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2-(CHLOROMETHYL)ALLYLTRICHLOROSILANE

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2-(CHLOROMETHYL)ALLYLTRICHLOROSILANE Basic information
Product Name:2-(CHLOROMETHYL)ALLYLTRICHLOROSILANE
Synonyms:2-(CHLOROMETHYL)-3-(TRICHLOROSILYL)PROPENE;2-(CHLOROMETHYL)ALLYLTRICHLOROSILANE;TRICHLORO[2-(CHLOROMETHYL)ALLYL]SILANE;trichloro-[2-(chloromethyl)prop-2-enyl]silane;Trichloro[2-(chloromethyl)allyl]silane 98%;richloro-[2-(chloromethyl)prop-2-enyl]silane;Trichloro[2-(chloromethyl)-2-propen-1-yl]silane;Silane, trichloro[2-(chloromethyl)-2-propen-1-yl]-
CAS:18147-84-7
MF:C4H6Cl4Si
MW:223.99
EINECS:
Product Categories:POSS? Precursors and Intermediates;RSiCl3Self Assembly&Contact Printing;Self-Assembly Materials;Silanes;Silsesquioxanes: POSS? Nanohybrids
Mol File:18147-84-7.mol
2-(CHLOROMETHYL)ALLYLTRICHLOROSILANE Structure
2-(CHLOROMETHYL)ALLYLTRICHLOROSILANE Chemical Properties
Boiling point 31 °C0.1 mm Hg(lit.)
density 1.346 g/mL at 25 °C(lit.)
refractive index n20/D 1.484(lit.)
Fp 181 °F
Specific Gravity1.3473
Hydrolytic Sensitivity8: reacts rapidly with moisture, water, protic solvents
InChI1S/C4H6Cl4Si/c1-4(2-5)3-9(6,7)8/h1-3H2
InChIKeySJFJNNLIAXEOSE-UHFFFAOYSA-N
SMILESClCC(=C)C[Si](Cl)(Cl)Cl
Safety Information
Hazard Codes C
Risk Statements 14-34
Safety Statements 26-27-36/37/39-45
RIDADR UN 2987 8/PG 2
WGK Germany 3
TSCA No
Storage Class8A - Combustible corrosive hazardous materials
Hazard ClassificationsSkin Corr. 1B
MSDS Information
ProviderLanguage
SigmaAldrich English
2-(CHLOROMETHYL)ALLYLTRICHLOROSILANE Usage And Synthesis
UsesTrichloro[2-(chloromethyl)-2-propen-1-yl]silane is an intermediate used in the synthesis of 2-(Chloromethyl)allyl-trimethylsilane (C371430), which is one of the reagents to synthesize Leucasandrolide A Macrolide (I) via Mukaiyama aldol coupling.2-(Chloromethyl)allyl-trimethylsilane was used in catalytic Sakurai reaction of α,β-enones.
2-(CHLOROMETHYL)ALLYLTRICHLOROSILANE Preparation Products And Raw materials
Tag:2-(CHLOROMETHYL)ALLYLTRICHLOROSILANE(18147-84-7) Related Product Information
3-Chloro-2-methylpropene Isobutylene 1-Methylcyclopropene Methacryloyl chloride METHYLSTYRENE PROPYLENE 2-(CHLOROMETHYL)ALLYLTRICHLOROSILANE 3-Chloropropyltrichlorosilane ALLYLTRICHLOROSILANE 2-(CHLOROMETHYL)ALLYLTRICHLOROSILANE ALLYLDICHLOROSILANE