氯化氰

氯化氰

中文名称氯化氰
中文同义词氯甲腈;氯化氰;氰化氯
英文名称Cyanogen chloride
英文同义词Cyanogen chloride ((CN)Cl);Chlorine cyanide;Chlorocyan;chlorocyanogen;Cyanogen chloride;Chloro cyanide;Cyan chloride;RCRA waste number P-033
CAS号506-77-4
分子式CClN
分子量61.47
EINECS号208-052-8
相关类别
Mol文件506-77-4.mol
结构式氯化氰 结构式

氯化氰 性质

熔点-6°
沸点14°C
密度1.186
蒸气压60kPa at 0℃
溶解度溶于水、乙醇、乙醚
形态无色气体
颜色无色液体或气体
水溶解性soluble H2O, ether, alcohol [MER06]
比热容Cp(gas): 0.73 J/(g·K), at 25℃
Henry's Law Constant1.2×10-2 mol/(m3Pa) at 25℃, Hilal et al. (2008)
暴露限值MAC:0.75 mg/m3
LogP0.64 at 20℃
CAS 数据库506-77-4
NIST化学物质信息Cyanogen chloride(506-77-4)
EPA化学物质信息Cyanogen chloride (506-77-4)

氯化氰 用途与合成方法

用于制备双酚A氰酸酯可用作有机合成和医药中间体,用于制备氯磺酰异氰酸酯。
类别
有害气体
毒性分级
中毒
急性毒性
吸入-大鼠LC50:5400毫克/立方米/3分;吸入-小鼠LC50:3000毫克/立米/30秒
刺激数据
吸入- 人 2.5 毫克/ 立方米 重度; 120 毫克/ 立方米 死亡
爆炸物危险特性
受热、日晒钢瓶可爆; 泄漏放出剧毒烟雾
可燃性危险特性
遇水生成毒性极强的氢氰酸; 燃烧产生有毒氰化物和氯化物烟雾
储运特性
库房通风低温干燥; 轻装轻卸
灭火剂
二氧化碳、砂土
职业标准
TWA 0.3 毫克/ 立方米; STEL 0.75 毫克/ 立方米

安全信息

危险品标志T
职业暴露限值Ceiling: 0.3 ppm (0.6 mg/m3)
危险品运输编号UN 1589 (CYANOGEN CHLORIDE, STABILIZED)
TSCATSCA listed
危险等级2.3
毒害物质数据506-77-4(Hazardous Substances Data)
毒性CK may polymerize violently if contaminated with hydrogen chloride or ammonium chloride. Upon heating, it decomposes, producing toxic and corrosive fumes of hydrogen cyanide, hydrochloric acid, and nitrogen oxides. Hazardous polymerization can occur. Cyanogen chloride will react slowly with water to form hydrogen chloride gas. It acts on the body in two ways. Systemic effects of CK are much like those of hydrogen cyanide. Additionally, it causes irritation of the eyes, upper respiratory tract, and lungs. Eye irritation results in tearing. CK, like AC, stimulates the respiratory system and rapidly paralyzes it. Exposure is followed by immediate, intense irritation of the nose, throat, and eyes, with coughing, tightness in the chest, and lacrimation. This is followed by dizziness and increasing difficulty breathing. Unconsciousness comes next, with failing respiration and death within a few minutes. Convulsions, retching, and involuntary urination and defecation may occur. If these effects are not fatal, the signs and symptoms of pulmonary edema may develop. There may be repeated coughing, with profuse foamy sputum, rales in the chest, severe dyspnea, and distinct cyanosis. Recovery from the systemic effects is usually as prompt as in AC poisoning. However, a higher incidence of residual damage to the central nervous system should be expected. Based upon the concentration of the cyanogen chloride to which the victim has been exposed, the pulmonary effects may evolve instantly or may be delayed until the systemic effects have subsided. Consequently, early prognosis must be cautious.

MSDS信息

提供商 语言
中文
"氯化氰"相关产品信息
氯化钙 氯化胆碱 三氯化铁 氰化亚铜 氯化钠 磺酰氯 氯化铵 二氧化氯 聚氯乙烯 氯化钾 氢氰酸 氰化物 氰 三聚氯氰 Cyanide 氯化花青素 氯化氰 二氯甲烷
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