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alpha-Hexylcinnamaldehyde manufacturers

alpha-Hexylcinnamaldehyde Basic information
Product Name:alpha-Hexylcinnamaldehyde
Synonyms:(2Z)-2-Hexyl-3-phenyl-2-propenal;.alpha.-hexylcinnamaldehyde(positivecontrolchemical);2-(phenylmethylene)-octana;2-(Phenylmethylene)octanal,a-Hexyl-phenylacrolein;A-N-HEXYL-B-PHENYLACROLEIN;ALPHA-HEXYLCINNAMIC ALDEHYDE;ALPHA-HEXYLCINNAMALDEHYDE;ALPHA-N-HEXYLCINNAMALDEHYDE
Product Categories:Aldehydes;C10 to C21;Carbonyl Compounds;aldehyde Flavor;Pharmaceutical Intermediates;Alphabetical Listings;Flavors and Fragrances;G-H;11
Mol File:101-86-0.mol
alpha-Hexylcinnamaldehyde Structure
alpha-Hexylcinnamaldehyde Chemical Properties
Boiling point 174-176 °C/15 mmHg (lit.)
density 0.95 g/mL at 25 °C (lit.)
refractive index n20/D 1.55(lit.)
Fp 200 °F
storage temp. -20°C
solubility water: soluble0.005g/L at 25°C
form Oil
color Clear Yellow
Odorat 100.00 %. fresh floral green jasmin herbal waxy
Odor Typefloral
JECFA Number686
CAS DataBase Reference101-86-0(CAS DataBase Reference)
NIST Chemistry ReferenceOctanal, 2-(phenylmethylene)-(101-86-0)
EPA Substance Registry System.alpha.-Hexylcinnamaldehyde (101-86-0)
Safety Information
Hazard Codes C,Xi
Risk Statements 36/37/38-34-43-52/53
Safety Statements 26-36/37/39-45-36-36/37-61
RIDADR UN 3265 8/PG 3
WGK Germany 2
RTECS GD6560000
HS Code 29122990
toxicityThe acute oral LD50 value in rats was reported as 3.1 g/kg (2.45-3.75 g/kg) (Moreno, 1971). The acute dermal LD50 value in rabbits was reported as > 3 g/kg (Moreno, 1971).
MSDS Information
SigmaAldrich English
alpha-Hexylcinnamaldehyde Usage And Synthesis
Descriptionα-Hexylcinnamaldehyde has a jasmine-like odor, particularly on dilution. May be synthesized by condensation of octylaldehyde with benzaldehyde.
Chemical Propertiesalpha-Hexylcinnamaldehyde is a yellow liquid with a mild, slightly fatty, floral, somewhat herbal odor, and a distinct jasmine note. Similarly to the ??-amyl homolog, ??-hexylcinnamaldehydemust be protected against oxidation by the addition of stabilizers. It is prepared in a manner similar to that of ??-amylcinnamaldehyde by alkaline condensation of excess benzaldehyde with octanal (instead of heptanal). ??-Hexylcinnamaldehyde is widely used in flower compositions (e.g., jasmine and gardenia) and, because of its stability to alkali, in soap perfumes.
Chemical PropertiesPale-yellow liquid; jasminelike odor, particularly on dilution. Soluble in most fixed oils and in mineral oil; insoluble in glycerol and in propylene glycol.
Chemical PropertiesHexyl cinnamaldehyde has a jasmine-like odor, particularly on dilution.
OccurrenceReported found in cooked, scented rice.
Useshexyl cinnamal is also known as hexyl cinnamic aldehyde. It is a fragrance that provides a floral, jasmine-like scent.
Usesα-Hexylcinnamaldehyde is characterized by a typical floral scent, which makes them suitable to be used as fragrances in personal care (perfumes, creams, shampoos, etc.) and household products. It has been also used as flavouring additive in food and pharmaceutical industry.
DefinitionChEBI: A member of the class of cinnamaldehydes carrying a hexyl substituent at the alpha-position.
PreparationBy condensation of octylaldehyde with benzaldehyde
Taste threshold valuesTaste characteristics at 5 ppm: sweet, waxy, floral, green, citrus and fruity nuances
General DescriptionSolubilization of α-hexylcinnamaldehyde by the ionic surfactants, sodium dodecyl sulfate and dodecyltrimethylammonium chloride and a non-ionic surfactant such as dodecyl polyoxyethylene ethers has been investigated.
Contact allergensHexyl cinnamic aldehyde is a fragrance allergen. Its presence has to be mentioned by name in cosmetics within the EU.
alpha-Hexylcinnamaldehyde Preparation Products And Raw materials
Raw materialsBenzaldehyde-->alpha-Amylcinnamaldehyde-->Octanal
Tag:alpha-Hexylcinnamaldehyde(101-86-0) Related Product Information
Tricyclohexyl phosphine α-Lipoic Acid α-Methylcinnamaldehyde Cinnamaldehyde Diethylstilbestrol Dicyclohexylamine 3-(trifluoromethyl) Cinnamaldehyde 4-(Dimethylamino)cinnamaldehyde Salicylic acid Glycerol Dicyclohexylcarbodiimide 3-(4-METHYLBENZYLIDENE)CAMPHOR  Phenanthrene alpha-Hexylcinnamaldehyde Cassia Aurantium P.E Catechins 8% HPLC TOSLAB 864097 2-(E)-BENZYLIDENE-6-(TRIFLUOROACETYL)CYCLOHEXANONE TOSLAB 860368