디클로프롭

디클로프롭
디클로프롭 구조식 이미지
카스 번호:
120-36-5
한글명:
디클로프롭
동의어(한글):
2-[2,4-(다이클로로페녹시)]-프로판산;디클로프롭
상품명:
Dichlorprop
동의어(영문):
rd406;Kildip;2,4-DP;PATRON;U46 DP;RD 406;Polytox;DROMONE;REDIPON;WEEDONE
CBNumber:
CB7179789
분자식:
C9H8Cl2O3
포뮬러 무게:
235.06
MOL 파일:
120-36-5.mol
MSDS 파일:
SDS

디클로프롭 속성

녹는점
110-112 °C(lit.)
끓는 점
335.78°C (rough estimate)
밀도
1.3965 (rough estimate)
굴절률
1.5000 (estimate)
저장 조건
APPROX 4°C
용해도
클로로포름(약간 용해됨), 메탄올(약간 용해됨)
산도 계수 (pKa)
3.03±0.10(Predicted)
색상
미색부터 페일 베이지까지
수용성
829mg/L(25 ºC)
Merck
14,3078
BRN
2213812
CAS 데이터베이스
120-36-5(CAS DataBase Reference)
NIST
Alpha-(2,4-dichlorophenoxy)propionic acid(120-36-5)
EPA
Dichlorprop (120-36-5)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 Xn,Xi
위험 카페고리 넘버 21/22-38-41-36/37/38-20/21/22
안전지침서 26-36/37-37/39
유엔번호(UN No.) UN 3077 9 / PGIII
WGK 독일 2
RTECS 번호 UF1050000
TSCA Yes
위험 등급 IRRITANT
포장분류 III
HS 번호 29189990
유해 물질 데이터 120-36-5(Hazardous Substances Data)
독성 LD50 oral in rat: 344mg/kg
그림문자(GHS): GHS hazard pictogramsGHS hazard pictograms
신호 어: Danger
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H302 삼키면 유해함 급성 독성 물질 - 경구 구분 4 경고 GHS hazard pictograms P264, P270, P301+P312, P330, P501
H312 피부와 접촉하면 유해함 급성 독성 물질 - 경피 구분 4 경고 GHS hazard pictograms P280,P302+P352, P312, P322, P363,P501
H315 피부에 자극을 일으킴 피부부식성 또는 자극성물질 구분 2 경고 GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H318 눈에 심한 손상을 일으킴 심한 눈 손상 또는 자극성 물질 구분 1 위험 GHS hazard pictograms P280, P305+P351+P338, P310
예방조치문구:
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
P305+P351+P338 눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.
NFPA 704
0
2 0

디클로프롭 C화학적 특성, 용도, 생산

화학적 성질

2,4-DP is a combustible, colorless to yellowish to tan crystalline solid with a faint phenolic odor

정의

ChEBI: An aromatic ether that is 2-hydroxypropanoic acid in which the hydroxy group at position 2 has been converted to its 2,4-dichlorophenyl ether.

일반 설명

Yellowish to colorless solid. Soluble in organic solvents. Used as an herbicide.

반응 프로필

Dichlorprop is an organic acid. Neutralizes bases in exothermic reactions.

Safety Profile

Suspected carcinogen. Poison by ingestion. Moderately toxic by skin contact. An experimental teratogen. Other experimental reproductive effects. Mutation data reported. A fumigant. When heated to decomposition it emits toxic fumes of Cl-.

잠재적 노출

A phenoxy herbicide

환경귀착

The average field half-life is 10 days. Microbial degradation and plant uptake account for the short half-life of dichlorprop. Losses due to leaching, photodegradation, and volatilization are minimal.

신진 대사

Chemical. Dichlorprop and its salts are very stable, but esters readily hydrolyze under acidic and basic conditions.
Plant. Degradation of the side chain of dichlorprop to form 2,4-dichlorophenol is most common. Dichlorprop may be conjugated to form glucosides, diglucosides, and to a limited extent triglucosides.
Soil. The degradation pathway of dichlorprop is similar in plants and soils, forming 2,4-dichlorophenol. Evidence indicates that some microbial communities preferentially degrade the R-enantiomer.

운송 방법

UN3345 Phenoxyacetic acid derivative pesticide, solid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials

Purification Methods

Crystallise 2,4-DP from MeOH. It is a plant growth substance, a herbicide and is TOXIC. The R(+)-and S(-)-enantiomers have m 124o (from *C6H6) and [] D ±35.2o (c 1, Me2CO). [Beilstein 6 H 189, 6 III 708, 6 IV 922-923.]

비 호환성

Dust may form explosive mixture with air. Contact with oxidizers may cause a fire and explosion hazard. The aqueous solution is a weak acid. Attacks many metals in presence of moisture. Compounds of the carboxyl group react with all bases, both inorganic and organic (i.e., amines) releasing substantial heat, water and a salt that may be harmful. Incompatible with arsenic compounds (releases hydrogen cyanide gas), diazo compounds, dithiocarbamates, isocyanates, mercaptans, nitrides, and sulfides (releasing heat, toxic and possibly flammable gases), thiosulfates and dithionites (releasing hydrogen sulfate and oxides of sulfur).

폐기물 처리

In accordance with 40CFR165, follow recommendations for the disposal of pesticides and pesticide containers. Must be disposed properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office.

디클로프롭 준비 용품 및 원자재

원자재

준비 용품


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