트리플루오르클로로에틸렌
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트리플루오르클로로에틸렌 속성
- 녹는점
- −158 °C(lit.)
- 끓는 점
- −28.4 °C(lit.)
- 밀도
- 1,305 g/cm3
- 증기 밀도
- 4.13 (vs air)
- 증기압
- 612kPa at 25℃
- 굴절률
- 1.3800
- 인화점
- -28°C
- 수용성
- 380mg/L at 28℃
- InChI
- InChI=1S/C2ClF3/c3-1(4)2(5)6
- InChIKey
- UUAGAQFQZIEFAH-UHFFFAOYSA-N
- SMILES
- C(/Cl)(\F)=C(\F)/F
- LogP
- 1.65
- CAS 데이터베이스
- 79-38-9(CAS DataBase Reference)
안전
- 위험 및 안전 성명
- 위험 및 사전주의 사항 (GHS)
| 위험품 표기 | F+,Xn,T,F | ||
|---|---|---|---|
| 위험 카페고리 넘버 | 12-20/22 | ||
| 안전지침서 | 16-38 | ||
| 유엔번호(UN No.) | UN 1082 2.3 | ||
| WGK 독일 | 3 | ||
| RTECS 번호 | KV0525000 | ||
| 위험 참고 사항 | Flammable/Toxic | ||
| 위험 등급 | 2.3 | ||
| HS 번호 | 2903779010 | ||
| 유해 물질 데이터 | 79-38-9(Hazardous Substances Data) | ||
| 독성 | LD50 oral in mouse: 268mg/kg | ||
| 기존화학 물질 | KE-05922 |
트리플루오르클로로에틸렌 C화학적 특성, 용도, 생산
화학적 성질
Colorless gas; faint ethereal odor. Decomposes in water.용도
Intermediate, monomer for chlorotrifluoroethylene resins.제조 방법
Chlorotrifluoroethylene is prepared from ethylene by the following route:
Ethylene is treated with an excess of chlorine at 300-350??C in the presence of activated charcoal to give hexachloroethane. This product is then treated with hydrogen fluoride in the presence of antimony pentachloride to yield trichlorotrifluoroethane. Dechlorination in the liquid phase with zinc dust and ethanol results in the formation of chlorotrifluoroethylene which is washed with water to remove alcohol, dried and distilled under pressure.
일반 설명
Chlorotrifluoroethylene is a colorless gas with a faint ethereal odor. Chlorotrifluoroethylene is shipped as a liquefied gas under its vapor pressure. Chlorotrifluoroethylene is very toxic by inhalation and is easily ignited. The vapors are heavier than air and a flame can flash back to the source of leak very easily. This leak can either be a liquid or vapor leak. The vapors can asphyxiate by the displacement of air. Contact with the liquid can cause frostbite. Under prolonged exposure to intense heat or fire the containers may violently rupture and rocket, or the material may polymerize with possible container rupture.공기와 물의 반응
Highly flammable.반응 프로필
Halogenated aliphatic compounds, such as Chlorotrifluoroethylene, are moderately or very reactive. Reactivity generally decreases with increased degree of substitution of halogen for hydrogen atoms. Low molecular weight haloalkanes are highly flammable and can react with some metals to form dangerous products. Materials in this group are incompatible with strong oxidizing and reducing agents. Also, they are incompatible with many amines; nitrides; azo/diazo compounds; alkali metals; strong oxidizers such as chlorine perchlorate, oxygen, bromine; and epoxides.위험도
Dangerous fire risk. Flammable limits in air 8.4–38.7%.건강위험
Inhalation causes dizziness, nausea, vomiting; liver and kidney injury may develop after several hours and cause jaundice and necrosis of the kidney. Contact with liquid causes frostbite of eyes and possibly of skin.Safety Profile
Poison by ingestion and intraperitoneal routes. Moderately toxic by inhalation. Very dangerous fire hazard when exposed to heat, flames (sparks), or oxidizers. To fight fire, stop flow of gas. Violent reaction when mixed with (Brz + 02) or (CIF3 + water). Potentially explosive polymerization reaction with ethylene. Incompatible with 1,l -dchloroethylene; oxygen. When heated to decomposition it emits toxic fumes of Fand Cl-. See also CHLORINATED HYDROCARBONS, ALIPHATIC; and FLUORIDES.Purification Methods
Scrub it with 10% KOH solution, then 10% H2SO4 solution to remove inhibitors, dry and pass it through silica gel. It is stabilized with ~1% tributylamine. Use brass equipment. [Beilstein 1 III 646.] TOXIC GAS.트리플루오르클로로에틸렌 준비 용품 및 원자재
원자재
아연
염화 아연
티오황산 나트륨 펜타수화물
1,1,2-트리클로로-1,2,2-트리플루오로에탄
Silane, trichloro(2,2-dichloro-1,1,2-trifluoroethyl)-
1-bromo-1,2,2-trifluoro-1,2-chloroethane
1,2-DICHLORO-2-IODO-1,1,2-TRIFLUOROETHANE
1,2-디클로로테트라플루오로에탄
1,1-DICHLORO-1,2-DIFLUOROETHANE
TRIFLUOROETHYLENE
1,2-Dibromo-1-chloro-1,2,2-trifluoroethane
준비 용품
트리플루오르클로로에틸렌 공급 업체
글로벌( 94)공급 업체
| 공급자 | 전화 | 이메일 | 국가 | 제품 수 | 이점 |
|---|---|---|---|---|---|
| Hangzhou Verychem Science And Technology Co.Ltd | +86-86-57188162785 13606544505 |
lucy@verychem.com | China | 1001 | 58 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 |
info@tianfuchem.com | China | 21691 | 55 |
| career henan chemical co | +86-0371-86658258 |
sales@coreychem.com | China | 29914 | 58 |
| Hubei Jusheng Technology Co.,Ltd. | 18871490254 |
linda@hubeijusheng.com | CHINA | 28180 | 58 |
| Hubei xin bonus chemical co. LTD | 86-13657291602 |
linda@hubeijusheng.com | CHINA | 22968 | 58 |
| Shandong chuangyingchemical Co., Ltd. | 18853181302 |
sale@chuangyingchem.com | CHINA | 5909 | 58 |
| Chongqing Chemdad Co., Ltd | +86-023-61398051 +8613650506873 |
sales@chemdad.com | China | 39916 | 58 |
| CONIER CHEM AND PHARMA LIMITED | +8618523575427 |
sales@conier.com | China | 49390 | 58 |
| BEYOND INDUSTRIES (CHINA) LIMITED | +86-21-52699951; +8613917686115 |
sales@beyondindustriesgroup.com | China | 699 | 58 |
| SIMAGCHEM CORP | +86-13806087780 |
sale@simagchem.com | China | 17367 | 58 |
트리플루오르클로로에틸렌 관련 검색:
퍼클로로에틸렌 염화 트리플루오로아세틸 LAMBDACYHALOTHRIN 테크니컬 염화비닐 1,2-다이클로로에틸렌 폴리(클로로트리플루오르에틸렌) 플루오르화비닐리덴 비닐 플루오르화물 클로로트리플루오로에틸렌/비닐리덴 플루오르화 공중합물 에텐과 결합한 클로로트라이플루오로에텐 고분자 4-(에테닐옥시)-1-부탄올 중합체, 클로로 트라이 플루오르에텐, (에테닐옥시) 사이클로헥세인 및 에톡시에텐 함유 트리플루오르클로로에틸렌
TRIFLUOROETHYLENE
Lambda Cyhalotric Acid
CHLOROTRIFLUORETHENE (CTFE)
perchlorovinyl resin coating
2-CHLORO-1,1-DIFLUOROETHYLENE
Chlorofluoromethane