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ChemicalBook >> CAS DataBase List >> Benzyl chloride

Benzyl chloride

Benzyl chloride price.
  • $13.5 - $1060
  • Product name: Benzyl chloride
  • CAS: 100-44-7
  • MF: C7H7Cl
  • MW: 126.58
  • EINECS:202-853-6
  • MDL Number:MFCD00000889
  • Synonyms:AKOS BBS-00003953;Benzyl chloride, 99.5+%, stabilized, extra pure;Benzyl chloride, 99%, stabilized, pure;Benzyl chloride, 90%, pure;Benzyl chloride, stabilized, extra pure;Benzyl chloride,99.5+%,extra pure,stabilized;Benzyl chloride,99%,pure,stabilized;Benzyl Chloride (stabilized with epsilon-Caprolactam)
33 prices
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  • Chem-Impex
  • ChemSupplyAustralia
  • GFS CHEMICALS
  • Matrix Scientific
  • Medical Isotopes, Inc.
  • Sigma-Aldrich
  • TCI Chemical
  • Thermo Scientific Chemicals
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  • ManufacturerChem-Impex
  • Product number02278
  • Product descriptionBenzyl chloride ≥98.0%(GC)
  • Packaging250G
  • Price$18.53
  • Updated2026-05-19
  • Buy
  • ManufacturerChem-Impex
  • Product number02278
  • Product descriptionBenzyl chloride ≥ 98% (GC)
  • Packaging250ML
  • Price$20.7
  • Updated2021-12-16
  • Buy
  • ManufacturerChem-Impex
  • Product number02278
  • Product descriptionBenzylchloride,≥98.0%(GC),ACSreagentHazmat ≥98.0%(GC)
  • Packaging250G
  • Price$13.5
  • Updated2021-12-16
  • Buy
  • ManufacturerChem-Impex
  • Product number02278
  • Product descriptionBenzylchloride,≥98.0%(GC),ACSreagentHazmat ≥98.0%(GC)
  • Packaging1KG
  • Price$34.94
  • Updated2021-12-16
  • Buy
  • ManufacturerChem-Impex
  • Product number02278
  • Product descriptionBenzyl chloride ≥98.0%(GC)
  • Packaging1KG
  • Price$46.77
  • Updated2026-05-19
  • Buy
  • ManufacturerChem-Impex
  • Product number02278
  • Product descriptionBenzylchloride,≥98.0%(GC),ACSreagentHazmat ≥98.0%(GC)
  • Packaging2.5KG
  • Price$81.54
  • Updated2021-12-16
  • Buy
  • ManufacturerChem-Impex
  • Product number02278
  • Product descriptionBenzyl chloride ≥98.0%(GC)
  • Packaging2.5KG
  • Price$103.96
  • Updated2026-05-19
  • Buy
  • ManufacturerChem-Impex
  • Product number02278
  • Product descriptionBenzylchloride,≥98.0%(GC),ACSreagentHazmat ≥98.0%(GC)
  • Packaging5KG
  • Price$151.42
  • Updated2021-12-16
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  • ManufacturerChem-Impex
  • Product number02278
  • Product descriptionBenzyl chloride ≥98.0%(GC)
  • Packaging5KG
  • Price$185.18
  • Updated2026-05-19
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  • ManufacturerChem-Impex
  • Product number02278
  • Product descriptionBenzylchloride,≥98.0%(GC),ACSreagentHazmat ≥98.0%(GC)
  • Packaging10KG
  • Price$279.55
  • Updated2021-12-16
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  • ManufacturerChem-Impex
  • Product number02278
  • Product descriptionBenzyl chloride ≥98.0%(GC)
  • Packaging10KG
  • Price$331.4
  • Updated2026-05-19
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  • ManufacturerChemSupplyAustralia
  • Product number300426
  • Product descriptionBenzyl chloride, 99%
  • Packaging1000g
  • Price$35.2
  • Updated2021-12-16
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  • ManufacturerChemSupplyAustralia
  • Product number300426
  • Product descriptionBenzyl chloride, 99%
  • Packaging100g
  • Price$22
  • Updated2021-12-16
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  • ManufacturerGFS CHEMICALS
  • Product number15672
  • Product descriptionBENZYLCHLORIDE,99%
  • Packaging500mL
  • Price$33.12
  • Updated2021-12-16
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  • ManufacturerGFS CHEMICALS
  • Product number15673
  • Product descriptionBENZYLCHLORIDE,99%
  • Packaging2L
  • Price$79.13
  • Updated2021-12-16
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  • ManufacturerMatrix Scientific
  • Product number134355
  • Product description(Chloromethyl)benzene 95%+
  • Packaging2.500g
  • Price$215
  • Updated2021-12-16
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Chem-Impex 02278 Benzyl chloride ≥98.0%(GC) 250G $18.53 2026-05-19 Buy
Chem-Impex 02278 Benzyl chloride ≥ 98% (GC) 250ML $20.7 2021-12-16 Buy
Chem-Impex 02278 Benzylchloride,≥98.0%(GC),ACSreagentHazmat ≥98.0%(GC) 250G $13.5 2021-12-16 Buy
Chem-Impex 02278 Benzylchloride,≥98.0%(GC),ACSreagentHazmat ≥98.0%(GC) 1KG $34.94 2021-12-16 Buy
Chem-Impex 02278 Benzyl chloride ≥98.0%(GC) 1KG $46.77 2026-05-19 Buy
Chem-Impex 02278 Benzylchloride,≥98.0%(GC),ACSreagentHazmat ≥98.0%(GC) 2.5KG $81.54 2021-12-16 Buy
Chem-Impex 02278 Benzyl chloride ≥98.0%(GC) 2.5KG $103.96 2026-05-19 Buy
Chem-Impex 02278 Benzylchloride,≥98.0%(GC),ACSreagentHazmat ≥98.0%(GC) 5KG $151.42 2021-12-16 Buy
Chem-Impex 02278 Benzyl chloride ≥98.0%(GC) 5KG $185.18 2026-05-19 Buy
Chem-Impex 02278 Benzylchloride,≥98.0%(GC),ACSreagentHazmat ≥98.0%(GC) 10KG $279.55 2021-12-16 Buy
Chem-Impex 02278 Benzyl chloride ≥98.0%(GC) 10KG $331.4 2026-05-19 Buy
ChemSupplyAustralia 300426 Benzyl chloride, 99% 1000g $35.2 2021-12-16 Buy
ChemSupplyAustralia 300426 Benzyl chloride, 99% 100g $22 2021-12-16 Buy
GFS CHEMICALS 15672 BENZYLCHLORIDE,99% 500mL $33.12 2021-12-16 Buy
GFS CHEMICALS 15673 BENZYLCHLORIDE,99% 2L $79.13 2021-12-16 Buy
Matrix Scientific 134355 (Chloromethyl)benzene 95%+ 2.500g $215 2021-12-16 Buy

Properties

Melting point :-39 °C
Boiling point :179 °C
Density :1.1 g/mL at 25 °C(lit.)
vapor density :4.36 (vs air)
vapor pressure :10.3 mm Hg ( 60 °C)
refractive index :n20/D 1.538(lit.)
Flash point :165 °F
storage temp. :Store below +30°C.
solubility :soluble0.46g/L at 30°C (Decomposes in contact with water)
form :Liquid
color :Clear colorless to slightly yellow
Odor :Pungent, irritating.
explosive limit :1.1-14%(V)
Water Solubility :0.3 g/L (20 ºC)
Merck :14,1129
BRN :471308
Henry's Law Constant :(x 10-4 atmm3/mol): 3.57 at 20.00 °C (inert gas stripping, Hovorka and Dohnal, 1997)
Dielectric constant :7.0(13℃)
Exposure limits :TLV-TWA 1 ppm (~5mg/m3) (ACGIH, MSHA, and OSHA); IDLH 10 ppm (NIOSH); carcinogenicity: Animal Limited Evidence, Human Inadequate Evidence (IARC).
Stability :Unstable - inhibitors such as propylene oxide or trimethylamine are usually added to prevent polymerization. Combustible. Incompatible with strong oxidizing agents, water, acids, most common metals, dimethyl sulfoxide. Above flash point vapour-air mixtures are explosive within the limits noted above. Contact with water produces toxic fumes.
InChI :1S/C7H7Cl/c8-6-7-4-2-1-3-5-7/h1-5H,6H2
InChIKey :KCXMKQUNVWSEMD-UHFFFAOYSA-N
SMILES :ClCc1ccccc1
LogP :2.3 at 20℃ and pH7
Surface tension :39.36mN/m at 298.15K
CAS DataBase Reference :100-44-7(CAS DataBase Reference)
IARC :2A (Vol. 29, Sup 7, 71) 1999
NIST Chemistry Reference :Benzyl chloride(100-44-7)
EPA Substance Registry System :Benzyl chloride (100-44-7)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H227 Combustible liquid Flammable liquids Category 4 Warning P210, P280, P370+P378, P403+P235,P501
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning GHS hazard pictograms P264, P270, P301+P312, P330, P501
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H330 Fatal if inhaled Acute toxicity,inhalation Category 1, 2 Danger GHS hazard pictograms P260, P271, P284, P304+P340, P310,P320, P403+P233, P405, P501
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
H350 May cause cancer Carcinogenicity Category 1A, 1B Danger GHS hazard pictograms
H370 Causes damage to organs Specific target organ toxicity, single exposure Category 1 Danger GHS hazard pictograms P260, P264, P270, P307+P311, P321,P405, P501
H372 Causes damage to organs through prolonged or repeated exposure Specific target organ toxicity, repeated exposure Category 1 Danger GHS hazard pictograms P260, P264, P270, P314, P501
H373 May cause damage to organs through prolonged or repeated exposure Specific target organ toxicity, repeated exposure Category 2 Warning P260, P314, P501
H400 Very toxic to aquatic life Hazardous to the aquatic environment, acute hazard Category 1 Warning GHS hazard pictograms P273, P391, P501
Precautionary statements:
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P284 Wear respiratory protection.
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P363 Wash contaminated clothing before reuse.
P370+P378 In case of fire: Use … for extinction.
P391 Collect spillage. Hazardous to the aquatic environment
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P403+P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.
P501 Dispose of contents/container to..…

Description

Benzyl Chloride is used as an intermediate for manufacturing of benzyl alcohol, benzoic acid and benzyl cyanide. It is also used to prepare benzyl esters, which are used as plasticizer, flavorants and perfumes. It acts as an intermediate in the preparation of phenylacetic acid. In organic synthesis, it is used as an alkylating agent and utilized for the introduction of the benzyl protecting group for alcohols. Further, it is involved in the preparation of quaternary ammonium salts by reaction with tertiary amines. In addition to this, it is used to prepare Grignard reagent by reacting with metallic magnesium.

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