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헥사플루오로프로필렌

헥사플루오로프로필렌
헥사플루오로프로필렌 구조식 이미지
카스 번호:
116-15-4
한글명:
헥사플루오로프로필렌
동의어(한글):
육불화프로펜;헥사플루오로프로펜;헥사플루오로프로필렌
상품명:
Hexafluoropropylene
동의어(영문):
HEXAFLUOROPROPENE;1,1,2,3,3,3-hexafluoro-1-propene;CF3CF=CF2;Hexafluorpropen;PERFLUOROPROPENE;Hexafluofoproene;hexafluoro-propen;PERFLUOROPROPYLENE;hexfluoropropylene;Perfluoroprop-1-ene
CBNumber:
CB6210942
분자식:
C3F6
포뮬러 무게:
150.02
MOL 파일:
116-15-4.mol

헥사플루오로프로필렌 속성

녹는점
−153 °C(lit.)
끓는 점
−28 °C(lit.)
밀도
1,583 g/cm3
굴절률
1.4000
물리적 상태
gas
BRN
1705671
안정성
Stable. Incompatible with alkali metals, powdered metals.
InChIKey
HCDGVLDPFQMKDK-UHFFFAOYSA-N
CAS 데이터베이스
116-15-4(CAS DataBase Reference)
NIST
Propene, hexafluoro-(116-15-4)
EPA
Hexafluoropropene (116-15-4)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 Xn,Xi
위험 카페고리 넘버 20-37-68/20-48/20
안전지침서 41-36/37
유엔번호(UN No.) UN 1858 2.2
WGK 독일 1
RTECS 번호 UD0350000
F 고인화성물질 4.5
위험 참고 사항 Irritant
위험 등급 2.2
유해 물질 데이터 116-15-4(Hazardous Substances Data)
독성 LC50 inhalation in mouse: 750ppm/4H
기존화학 물질 KE-18543
그림문자(GHS):
신호 어: Warning
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H280 고압가스; 가열시 폭발할 수 있음 고압가스 압축가스
액화가스
용존 가스
경고 P410+P403
H332 흡입하면 유해함 급성 독성 물질 흡입 구분 4 경고 P261, P271, P304+P340, P312
H335 호흡 자극성을 일으킬 수 있음 특정 표적장기 독성 - 1회 노출;호흡기계 자극 구분 3 경고
H371 장기(또는, 영향을 받은 알려진 모든 장기를 명시)에 손상을 일으킬 수 있음(노출되어도 특정 표적장기 독성을 일으키지 않는다는 결정적인 노출경로가 있다면 노출경로를 기재) 특정 표적장기 독성 - 2회 노출 구분 2 경고 P260, P264, P270, P309+P311, P405,P501
H373 장기간 또는 반복 노출되면 장기(또는, 영향을 받은 알려진 모든 장기를 명시)에 손상을 일으킬 수 있음 특정 표적장기 독성 - 반복 노출 구분 2 경고 P260, P314, P501
예방조치문구:
P260 분진·흄·가스·미스트·증기·...·스프레이를 흡입하지 마시오.
P410+P403 직사광선을 피하고 환기가 잘 되는 곳에 보관하시오.
NFPA 704
0
2 0

헥사플루오로프로필렌 MSDS


Hexafluoropropylene

헥사플루오로프로필렌 C화학적 특성, 용도, 생산

화학적 성질

Hexafluoropropylene (HFP) is a colourless, odourless, non-flammable gas that is only slightly soluble in water. It is used as chemical intermediate primarily in the synthesis of fluoropolymers, fluoro-elastomers and fluorinated materials (e.g. perfluoropolyether functional fluids, oils and greases).

용도

Hexafluoropropene is used in the synthesis of polyvinylidene fluoride-co-hexafluoropropylene, a polymer which is currently being used in various fields of the nano and electronic sector ranging from membranes to nanoparticles.

제조 방법

Hexafluoropropylene can be produced by pyrolysis of tetrafluoroethylene (TFE):
3 CF2=CF2 → 2 CF3CF=CF
This reaction is carried out in a closed continuous reactor at 600 to 900°C. The yield can be improved at low partial pressure, achieved either by operating under reduced total pressure (down to 0.1 bar) or by injecting an inert diluent such as steam or CO2.
Significant quantities of by-products, including the highly toxic perfluoroisobutylene (PFIB), are formed during the pyrolysis of TFE. Such by-products are either incinerated directly or are collected and transported for incineration at a remote facility.
Hexafluoropropylene can also be prepared from chlorodifluoromethane, or produced from various chlorofluorocarbons.

일반 설명

Hexafluoropropylene is an odorless, colorless gas. Hexafluoropropylene is noncombustible. Hexafluoropropylene can asphyxiate by the displacement of air. Exposure of the container to prolonged heat or fire can cause Hexafluoropropylene to rupture violently and rocket.

반응 프로필

Halogenated aliphatic compounds, such as Hexafluoropropylene, are moderately or very reactive. Reactivity generally decreases with increased degree of substitution of halogen for hydrogen atoms. Materials in this group may be incompatible with strong oxidizing and reducing agents. Also, they may be incompatible with many amines, nitrides, azo/diazo compounds, alkali metals, and epoxides. Above a minimum oxygen pressure, the reaction of oxygen difluoride and hexafluoropropene to yield the Hexafluoropropylene oxide becomes explosive, Chem. Abs., 1987, 107, 175302. The reaction of hexafluoropropene with grignard reagent (subst. phenylmagnesium bromides) led to explosion, Fluorine Chem., 1981, 18, 25.

건강위험

Vapors may cause dizziness or asphyxiation without warning. Vapors from liquefied gas are initially heavier than air and spread along ground. Contact with gas or liquefied gas may cause burns, severe injury and/or frostbite. Fire may produce irritating, corrosive and/or toxic gases.

화재위험

Some may burn but none ignite readily. Containers may explode when heated. Ruptured cylinders may rocket.

헥사플루오로프로필렌 준비 용품 및 원자재

원자재

준비 용품


헥사플루오로프로필렌 공급 업체

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Henan Tianfu Chemical Co.,Ltd.
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Shanghai Time Chemicals CO., Ltd.
+86-021-57951555 +8617317452075
jack.li@time-chemicals.com China 1809 55
Hangzhou FandaChem Co.,Ltd.
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Hubei Jusheng Technology Co.,Ltd.
86-18871470254
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Hubei xin bonus chemical co. LTD
86-13657291602
linda@hubeijusheng.com CHINA 23034 58
Shandong chuangyingchemical Co., Ltd.
18853181302
sale@chuangyingchem.com CHINA 5917 58
HENAN BON INDUSTRIAL CO.,LTD
0371-55170695
info@hnbon.com CHINA 26742 58
CONIER CHEM AND PHARMA LIMITED
+8618523575427
sales@conier.com China 47501 58
career henan chemical co
+86-0371-86658258
factory@coreychem.com China 29862 58
Shaanxi Dideu Medichem Co. Ltd
18192627656
1012@dideu.com China 3950 58

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