Ethyl formate

Melting point :-80 °C (lit.)
Boiling point :52-54 °C (lit.)
Density :0.921 g/mL at 20 °C (lit.)
vapor density :2.5 (vs air)
vapor pressure :15.16 psi ( 55 °C)
refractive index :n20/D 1.359(lit.)
FEMA :2434 | ETHYL FORMATE
Flash point :7 °F
storage temp. :2-8°C
solubility :Miscible with alcohol, benzene, and ether (Hawley, 1981)
form :Liquid
color :Clear
Odor :Characteristic; pleasant aromatic.
Odor Threshold :2.7ppm
explosive limit :16%
Odor Type :ethereal
Water Solubility :11 g/100 mL (18 ºC)
Sensitive :Moisture Sensitive
JECFA Number :26
Merck :14,3807
BRN :906769
Henry's Law Constant :0.097(x 10^-3 atm?m³/mol) at 5.00 °C, 0.13 at 10.00 °C, 0.17 at 15.00 °C, 0.23 at 20.00 °C, 0.29 at 25.00 °C (column stripping-UV, Kutsuna et al., 2005)
Exposure limits :TLV-TWA 100 ppm (～300 mg/m³) (ACGIH, MSHA, and OSHA); IDLH 8000 ppm (NIOSH).
Dielectric constant :8.4（6℃）
Stability :Stable. Extremely flammable. May form explosive mixtures with air. Note low flash point and wide explosive limits. Incompatible with strong oxidizing agents, strong bases, strong acids, nitrates.
InChIKey :WBJINCZRORDGAQ-UHFFFAOYSA-N
LogP :1.504 at 25℃
CAS DataBase Reference :109-94-4(CAS DataBase Reference)
NIST Chemistry Reference :Formic acid, ethyl ester(109-94-4)
EPA Substance Registry System :Ethyl formate (109-94-4)

Symbol(GHS):
Signal word:	Danger
Hazard statements:	Code Hazard statements Hazard class Category Signal word Pictogram P-Codes H225 Highly Flammable liquid and vapour Flammable liquids Category 2 Danger P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501 H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning P264, P280, P305+P351+P338,P337+P313P H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning
Precautionary statements:	P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. P233 Keep container tightly closed. P240 Ground/bond container and receiving equipment. P301+P312 IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.