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Ethyl formate

CAS No. 109-94-4
Chemical Name: Ethyl formate
Synonyms: Areginal;HCOOC2H5;FEMA 2434;FORMIC ETHER;Ethylformiat;Ethyl forMat;Aethylformiat;ETHYL FORMATE;Ethylformiaat;mrowczanetylu
CBNumber: CB3411274
Molecular Formula: C3H6O2
Formula Weight: 74.08
MOL File: 109-94-4.mol
Ethyl formate Property
Melting point : −80 °C(lit.)
Boiling point : 52-54 °C(lit.)
density : 0.921 g/mL at 20 °C(lit.)
vapor density : 2.5 (vs air)
vapor pressure : 15.16 psi ( 55 °C)
FEMA : 2434
refractive index : n20/D 1.359(lit.)
Fp : 7 °F
storage temp. : Flammables area
Water Solubility : 11 g/100 mL (18 ºC)
Sensitive : Moisture Sensitive
Merck : 14,3807
BRN : 906769
Stability:: Stable. Extremely flammable. May form explosive mixtures with air. Note low flash point and wide explosive limits. Incompatible with strong oxidizing agents, strong bases, strong acids, nitrates.
CAS DataBase Reference: 109-94-4(CAS DataBase Reference)
NIST Chemistry Reference: Formic acid, ethyl ester(109-94-4)
EPA Substance Registry System: Formic acid, ethyl ester(109-94-4)
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
Hazard Codes : F,Xn
Risk Statements : 11-20/22-36/37
Safety Statements : 9-16-24-26-33
RIDADR : UN 1190 3/PG 2
WGK Germany : 1
RTECS : LQ8400000
TSCA : Yes
HazardClass : 3
PackingGroup : II
Hazardous Substances Data: 109-94-4(Hazardous Substances Data)
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H225 Highly Flammable liquid and vapour Flammable liquids Category 2 Danger P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning P264, P270, P301+P312, P330, P501
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning P264, P280, P305+P351+P338,P337+P313P
H332 Harmful if inhaled Acute toxicity,inhalation Category 4 Warning P261, P271, P304+P340, P312
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P243 Take precautionary measures against static discharge.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P262 Do not get in eyes, on skin, or on clothing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P370+P378 In case of fire: Use … for extinction.
P403 Store in a well-ventilated place.
P403+P235 Store in a well-ventilated place. Keep cool.

Ethyl formate Chemical Properties,Usage,Production

Chemical Properties
colourless liquid with an aromatic odour
ChEBI: A formate ester resulting from the formal condensation of formic acid with ethanol.
General Description
A clear colorless liquid with a pleasant odor. Flash point -4°F. Less dense than water. Vapors heavier than air.
Air & Water Reactions
Highly flammable. Soluble in water. Slowly decomposed by water to formic acid, a corrosive material and ethyl alcohol, another flammable liquid.
Reactivity Profile
Ethyl formate is an ester. Esters react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides. Ethyl formate is incompatible with the following: Nitrates; strong oxidizers, alkalis & acids [Note: Decomposes slowly in water to form ethyl alcohol and formic acid.] .
Health Hazard
Inhalation of vapor causes slight irritation of the eyes and rapidly increasing irritation of the nose. High concentrations cause deep narcosis within a few minutes followed by death within a few hours. Contact with liquid causes moderate irritation of eyes and mild irritation of skin. Ingestion causes irritation of mouth and stomach; may cause deep narcosis and death if not treated.
Fire Hazard
Behavior in Fire: Vapor is heavier than air and may travel long distance to a source of ignition and flash back.
Ethyl formate Preparation Products And Raw materials
Raw materials
Etanol Calcium chloride Formic acid Aluminium chloride hexahydrate
Preparation Products
Thiamine chloride 4-CHLORO-2-(TRIFLUOROMETHYL)PYRIMIDINE 4-CHLORO-1-ETHYL-3-METHYL-1H-PYRAZOLE-5-CARBOXYLIC ACID ETHYL ESTER 2-AMINO-4-METHYLOXAZOLE 1-Methyl-2-imidazolecarboxaldehyde METHYL 3-AMINO-6-METHYLTHIOPHENO[2,3-B]PYRIDINE-2-CARBOXYLATE Ninhydrin hydrate 4,5,6-TRIAMINOPYRIMIDINE 2-Chloro-6-methyl-3-pyridinecarbonitrile AMITRAZ METABOLITE HYDROCHLORIDE 5-Acetamidomethyl-4-Amino-2-Methyl pyrimidine 6-Methyl-1H-pyrazolo[3,4-b]pyridin-3-amine 5-PROPYL-2-THIOURACIL Methyl 3-amino-4-phenylthiophene-2-carboxylate 7-Aminoisoquinoline 1H-1,2,3-Triazolo[4,5-d]pyrimidin-7-amine Tropic acid 5-BROMO-4-HYDROXY-2-METHYLPYRIMIDINE 4-HYDROXY-2-METHYLPYRIMIDINE 2-AMINO-PYRIMIDINE-5-CARBOXYLIC ACID ETHYL ESTER 5-N-PROPYLURACIL 7-Bromoisoquinoline 4-METHOXY-3-BUTEN-2-ONE 4-METHYLPYRIMIDIN-2-OL HYDROCHLORIDE α-Dimethoxymethyl-methoxypropionitrile alpha,alpha-Diphenyl-L-prolinol 4,5-DIBROMOTHIOPHENE-2-CARBOXALDEHYDE 2-(TRIFLUOROMETHYL)PYRIMIDIN-4-AMINE 4-chloro-5-fluoropyrimidine EPOSTANE 3-Cyano-6-methyl-2(1H)-pyridinone A-(HYDROXYMETHYL)BENZENACETIC ACID METHYL ESTER 1,1-Diethoxy-3,7-dimethylocta-2,6-diene 3,4-DIHYDROISOQUINOLINE 4-Hydroxy-2-(trifluoromethyl)pyrimidine 4-Chloropyridine-3-carboxaldehyde N-Methylformamide 7-NITRO-3,4-DIHYDROISOQUINOLINE 1-(PHENYLSULFONYL)-1H-INDOLE-2-CARBALDEHYDE 2-Aminopyrimidine-5-carbonitrile
Ethyl formate Suppliers      Global( 219)Suppliers     
Supplier Tel Fax Email Country ProdList Advantage
Shenzhen Sendi Biotechnology Co.Ltd. 0755-23311925 18102838259
0755-23311925 CHINA 3230 55
Shanghai Aladdin Bio-Chem Technology Co.,LTD 021-20337333/400-620-6333
021-50323701 China 28587 65
J & K SCIENTIFIC LTD. 400-666-7788 +86-10-82848833
+86-10-82849933; China 96832 76
Meryer (Shanghai) Chemical Technology Co., Ltd. +86-(0)21-61259100(Shanghai) +86-(0)755-86170099(ShenZhen) +86-(0)10-62670440(Beijing)
+86-(0)21-61259102(Shanghai) +86-(0)755-86170066(ShenZhen) +86-(0)10-88580358(Beijing) China 40403 62
3B Pharmachem (Wuhan) International Co.,Ltd. 86-21-50328103 * 801、802、803、804 Mobile:18930552037
86-21-50328109 China 15950 69
Alfa Aesar 400-610-6006; 021-67582000
021-67582001/03/05 China 30315 84
TCI (Shanghai) Development Co., Ltd. 800-988-0390
021-67121385 China 22833 81
Beijing dtftchem Technology Co., Ltd. 13651141086; 86(10)60275028、60275820
86 (10) 60270825 China 1443 62
Energy Chemical 021-58432009 / 400-005-6266
021-58436166-800 China 44198 61
Beijing Ouhe Technology Co., Ltd +86-10-4006331231;+86-10-51280831;+86-10-82967028
+86-10-82967029 China 10814 60
109-94-4(Ethyl formate)Related Search:
ZINC FORMATE TRIS(TRIMETHYLSILYL) PHOSPHATE Dimethyl succinate Ethyl benzoate Ethylparaben Ethyl chloroformate Benzocaine ISOXADIFEN-ETHYL Trinexapac-ethyl Ethyl isocyanoacetate DL-Ethyl 2-bromobutyrate Ethyl 2-bromopropionate Ethyl 2-bromoisobutyrate Formic acid Diethyl ether Etanol Ethyl formate(ortho) FORMATE ION CHROMATOGRAPHY STANDARD
109-94-4 Analytical Chromatography Product Catalog Alphabetic Analytical Standards FEMA 2434 FORMIC ACID ETHYL ESTER FORMIC ETHER ETHYL METHANOATE ETHYL FORMATE EQ - EZ Aethylformiat Areginal Ethyl ester of formic acid Ethyle(formiate d') ethyle(formiated’) ethyle(formiated’)(french) Ethylester kyseliny mravenci ethylesterkyselinymravenci ethylformate(dot) Ethylformiaat Ethylformic ester ethylformicester Etile(formiato di) etile(formiatodi) femanumber2434. formiated’ethyle HCOOC2H5 Methanoicacid,ethylester Methanoicacidethylester Mrowczan etylu mrowczanetylu mrowczanetylu(polish) Solvents for Spectrophotometry Solvents for HPLC & Spectrophotometry ETHYL FORMATE NATURAL ETHYL FORMATE 97+% FCC ETHYL FORMATE, STANDARD FOR GC ETHYL FORMATE REAGENT GRADE 97% EthylFormateForSynthesis Ethyl formate (technical) Ethyl formate, 98+% ethyl formiate ETHYLFORMATE,REAGENT Ethylformiat 109944 Organics Analytical Chemistry Solvents for HPLC & Spectrophotometry Solvents for Spectrophotometry ETHYL FORMATE pure Formic acid ethyl HCO2CH2CH3 Ethyl formate >=99.0% Ethyl methanoateFormic acid ethyl ester Ethyl formate,Formic acid ethyl ester Ethyl formate, AcroSeal, Extra Dry, 98+% Ethyl formate, pure, 98+% Ethyl ForMate [for SpectrophotoMetry]
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