삼불화 브롬 C화학적 특성, 용도, 생산
화학적 성질
Bromine trifluoride is a noncombustible, colorless
to gray-yellow fuming liquid. Extremely irritating odor.
물리적 성질
Colorless liquid; hygroscopic; density 2.803 g/mL; boils at 125.8°C; solidifies at 8.8°C; vapor pressure 8 torr at 21°C; decomposes violently in water.
용도
Solvent for fluorides.
제조 방법
Bromine trifluoride may be prepared by fluorination of bromine at 80°C. The halogen mixtures may be diluted in nitrogen or an inert gas.
일반 설명
A colorless to yellow, fuming liquid with a pungent odor. Solidifies at 48°F. Very toxic by inhalation and corrosive to metals and tissue. Containers exposed to prolonged heat may violently rupture and rocket.
공기와 물의 반응
Fumes in air. Reacts with water with explosive force, oxygen being evolved [Handbook of Chemistry and Physics].
반응 프로필
BROMINE TRIFLUORIDE is a very reactive oxidizing agent. Reacts violently on contact with water to evolve oxygen. Accelerates the burning of combustible material. Mixing with the following hydrogen-containing substances is likely to cause a fire or explosion: acetic acid, ammonia, benzene, ethanol, 2-pentanone, hydrogen, hydrogen sulfide, methane, cork, grease paper , wax. Mixing with acids, halogens, ammonium halides, metal halides, metals, nonmetals, or metal oxides at ambient or slightly above ambient temperatures has resulted in violent reactions. Specifically, reacts dangerously with nitric acid, sulfuric acid, chlorine, iodine, ammonium chloride, potassium iodide, boron powder, selenium, tellurium, aluminum powder, bismuth, cobalt powder, iron powder, arsenic, nickel powder, chromium trioxide, charcoal, red phosphorus, sulfur dioxide, magnesium oxide.
위험도
Corrosive to skin. Very reactive and dan-
gerous.
건강위험
The vapors of bromine trifluoride are highlyirritating to the eyes, skin, and mucousmembranes. Upon contact with the skin, theliquid can cause severe burns. The toxicitydata for this compound are not available.
화재위험
Behavior in Fire: Forms very toxic and irritating fumes.
Safety Profile
Poisonous and
corrosive. Very reactive, a powerful oxidizer.
Explosive or violent reaction with organic
materials, water, acetone, ammonium
halides, antimony, antimony trichloride
oxide, arsenic, benzene, boron, bromine,
carbon, carbon monoxide, carbon
tetrachloride, carbon tetraiodlde,
chloromethane, cobalt, ether, halogens,
iodine, powdered molybdenum, niobium, 2
pentanone, phosphorus, potassium
hexachloroplatinate, pyridine, sihcon,
silicone grease, sulfur, tantalum, tin
dichloride, titanium, toluene, vanadurn,
uranium, uranium hexafluoride.
Incompatible with Sb203, BaCl2, Bi205,
CdCl2, CaCl2, CsCl, LiCl, MnI03, metals,
Nb205, PtBr4, PtCl4, (Pt + KFO), Iar, KCl,
KI, RhBr4, RbCl, AgCl, NaBr, NaCl, NaI,
Ta205, Sn, W, UO,, rubber, plastics. The
product of reaction with pyridine ignites
when dry. When heated to decomposition it
emits toxic fumes of Fand Br-. Very
dangerous. See also BROMINE
잠재적 노출
Bromine Trifluoride is used as a fluorinating
agent and an electrolytic solvent.
운송 방법
UN1746 Bromine trifluoride, Hazard class 5.1;
Labels: 5.1—Oxidizer, 6.1—Poison Inhalation Hazard, 8—
Corrosive material, Inhalation Hazard Zone B.
비 호환성
A powerful oxidizer; highly reactive and
a dangerous explosion hazard. Contact with water or other
hydrogen containing materials forms hydrogen fluoride gas.
Reacts with almost all elements except for inert gases.
Violent reaction with reducing agents; organic materials;
strong acids; strong bases; halogens, salts (antimony salts),
metal oxides; and many other materials. Attacks some plastics,
rubber, or coatings.
삼불화 브롬 준비 용품 및 원자재
원자재
준비 용품
