| Company Name: |
Shanghai Anyinuo Biomedical Technology Co., Ltd. Gold
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| Tel: |
021-34625901 18018851262; |
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420970979@qq.com |
| Products Intro: |
Product Name:(S)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis(di-2-furylphosphine)
CAS:145214-59-1
Purity:>=98% Package:100mg;250mg;500mg;1g;10g;100g;1kg
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| Company Name: |
J & K SCIENTIFIC LTD.
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| Tel: |
18210857532; 18210857532 |
| Email: |
jkinfo@jkchemical.com |
| Products Intro: |
Product Name:(S)-(-)-2,2'-Bis(di-2-furanylphosphino)-6,6'-dimethoxy-1,1'-biphenyl, min. 97%
CAS:145214-59-1
Purity:min. 97% Package:100mg;10g;2g;500mg
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| Company Name: |
Shanghai Aladdin Bio-Chem Technology Co.,LTD
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| Tel: |
400-6206333 13167063860 |
| Email: |
anhua.mao@aladdin-e.com |
| Products Intro: |
Product Name:(S)-(-)-2,2''-Bis(di-2-furanylphosphino)-6,6''-dimethoxy-1,1''-biphenyl
CAS:145214-59-1
Purity:≥97% Package:100mg/RMB 722.90;500mg/RMB 2864.90
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| | (S)-(-)-2,2'-Bis(di-2-furanylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% Basic information | | Reaction |
| Product Name: | (S)-(-)-2,2'-Bis(di-2-furanylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% | | Synonyms: | (S)-(-)-2,2'-Bis(di-2-furanylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%;(S)-(6,6μ-Dimethoxybiphenyl-2,2μ-diyl)bis(di-2-furylphosphine);(S)-2-Furyl-MeOBIPHEP, SL-A108-2, (S)-(-)-2,2μ-Bis(di-2-furylphosphino)-6,6μ-dimethoxy-1,1μ-biphenyl;(S)-(-)-2,2''-BIS(DI-2-FURANYLPHOSPHINO)-6,6''-DIMETHOXY-1,1''-BIPHENYL, MIN. 97%;(S)-(-)-2,2'-Bis(di-2-furanylphosphino)-6,6'-dimethoxy-1,1'-biphenyl;SL-A108-2;(S)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis(di-2-furylphosphine) >=97%, optical purity ee: >=99%;[2-[2-[bis(furan-2-yl)phosphanyl]-6-methoxyphenyl]phenyl]-bis(furan-2-yl)phosphane | | CAS: | 145214-59-1 | | MF: | C30H24O6P2 | | MW: | 542.46 | | EINECS: | | | Product Categories: | Chiral Phosphine;MeOBIPHEP Series | | Mol File: | 145214-59-1.mol |  |
| | (S)-(-)-2,2'-Bis(di-2-furanylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% Chemical Properties |
| Boiling point | 587.5±50.0 °C(Predicted) | | storage temp. | 2-8°C, protect from light, stored under nitrogen | | form | Powder | | color | off-white | | Stability: | store cold | | InChI | InChI=1S/C30H24O6P2/c1-31-21-9-3-11-23(37(25-13-5-17-33-25)26-14-6-18-34-26)29(21)30-22(32-2)10-4-12-24(30)38(27-15-7-19-35-27)28-16-8-20-36-28/h3-20H,1-2H3 | | InChIKey | ABGYJVGTLXSMBM-UHFFFAOYSA-N | | SMILES | C1C=CC(P(C2OC=CC=2)C2OC=CC=2)=C(C2C(P(C3OC=CC=3)C3OC=CC=3)=CC=CC=2OC)C=1OC | | CAS DataBase Reference | 145214-59-1 |
| WGK Germany | 3 | | HS Code | 29321900 | | Storage Class | 11 - Combustible Solids |
| | (S)-(-)-2,2'-Bis(di-2-furanylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% Usage And Synthesis |
| Reaction | In many respects the catalytic profile of the MeO-BIPHEP ligands is similar to that of other atropisomeric diphosphines such as binap and its many analogs. The nature of the PR2 group strongly influences the catalytic performance of the metal complexes. The rhodium and ruthenium MeO-BIPHEP catalysts are highly effective for the hydrogenation of various C=O, C=C and C=N bonds and several synthetically useful C-C coupling reactions.
Stereocontrol in palladium-catalyzed propargylic substitutions: kinetc resolution to give enantioenriched 1,5-enynes and propargyl acetates.
Study of enantioselective catalysis of nitroso-Diels-Alder reaction on solid support.
| | Chemical Properties | White powder | | Uses | Atropisomeric MeOBIPHEP ligands | | General Description | sold in collaboration with Solvias AG |
| | (S)-(-)-2,2'-Bis(di-2-furanylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% Preparation Products And Raw materials |
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