(Perfluorobut-1-yl)ethyl acrylate, 3,3,4,4,5,5,6,6,6-Nonafluorohex-1-yl prop-2-enoate, TEAc-4
  • DAIKIN R-1420
  • 1H,1H,2H,2H-Nonafluorohexyl acrylate
  • 2-(Perfluorobutyl)ethyl acrylate
  • 3,3,4,4,5,5,6,6,6-Nonafluorohex-1yl acrylate 97%
  • 1H,1H,2H,2H-Nonafluorohexyl Acrylate (stabilized with MEHQ)
  • 9-formyl-3-hydroxy-6-oxo-7-(1-oxopentyl)-1-pentyl-2-benzo[b][1,4]benzodioxepincarboxylic acid
  • 1H,1H,2H,2H-Nonafluorohexyl Acrylate (stabilized with MEHQ) >
  • 2-Propenoic acid,3,3,4,4,5,5,6,6,6-nonafluorohexyl ester,>98.0%(GC)
  • Acrylic Acid 1H,1H,2H,2H-Nonafluorohexyl Ester
  • TEAc-4
  • 3,3,4,4,5,5,6,6,6-ノナフルオロヘキサン-1-イル=アクリラート
  • アクリル酸2-(ノナフルオロブチル)エチル
  • アクリル酸3,3,4,4,5,5,6,6,6-ノナフルオロヘキシル
  • アクリル酸=3,3,4,4,5,5,6,6,6-ノナフルオロヘキシル
  • プロペン酸3,3,4,4,5,5,6,6,6-ノナフルオロヘキシル
  • 3,3,4,4,5,5,6,6,6-ノナフルオロヘキシルアクリラート
  • アクリル酸2-(パーフルオロブチル)エチル
  • アクリル酸1H,1H,2H,2H-ノナフルオロヘキシル
  • アクリル酸 3,3,4,4,5,5,6,6,6-ノナフルオロヘキシル
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