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| | 1,2-BIS(DIMETHYLPHOSPHINO)ETHANE Basic information |
| | 1,2-BIS(DIMETHYLPHOSPHINO)ETHANE Chemical Properties |
| Melting point | 0℃ | | Boiling point | 180 °C(lit.) | | density | 0.9 g/mL at 25 °C(lit.) | | refractive index | n20/D 1.507(lit.) | | Fp | -16 °C | | storage temp. | Flammables area | | form | liquid | | Specific Gravity | 0.90.900 | | color | colorless | | Sensitive | Air & Moisture Sensitive | | BRN | 1732994 | | InChI | 1S/C6H16P2/c1-7(2)5-6-8(3)4/h5-6H2,1-4H3 | | InChIKey | ZKWQSBFSGZJNFP-UHFFFAOYSA-N | | SMILES | CP(C)CCP(C)C | | CAS DataBase Reference | 23936-60-9(CAS DataBase Reference) |
| Hazard Codes | F,Xi | | Risk Statements | 11-36/37/38 | | Safety Statements | 16-26-36-36/37/39 | | RIDADR | UN 1993 3/PG 2 | | WGK Germany | 3 | | F | 10-13-23 | | TSCA | No | | HazardClass | 3 | | PackingGroup | II | | HS Code | 29310099 | | Storage Class | 3 - Flammable liquids | | Hazard Classifications | Eye Irrit. 2 Flam. Liq. 2 Skin Irrit. 2 STOT SE 3 |
| | 1,2-BIS(DIMETHYLPHOSPHINO)ETHANE Usage And Synthesis |
| Chemical Properties | Colorless to light yellow liqui | | Uses | 1,2-Bis(dimethylphosphino)ethane (dmpe) may be employed as ligand in the preparation of cis-arylmethyl(dmpe) nickel(II) complexes. | | General Description | 1,2-Bis(dimethylphosphino)ethane (dmpe) is a polydentate phosphine ligand. Synthesis of 1,2-bis(dimethylphosphino)ethane has been reported. It reacts with ZrCl2 to afford ZrCl4(dmpe)2 complexes. | | reaction suitability | reaction type: Buchwald-Hartwig Cross Coupling Reaction reaction type: Heck Reaction reaction type: Hiyama Coupling reaction type: Negishi Coupling reaction type: Sonogashira Coupling reaction type: Stille Coupling reaction type: Suzuki-Miyaura Coupling reagent type: ligand |
| | 1,2-BIS(DIMETHYLPHOSPHINO)ETHANE Preparation Products And Raw materials |
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