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2,4-디클로로페녹시에타노익 엑시드

2,4-디클로로페녹시에타노익 엑시드
2,4-디클로로페녹시에타노익 엑시드 구조식 이미지
카스 번호:
94-75-7
한글명:
2,4-디클로로페녹시에타노익 엑시드
동의어(한글):
2,4-디클로로페녹시아세트산;2,4-디;2,4-디클로로페녹시에타노익엑시드;2,4-D산;2,4-디클로로페녹시에탄산;HEDONAL;페르니민
상품명:
2,4-Dichlorophenoxyacetic acid
동의어(영문):
For;GAPL;dma4;u46d;moxon;RASA4;DMA-4;CAPRI;DYMEC;KAY-D
CBNumber:
CB8762041
분자식:
C8H6Cl2O3
포뮬러 무게:
221.04
MOL 파일:
94-75-7.mol

2,4-디클로로페녹시에타노익 엑시드 속성

녹는점
136-140 °C (lit.)
끓는 점
160 °C (0.4 mmHg)
밀도
1.563
증기압
0.4 mm Hg ( 160 °C)
굴절률
1.5000 (estimate)
인화점
160°C/0.4mm
저장 조건
2-8°C
용해도
Soluble in organic solvents (ethanol, acetone, dioxane)
산도 계수 (pKa)
pK1:2.64 (25°C)
물리적 상태
crystalline
색상
off-white to tan
pH 범위
Acidic
Odor Threshold
3.13 ppm
수용성
Slightly soluble. Decomposes. 0.0890 g/100 mL
Merck
14,2796
BRN
1214242
Henry's Law Constant
6.72 and 0.84 x 10-5 atm?m3/mol were reported at pH values of 1 and 7, respectively (wetted-wall column, Rice et al., 1997a)
노출 한도
NIOSH REL: TWA 10 mg/m3, IDLH 100 mg/m3; OSHA PEL: TWA 10 mg/m3; ACGIH TLV: TWA 10 mg/m3.
안정성
Stable, but moisture-sensitive and may be light-sensitive. Incompatible with strong oxidizing agents, corrodes many metals. Decomposes in water.
CAS 데이터베이스
94-75-7(CAS DataBase Reference)
NIST
(2,4-Dichlorophenoxy)acetic acid(94-75-7)
IARC
2B (Vol. 113) 2018
EPA
2,4-D (94-75-7)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 Xn,Xi,T,F
위험 카페고리 넘버 22-37-41-43-52/53-39/23/24/25-23/24/25-36/37/38-11-36-20/21/22-67-66
안전지침서 24/25-26-36/37/39-46-61-2-45-36/37-27-16-7-9
유엔번호(UN No.) UN 3077 9/PG 3
WGK 독일 2
RTECS 번호 AG6825000
자연 발화 온도 > 180 °C
TSCA Yes
위험 등급 6.1
포장분류 III
HS 번호 29189090
유해 물질 데이터 94-75-7(Hazardous Substances Data)
독성 LD50 (oral): rat [free] 375 mg/kg, [-Na] 666-805 mg/kg.
기존화학 물질 KE-05-0002
유해화학물질 필터링 97-1-413
함량 및 규제정보 물질구분: 유독물질; 혼합물(제품)함량정보: 2,4-디 및 이를 25% 이상 함유한 혼합물
그림문자(GHS):
신호 어: Danger
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H302 삼키면 유해함 급성 독성 물질 - 경구 구분 4 경고 P264, P270, P301+P312, P330, P501
H317 알레르기성 피부 반응을 일으킬 수 있음 피부 과민성 물질 구분 1 경고 P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H318 눈에 심한 손상을 일으킴 심한 눈 손상 또는 자극성 물질 구분 1 위험 P280, P305+P351+P338, P310
H335 호흡 자극성을 일으킬 수 있음 특정 표적장기 독성 - 1회 노출;호흡기계 자극 구분 3 경고
H412 장기적 영향에 의해 수생생물에 유해함 수생 환경유해성 물질 - 만성 구분 3 P273, P501
예방조치문구:
P261 분진·흄·가스·미스트·증기·...·스프레이의 흡입을 피하시오.
P264 취급 후에는 손을 철저히 씻으시오.
P264 취급 후에는 손을 철저히 씻으시오.
P273 환경으로 배출하지 마시오.
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.

2,4-디클로로페녹시에타노익 엑시드 MSDS


2,4-D LV6

2,4-디클로로페녹시에타노익 엑시드 C화학적 특성, 용도, 생산

개요

2,4-D free acids, esters, amines, and salts are formulated in water suspensions or solutions, or in various organic solvents, for application as systemic herbicides that are used postemergence for selective control of broadleaf weeds.

화학적 성질

2,4-Dichlorophenoxyacetic acid is a white to yellow crystalline powder with a slight phenolic odor. It is used as a herbicide for the selective control of broad-leaved weeds in agriculture, and for the control of woody plants along roadsides, railways, and utilities rights of way. It is one of the most widely used herbicides in the world and is commonly used on crops such as wheat and corn, and on pasture and rangelands. It is also used to control broad-leaved aquatic weeds.

물리적 성질

Odorless, white to pale yellow, powder or prismatic crystals. Impure formulations containing 2,4- D as the main component may have a phenolic odor.

용도

2,4-D is registered with the US Environmental Protection Agency (EPA) for use on a variety of food/feed sites, turf, lawn, aquatic sites, and forestry applications, and as a growth regulator in citrus crops. Residents and professional applicators may use 2,4-D on home lawns.

용도

2,4-D is one of the most widely used herbicides. It is a chlorine-substituted phenoxyacetic acid herbicide used for postemergence control of annual and perennial broad-leaved weeds in fruits, vegetables, turfs and ornamentals.Exposure to this chemical may arisein the garden, farm, or plantation setting,where it is sprayed for weed control andto enhance the plant growth. Its residueshave been detected in soils, sediments, andgroundwater, as well as in tissues of corals(Crockett et al. 1986; Glynn et al. 1984).

용도

2,4-Dichlorophenoxyacetic acid is often formulated as various forms of inorganic salts or esters. 2,4-D was first registered as a herbicide in 1948, and its annual production was estimated at 52–67 million lb in 1990. The primary use of 2,4-D is for control of broadleaf weeds, and as such, it is used for a large spectrum of applications in agriculture, forestry, and lawn care. 2,4-D also is used along right-ofways, on rangelands, parks, and in aquatic environments.

제조 방법

Two processes are currently used for the production of 2,4-Dichlorophenoxyacetic acid. In the first process, phenol is condensed with chloroacetic acid forming phenoxyacetic acid, which is subsequently chlorinated. In the second process, phenol is chlorinated, generating 2,4-dichlorophenol, which is subsequently condensed with chloroacetic acid. The butyl ester derivative of 2,4-D is produced by the esterification of the acid with butanol in the presence of a ferric chloride catalyst and chlorine (Liu et al., 2013).
Preparation of 2,4-Dichlorophenoxyacetic acid
Preparation of 2,4-Dichlorophenoxyacetic acid

정의

ChEBI: A chlorophenoxyacetic acid that is phenoxyacetic acid in which the ring hydrogens at postions 2 and 4 are substituted by chlorines.

일반 설명

Odorless white to tan solid. Sinks in water.

공기와 물의 반응

Decomposes rapidly in water.

반응 프로필

2,4-Dichlorophenoxyacetic acid is incompatible with strong oxidizers. 2,4-Dichlorophenoxyacetic acid is corrosive to metals.

건강위험

The acute toxic symptoms from ingestion,absorption through skin, and inhalation ofits dusts include lethargy, stupor, weakness,incoordination, muscular twitch, nausea, vomiting, gastritis, convulsions, and coma.Death resulted in animals from ventricularfibrillation. In humans, ingestion of 4–6 gof 2,4-D can cause death. The toxic effectsare nausea, vomiting, somnolence, convul-sions, and coma. The oral LD50 value in testanimals varied at 100–500 mg/kg, depend-ing on species, which included dogs, guineapigs, hamsters, rats, mice, and rabbits.
Gorzinski and co-workers (1987) have investigated acute, pharmacokinetic, and subchronic toxicity of 2,4-D and its estersand salts in rats and rabbits. The acutedermal LD50 values in rabbits for theacid, esters, and salts were >2000 mg/kg.Urinary elimination of 2,4-D was saturatedin male rats given oral doses of 50 mg/kg.There was a decrease in body weightgain and increase in kidney weightsin animals, resulting from subchronicdietary doses. A dose-related degenerativechange was observed in the proximalrenal tubules. Repeated subcutaneous dosing(150–250 mg/kg) of 2,4-D butyl esterresulted in accumulation of the compoundin the brain, causing neurobehavioral toxicity(Schulze and Dougherty 1988).
Alexander and associates (1985) determined the 48-hour median lethal con-centration values for 2,4-D to aquatic organ-isms. These values are 25, 325, 290, and358 mg/L for Daphnia magna, fathead min-nows, bluegill, and rainbow trout, respec-tively.

화재위험

Special Hazards of Combustion Products: Toxic and irritating hydrogen chloride or phosgene gases may form.

농업용

Herbicide, Plant growth regulator: 2,4-Dichlorophenoxyacetic acid was introduced as a plant growth-regulator in 1942. 2, 4-D is the most widely used herbicide in the United States and its used in more than 100 countries. It is registered in the United States as a herbicide for control of broadleaf plants and as a plant growth-regulator. There are many forms or derivatives of 2,4-D including esters, amines, and salts. It is used in cultivated agriculture, in pasture and rangeland applications, forest management, home, garden, and to control aquatic vegetation. It may be found in emulsion form, in aqueous solutions (salts), and as a dry compound. The product Agent Orange, made by Monsanto Chemical and used extensively throughout Vietnam, was about 50% 2,4-D. However, the controversies associated with the use of Agent Orange involved a contaminant (dioxin) in the 2,4,5-T component of the defoliant. In 1964 Agent Orange replaced Agent Purple a mixture of the n-butyl esters of 2,4-D and 2,4,5-T plus the isobutyl ester of 2,4,5-T.

상품명

Hedonal; 2,4-D; Estone; Agrotect; Fernesta; Fernimine; Netagrone; Tributon; Vergemaster; Amoxone; Dicopur; Dormone; Ipaner; Moxone; Phenox; Pielik; Rhodia; Weedone; B-Selektonon.

잠재적 노출

2,4-Dichlorophenoxyacetic acid, was introduced as a plant growth-regulator in 1942. It is registered in the United States as a herbicide for control of broadleaf plants and as a plant growth-regulator. Thus, workers engaged in manufacture, formulation or application are affected, as may be citizens in areas of application. The Vietnam war era defoliant, Agent Orange, was a mixture of 2,4-D and 2,4,5-T.

Carcinogenicity

Collectively, the epidemiological and toxicological data show that 2,4-D is not likely to be carcinogenic in humans unless it is acting through an unknown mechanism that is not evident in animals. According to the calculated RfD and data from exposure studies, the general public should not experience toxic effects from exposure to 2,4-D. Because workers involved in the manufacture or application of 2,4-D may be exposed to levels above the RfD, appropriate protective equipment should be used.

환경귀착

2,4-Dichlorophenoxyacetic acid (2,4-d) is rapidly degraded by microbes in soil and water, with a half-life of 3-22 days in different soils. 2,4-d is weakly sorbed by soil with sorption generally increasing with increasing soil organic carbon content. Leaching to groundwater is most likely in coarse-grained sandy soils with low organic content or with very basic soils. In general, little runoff occurs with 2,4-d or its amine salts.

신진 대사

Chemical. 2,4-D and its salts are very stable, but esters are sensitive to hydrolysis under acidic and basic conditions. In the field, 2,4-D losses due to photodegradation are minor. 2,4-D is a strong acid and forms water-soluble salts with amines and alkali metals. A sequestering agent is included in 2,4-D formulations to prevent precipitation of Ca2+ andMg2+ salts in hard water.
Plant. 2,4-D detoxification occurs relatively slowly in plants. There are many possible routes of detoxification, and these are usually grouped into those reactions that are consistent with phase I metabolism and those that are consistent with phase II metabolism. Phase I reactions that have been observed to occur with 2,4-D include dechlorination, decarboxylation, hydroxylation, and dealkylation. Phase II reactions that have been observed to occur with 2,4-D include conjugation of the side chain to amino acids, particularly glutamate and aspartate, and glucose conjugation following hydroxylation of the phenoxy ring. Selectivity differences among broadleaf species may be accounted for by differences in the rates of 2,4-D detoxification.
Soil. Microbial degradation in the soil involves cleavage of the acid side chain, decarboxylation, hydroxylation, and ring opening.

운송 방법

UN3345 Phenoxyacetic acid derivative pesticide, solid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials. A DOT regulated marine pollutant.

Purification Methods

Crystallise 2,4-D from MeOH. It is a plant growth substance, a herbicide and is TOXIC. [Beilstein 6 IV 908.]

Toxicity evaluation

2,4-D is excreted unchanged in the urine of humans and rat. When used under normal conditions, 2,4-D does not appear to produce acute toxic effects on any animal species. The acute oral LD50s of 2,4- D in rat and mouse are 639–764 mg/kg, and 138 mg/kg, respectively.

비 호환성

A weak acid, incompatible with bases. Decomposes in sunlight or heat, forming hydrogen chloride and phosgene. Contact with strong oxidizers may cause fire and explosions.

폐기물 처리

Incineration of phenoxys is effective in 1 second @ 982 C, using a straight combustion process or @ 482℃ using catalytic combustion. Over 99% decomposition was reported when small amounts of 2,4-D were burned in a polyethylene bag. See "References" for additional detail. In accordance with 40CFR165, follow (31); recommendations for the disposal of pesticides and pesticide containers. Must be disposed properly by follow- ing (100) Package (2) label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office. Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≥100 kg/mo) must conform with EPA regulations governing storage, transportation, treatment, and waste disposal.

2,4-디클로로페녹시에타노익 엑시드 준비 용품 및 원자재

원자재

준비 용품


2,4-디클로로페녹시에타노익 엑시드 공급 업체

글로벌( 413)공급 업체
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Henan DaKen Chemical CO.,LTD.
+86-371-66670886
info@dakenchem.com China 15426 58
Henan Tianfu Chemical Co.,Ltd.
0371-55170693
0371-55170693 info@tianfuchem.com China 22607 55
Anhui Royal Chemical Co., Ltd.
+86-025-86655873
marketing@royal-chem.com CHINA 536 55
career henan chemical co
+86-0371-55982848
sales@coreychem.com China 29953 58
Hubei Jusheng Technology Co.,Ltd.
86-18871470254
027-59599243 linda@hubeijusheng.com CHINA 28229 58
Hebei Guanlang Biotechnology Co., Ltd.
+8619930503282
sales3@crovellbio.com China 5943 58
Xiamen AmoyChem Co., Ltd
+86 592-605 1114
sales@amoychem.com CHINA 6369 58
Xi'an Kono chem co., Ltd.,
13289246953 029-86107037
info@konochemical.com CHINA 3000 58
Hubei xin bonus chemical co. LTD
86-13657291602
027-59338440 linda@hubeijusheng.com CHINA 23035 58
Chongqing Chemdad Co., Ltd
+86-13650506873
sales@chemdad.com CHINA 37282 58

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