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ChemicalBook >> CAS DataBase List >> Methanesulfonic acid

Methanesulfonic acid

Methanesulfonic acid price.
  • $10 - $4328.79
  • Product name: Methanesulfonic acid
  • CAS: 75-75-2
  • MF: CH4O3S
  • MW: 96.11
  • EINECS:200-898-6
  • MDL Number:MFCD00007518
  • Synonyms:METHANESULFONIC ACID 4.0 M WITH 0.2%*(W/ V) TRYPTAMI;MethanesulfonicAcidForSynthesis;Methanesulfonic acid, 70% aq. soln.;Methanesulfonic acid, 98+%;LutropurMSA;Methanesulfonic acid, 70% solution in water, pure;METHANESULFONICACID,TECHNICAL;Methansulfonsure
41 prices
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  • AK Scientific
  • Alfa Aesar
  • American Custom Chemicals Corporation
  • Apolloscientific
  • Medical Isotopes, Inc.
  • Oakwood
  • Sigma-Aldrich
  • SynQuest Laboratories
  • TCI Chemical
  • TRC
  • Usbiological
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  • ManufacturerAK Scientific
  • Product numberJ54717
  • Product descriptionMethanesulfonicacid(MSA)
  • Packaging25g
  • Price$20
  • Updated2021-12-16
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberA17803
  • Product descriptionMethanesulfonic acid, 70% aq. soln.
  • Packaging100ml
  • Price$15.65
  • Updated2024-03-01
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberA13565
  • Product descriptionMethanesulfonic acid, 98+%
  • Packaging100g
  • Price$38.4
  • Updated2024-03-01
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberA17803
  • Product descriptionMethanesulfonic acid, 70% aq. soln.
  • Packaging500ml
  • Price$51.3
  • Updated2024-03-01
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberA13565
  • Product descriptionMethanesulfonic acid, 98+%
  • Packaging500g
  • Price$66.4
  • Updated2024-03-01
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberA17803
  • Product descriptionMethanesulfonic acid, 70% aq. soln.
  • Packaging2500ml
  • Price$172
  • Updated2024-03-01
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberA13565
  • Product descriptionMethanesulfonic acid, 98+%
  • Packaging2500g
  • Price$262
  • Updated2024-03-01
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  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberCHM0066298
  • Product descriptionMETHANE SULFONIC ACID 95.00%
  • Packaging25G
  • Price$1106.03
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberCHM0066298
  • Product descriptionMETHANE SULFONIC ACID 95.00%
  • Packaging500G
  • Price$4328.79
  • Updated2021-12-16
  • Buy
  • ManufacturerApolloscientific
  • Product numberOR322096
  • Product descriptionMethanesulfonic Acid 98+%
  • Packaging100g
  • Price$24
  • Updated2021-12-16
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  • ManufacturerMedical Isotopes, Inc.
  • Product numberD645
  • Product descriptionMethanesulfonicAcid-d4
  • Packaging1g
  • Price$495
  • Updated2021-12-16
  • Buy
  • ManufacturerOakwood
  • Product number152800
  • Product descriptionMethanesulfonic Acid 99%
  • Packaging5g
  • Price$10
  • Updated2021-12-16
  • Buy
  • ManufacturerOakwood
  • Product number152800
  • Product descriptionMethanesulfonic Acid 99%
  • Packaging25g
  • Price$15
  • Updated2021-12-16
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number471348
  • Product descriptionMethanesulfonic acid solution 70 wt. % in H2O
  • Packaging100ml
  • Price$41.5
  • Updated2024-03-01
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  • ManufacturerSigma-Aldrich
  • Product number8.06022
  • Product descriptionMethanesulfonic acid for synthesis
  • Packaging5ml
  • Price$47.6
  • Updated2024-03-01
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  • ManufacturerSigma-Aldrich
  • Product number55517
  • Product descriptionMethanesulfonic acid concentrate 0.1 M CH3SO3H in water (0.1N), eluent concentrate for IC
  • Packaging1l
  • Price$52.4
  • Updated2024-03-01
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
AK Scientific J54717 Methanesulfonicacid(MSA) 25g $20 2021-12-16 Buy
Alfa Aesar A17803 Methanesulfonic acid, 70% aq. soln. 100ml $15.65 2024-03-01 Buy
Alfa Aesar A13565 Methanesulfonic acid, 98+% 100g $38.4 2024-03-01 Buy
Alfa Aesar A17803 Methanesulfonic acid, 70% aq. soln. 500ml $51.3 2024-03-01 Buy
Alfa Aesar A13565 Methanesulfonic acid, 98+% 500g $66.4 2024-03-01 Buy
Alfa Aesar A17803 Methanesulfonic acid, 70% aq. soln. 2500ml $172 2024-03-01 Buy
Alfa Aesar A13565 Methanesulfonic acid, 98+% 2500g $262 2024-03-01 Buy
American Custom Chemicals Corporation CHM0066298 METHANE SULFONIC ACID 95.00% 25G $1106.03 2021-12-16 Buy
American Custom Chemicals Corporation CHM0066298 METHANE SULFONIC ACID 95.00% 500G $4328.79 2021-12-16 Buy
Apolloscientific OR322096 Methanesulfonic Acid 98+% 100g $24 2021-12-16 Buy
Medical Isotopes, Inc. D645 MethanesulfonicAcid-d4 1g $495 2021-12-16 Buy
Oakwood 152800 Methanesulfonic Acid 99% 5g $10 2021-12-16 Buy
Oakwood 152800 Methanesulfonic Acid 99% 25g $15 2021-12-16 Buy
Sigma-Aldrich 471348 Methanesulfonic acid solution 70 wt. % in H2O 100ml $41.5 2024-03-01 Buy
Sigma-Aldrich 8.06022 Methanesulfonic acid for synthesis 5ml $47.6 2024-03-01 Buy
Sigma-Aldrich 55517 Methanesulfonic acid concentrate 0.1 M CH3SO3H in water (0.1N), eluent concentrate for IC 1l $52.4 2024-03-01 Buy

Properties

Melting point :17-19 °C (lit.)
Boiling point :167 °C/10 mmHg (lit.)
Density :1.475-1.485 g/mL at 20 °C 1.481 g/mL at 25 °C (lit.)
vapor density :3.3 (vs air)
vapor pressure :1 mm Hg ( 20 °C)
refractive index :n20/D 1.429(lit.)
Flash point :>230 °F
storage temp. :2-8°C
solubility :water: soluble1,000 g/L at 20°C
pka :-2.6(at 25℃)
form :Solution
Specific Gravity :1.48 (18/4℃)
color :brown
Water Solubility :Miscible with water. Slightly miscible with benzene and toluene. Immiscible with paraffins.
λmax :λ: 240-320 nm Amax: <0.4
Sensitive :Light Sensitive & Hygroscopic
Merck :14,5954
BRN :1446024
Stability :Stable. Moisture sensitive. Incompatible with amines, bases, water, common metals. Releases a substantial amount of heat when diluted with water (add acid to water with care if diluting).
InChIKey :AFVFQIVMOAPDHO-UHFFFAOYSA-N
CAS DataBase Reference :75-75-2(CAS DataBase Reference)
NIST Chemistry Reference :CH3SO3H(75-75-2)
EPA Substance Registry System :Methanesulfonic acid (75-75-2)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H290 May be corrosive to metals Corrosive to Metals Category 1 Warning GHS hazard pictograms P234, P390, P404
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning GHS hazard pictograms P264, P270, P301+P312, P330, P501
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P234 Keep only in original container.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312 IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

Methanesulfonic acid is used as a catalyst in organic reactions namely esterification, alkylation and condensation reactions due to its non- volatile nature and solubility in organic solvents. It is also involved in the production of starch esters, wax oxidate esters, benzoic acid esters, phenolic esters, or alkyl esters. It reacts with sodium borohydride in presence of polar solvent tetrahydrofuran to prepare borane-tetrahydrofuran complex. It finds application in batteries, because of its purity and chloride absence. In pharmaceutical industry, it is used for the manufacturing of active pharmaceutical ingredients like telmisartan and eprosartan. It is useful in ion chromatography and is a source of carbon and energy for some gram-negative methylotropic bacteria.It is involved in the deprotection of peptides.

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