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ChemicalBook >> CAS DataBase List >> LITHIUM TETRAMETHYLPIPERIDIDE

LITHIUM TETRAMETHYLPIPERIDIDE

LITHIUM TETRAMETHYLPIPERIDIDE price.
  • $28 - $2480.5
  • Product name: LITHIUM TETRAMETHYLPIPERIDIDE
  • CAS: 38227-87-1
  • MF: C9H20LiN
  • MW: 149.21
  • EINECS:684-475-5
  • MDL Number:MFCD00015910
  • Synonyms:LITHIUM TETRAMETHYLPIPERIDIDE;Lithium·2,2,6,6-tetramethylpiperidine;LithiuM 2,2,6,6-tetraMethylpiperidide 97%;2,2,6,6-Tetramethylpiperidine lithium salt (1:1);Piperidine,2,2,6,6-tetramethyl-, lithium salt (1:1);ithium 2,2,6,6-tetramethyL;"2,2,6,6-tetramethylpiperidine lithium";Piperidine, 2,2,6,6-tetramethyl-, lithium salt
6 prices
Selected condition:
Brand
  • Aaron Chemicals
  • American Custom Chemicals Corporation
  • Sigma-Aldrich
Package
  • 1g
  • 10g
  • 25G
  • 250G
  • ManufacturerAaron Chemicals
  • Product numberAR003RZO
  • Product descriptionLithium 2,2,6,6-tetramethylpiperidide 97%
  • Packaging10g
  • Price$177
  • Updated2021-12-16
  • Buy
  • ManufacturerAaron Chemicals
  • Product numberAR003RZO
  • Product descriptionLithium 2,2,6,6-tetramethylpiperidide 97%
  • Packaging1g
  • Price$28
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberOGM0000655
  • Product descriptionLITHIUM 2,2,6,6-TETRAMETHYLPIPERIDIDE 95.00%
  • Packaging25G
  • Price$1275.81
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberOGM0000655
  • Product descriptionLITHIUM 2,2,6,6-TETRAMETHYLPIPERIDIDE 95.00%
  • Packaging250G
  • Price$2480.5
  • Updated2021-12-16
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number735353
  • Product descriptionLithium 2,2,6,6-tetramethylpiperidide 97%
  • Packaging10g
  • Price$243
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number735353
  • Product descriptionLithium 2,2,6,6-tetramethylpiperidide 97%
  • Packaging25g
  • Price$284
  • Updated2024-03-01
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Aaron Chemicals AR003RZO Lithium 2,2,6,6-tetramethylpiperidide 97% 10g $177 2021-12-16 Buy
Aaron Chemicals AR003RZO Lithium 2,2,6,6-tetramethylpiperidide 97% 1g $28 2021-12-16 Buy
American Custom Chemicals Corporation OGM0000655 LITHIUM 2,2,6,6-TETRAMETHYLPIPERIDIDE 95.00% 25G $1275.81 2021-12-16 Buy
American Custom Chemicals Corporation OGM0000655 LITHIUM 2,2,6,6-TETRAMETHYLPIPERIDIDE 95.00% 250G $2480.5 2021-12-16 Buy
Sigma-Aldrich 735353 Lithium 2,2,6,6-tetramethylpiperidide 97% 10g $243 2024-03-01 Buy
Sigma-Aldrich 735353 Lithium 2,2,6,6-tetramethylpiperidide 97% 25g $284 2024-03-01 Buy

Properties


Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H261 In contact with water releases flammable gas Substances And Mixtures Which, In Contact With Water,Emit Flammable Gases Category 2
Category 3
Danger
Warning
GHS hazard pictograms P231+P232, P280, P370+P378,P402+P404, P501
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
Precautionary statements:
P231+P232 Handle under inert gas. Protect from moisture.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P310 Immediately call a POISON CENTER or doctor/physician.
P422 Store contents under …

Description

Lithium 2,2,6,6-tetramethylpiperidide is a strong base and can be used:
  • For the synthesis of enamines from terminal epoxides through trans-α-lithiated epoxide as an intermediate.
  • For ortholithiation of arenes such as 1,3-bis(trifluoromethyl)benzene, 4,4-dimethyl-2-phenyl-2-oxazoline, 1,4-bis(trifluoromethyl)benzene and 1,3-dimethoxybenzene.
  • In combination with Lewis donor ligand, N,N,N′,N′-tetramethylethylenediamine (TMEDA) for deprotonative metalation of methoxy-substituted arenes.{21]


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