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PMK ethyl glycidate

PMK ethyl glycidate 구조식 이미지

카스 번호:: 28578-16-7

상품명:: PMK ethyl glycidate

동의어(영문):: GLYCIDATE;ethyl 3-(1,3-benzodioxol-5-yl)-2-methyloxirane-2-carboxylate;Pmk Glycidate Oil;3,4-MDP-2-P intermediate;ethyl 3-(benzo[d][1,3]dioxol-5-yl)-2-methyloxirane-2-carboxylate;2-Oxiranecarboxylicacid, 3-(1,3-benzodioxol-5-yl)-2-Methyl-, ethyl ester;cheap 3,4-MDP-2P ethyl ester;3-(1,3-benzodioxol-5-yl)-2-Methyl-;PMK BMK;New PMK

CBNumber:: CB22731285

분자식:: C13H14O5

포뮬러 무게:: 250.25

MOL 파일:: 28578-16-7.mol

속성

안전

용도

공급 업체 132

PMK ethyl glycidate 속성

끓는 점: 327.8±42.0 °C(Predicted)

밀도: 1.302±0.06 g/cm3(Predicted)

용해도: DMF: 15 mg/ml; DMSO: 30 mg/ml; Ethanol: 10 mg/ml; PBS (pH 7.2): 1 mg/ml

InChI: InChI=1S/C13H14O5/c1-3-15-12(14)13(2)11(18-13)8-4-5-9-10(6-8)17-7-16-9/h4-6,11H,3,7H2,1-2H3

InChIKey: BRILFEZHPXQINW-UHFFFAOYSA-N

SMILES: O1C(C2=CC=C3OCOC3=C2)C1(C)C(OCC)=O

안전

PMK ethyl glycidate C화학적 특성, 용도, 생산

개요

PMK ethyl glycidate is an analytical reference standard categorized as a precursor in the synthesis of methylenedioxy phenethylamines and amphetamines, including 3,4-MDMA. This product is intended for research and forensic applications.

용도

NSC 195099 can be used as an analytical reference standard.

주요 응용

PMK methyl glycidate is applied as immediate precursors of 3,4-methylenedioxymethamphetamine.

Synthesis

To a solution of piperonal (1, 3.00 g, 19.9 mmol) in CH2Cl2 (100 mL) was added (carbethoxyethylidene)triphenylphosphorane (2,14.5 g, 40.0 mmol), and the reaction mixture was stirred for 24 h at room temperature. The mixture was then concentrated at reduced pressure, and the residue was purified by flash column chromatography on silica gel (hexanes/EtOAc,10:1) to afford olefin 3 (4.45 g, 95%) as a colorless oil: 1H NMR (400 MHz, CDCl3) d 7.58 (s, 1H), 6.92 (d, J = 1.7 Hz, 1H), 6.90 (dd, J = 7.9, 1.7 Hz, 1H), 6.82 (d, J = 8.0 Hz, 1H), 5.97 (s, 2H), 4.24 (q, J = 7.1 Hz, 2H), 2.10 (d, J = 1.6 Hz, 3H),1.33 (t, J = 7.1 Hz, 3H); 13C NMR (100 MHz, CDCl3) d 168.7,147.6, 138.3, 129.9, 126.9, 124.6, 109.5, 108.2, 101.2, 60.7, 14.3,1 4.0; IR (ATR, cm-1): 2981, 2902,1698, 1628, 1502, 1489,1442, 1258, 1224; HRMS (EI) m/z calcd for C13H14O4 (M+) 234.0892, found 234.0895.

Fig The synthetic step of PMK ethyl glycidate

PMK ethyl glycidate 준비 용품 및 원자재

원자재

ethyl (±)-2-bromopropionate 클로로(2-)프로피온산에틸에스테르

준비 용품

PMK ethyl glycidate 공급 업체

글로벌( 132)공급 업체

공급자	전화	이메일	국가	제품 수	이점
Hong Kong Excellence Biotechnology Co., Ltd.	+86-86-18838029171 +8618126314766	ada@sh-teruiop.com	China	893	58
Dorne Chemical Technology co. LTD	+86-13583358881 +86-18560316533	Ethan@dornechem.com	China	294	58
Shanghai Worldyang Chemical Co.,Ltd.	,+86-21-56795779; +8613651600618	sales@worldyachem.com	China	879	58
Zhejiang J&C Biological Technology Co.,Limited	+1-2135480471 +1-2135480471	sales@sarms4muscle.com	China	10523	58
Xiamen Wonderful Bio Technology Co., Ltd.	+8613043004613	Sara@xmwonderfulbio.com	China	305	58
Taiyuan CJ Trading Co., Ltd	+86-18536636121	anna@lianxuchemical.com	China	8	58
Shandong Hanjiang Chemical Co., Ltd	+86-0533-2066820 +8618369939125	hanson@sdhanjiang.com	China	1527	58
Nanjing Deda New Material Technology Co., Ltd	+8613223293093	bella@njdeda.com	China	81	58
Hebei Mojin Biotechnology Co., Ltd	+8613288715578	sales@hbmojin.com	China	12456	58
.GZ HONESTCHEM CO.,LTD	+86-15013270415	honestchemical@foxmail.com	China	247	58