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Ferrocene

디시클로펜타디에닐 철 C화학적 특성, 용도, 생산

화학적 성질

Ferrocene, a metallocene, is a bright orange salt-like crystals from alcohol. Camphor odor.

물리적 성질

Orange crystals; camphor-like odor; melts at 172.5°C; vaporizes at 249°C; sublimes above 100°C; thermally stable above 500°C; insoluble in water; soluble in alcohol, ether and benzene; also soluble in dilute nitric acid and concentrated sulfuric acid forming a deep red solution that fluoresces.

용도

Ferrocene is used as a catalyst for vulcanization, acceleration, and polymerization, as a chemical intermediate for polymeric compounds such as high temperature polymers, as an antiknock additive for gasoline, as a coating for missiles and satellites, and as a high-temperature lubricant.

생산 방법

Ferrocene is produced from the reaction of cyclopentadiene with reduced iron in the presence of metal oxides. There is also a two-stage production process in which produced iron (II)oxide (stage 1) is reacted with cyclopentadiene.

정의

ferrocene: An orange-red crystallinesolid, Fe(C₅H₅)₂; m.p. 173°C. Itcan be made by adding the ioniccompound Na₊C₅H₅^- (cyclopentadienylsodium, made from sodium andcyclopentadiene) to iron(III) chloride.In ferrocene, the two rings are parallel,with the iron ion sandwiched betweenthem (hence the namesandwich compound: see formula).The bonding is between pi orbitalson the rings and d-orbitals on theFe²⁺ ion. The compound can undergoelectrophilic substitution on theC₅H₅rings (they have some aromatic character).It can also be oxidized to theblue ion (C₅H₅)₂Fe⁺. Ferrocene is the first of a class of similar complexescalled sandwich compounds. Its systematicname is di-π-cyclopentadienyliron(II).

제조 방법

Dicyclopentadienyliron may be obtained in a single-step synthetic route by heating cyclopentadiene with iron or iron pentacarbonyl at 300°C:
2C₅H₅ + Fe → (C₅H₅)₂Fe
Also, it can be prepared by the reaction of iron(II) chloride with cyclopentadiene in the presence of an alkyl amine or a similar base.
Another convenient method of preparing this π-complex of iron is a twostep process in which the first step involves preparation of cyclopentadienyl Grignard reagent, such as 2,4-cyclopentadienylmagnesium bromide C5H5MgBr which may then be combined with ferric chloride to yield dicyclopentadienyl iron:
3C₅H₅MgBr + FeCl₃ → (C₅H₅)₂Fe + 3MgBrCl
Another general method of preparation involves the reaction of cyclopentadiene with sodium metal or sodium hydride in tetrahydrofuran (THF). Addition of iron(II) chloride to this solution forms the complex dicyclopentadienyliron:
2C₅H₆ + 2Na → 2C₅H₅ˉ + 2Na+ + H₂
In 3:2 molar ratio of cyclopentadiene to sodium cyclopentene is obtained along with cyclopentadienidide (C₅H₅ˉ ) anion:
3C₅H₆ + 2Na → 2C5H5¯ + 2Na+ + C₅H₈
FeCl₂ + 2C5H₆Na → (C5H5)₂Fe + 2NaCl

일반 설명

Orange crystalline solid or orange-yellow powder. Sublimes above 212°F. Camphor odor.

공기와 물의 반응

Sensitive to prolonged exposure to air and may be sensitive to light. Insoluble in water.

반응 프로필

Ferrocene reacts violently with tetranitromethane. . Contact of tetranitromethane with Ferrocene under various conditions leads to violent explosion, [Trans. Met. Chem., 1979, 4, 207-208].

위험도

Moderate fire risk. Evolves toxic products on decomposition and heating.

건강위험

Dicyclopentadienyl iron causes changes in blood parameters and hepatic cirrhosis.
The toxicological properties of dicyclopentadienyl iron have not been extensively investigated. However, it has been used as a preventive and therapeutic iron deficiency drug, and its utilization is listed as tolerable.

화재위험

Flash point data for Ferrocene are not available. Ferrocene is probably combustible.

Safety Profile

Poison by intraperitoneal and intravenous routes. Moderately toxic by ingestion. Questionable carcinogen with experimental tumorigenic data. Mutation data reported. Flammable; reacts violently with NH4ClO4. When heated to decomposition it emits acrid smoke and irritating fumes.

잠재적 노출

Used as additive in fuel oil; antiknock agent in gasoline fuel; used in making rubber, silicone resins, high-temperature polymers and lubricants; interme diate for high-temperature polymers; as a smoke suppres sant and catalyst

Carcinogenicity

Ferrocene was administered by intramuscular injection at a dose of 5175 mg/kg/2 years. By the criterion established by the Registry of Toxic Effects of Chemical Substances (RTECS), ferrocene was an equivocal tumorigenic agent and tumors were most evident at the site of multiple injections.

운송 방법

UN1325 Flammable solids, organic, n.o.s., Hazard Class: 4.1; Labels: 4.1-Flammable solid.

Purification Methods

Purify it by crystallisation from pentane or cyclohexane (also *C6H6 or MeOH can be used). It is moderately soluble in Et2O and sublimes readily above 100o. Crystallisation from EtOH gave material m 172.5-173o. [Wilkinson Org Synth Coll Vol IV 473 1963, Miller J Chem Soc 632 1952.] It has also been crystallised from methanol and sublimed in vacuo. [Saltiel et al. J Am Chem Soc 109 1209 1987, Beilstein 16 IV 1783.]

비 호환성

Violent reaction with ammonium per chlorate, tetranitromethane, mercury(II) nitrate. Incompa tible with oxidizers (chlorates, nitrates, peroxides, perman ganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides.
Peroxomonosulfuric acid. Decomposes @≧465 ℃.

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공급자	전화	이메일	국가	제품 수	이점
Changyi Longchang Bio-Chemical Co., LTD	+86-13256193735; +8613256193735	sale01@longchangchemical.com	China	964	58
Dalian Richfortune Chemicals Co., Ltd	0411-84820922 8613904096939	sales@richfortunechem.com	China	304	57
SIMAGCHEM CORP	+86-13806087780	sale@simagchem.com	China	17367	58
Hebei Yanxi Chemical Co., Ltd.	+86-17531190177; +8617531190177	peter@yan-xi.com	China	6011	58
airuikechemical co., ltd.	+undefined86-15315557071	sales03@airuikechemical.com	China	983	58
Shijiazhuang Jianxin Biotechnology Co., LTD	+undefined+86-17692708569	liyingjian1997@gmail.com	China	711	58
Xiamen Eagle Chemical Limited Corporation	+86-5925023701 +86-18900207489	yiyunchem@163.com	China	6046	58
Hebei Weibang Biotechnology Co., Ltd	+8615350571055	Sibel@weibangbio.com	China	4822	58
Hebei Mojin Biotechnology Co., Ltd	+86 13288715578 +8613288715578	sales@hbmojin.com	China	12460	58
Hebei Guanlang Biotechnology Co,.LTD	+86-19930503253; +8619930503252	daisy@crovellbio.com	China	5840	58

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