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alpha-Hexylcinnamaldehyde

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Products Intro: Product Name:101-86-0
CAS:101-86-0
Purity:0.99 Package:25KG,5KG;1KG;500G
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Products Intro: Product Name:alpha-Hexylcinnamaldehyde
CAS:101-86-0
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CAS:101-86-0
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Products Intro: Product Name:α-Hexylcinnamal
CAS:101-86-0
Purity:99% Package:5KG;1KG Remarks:C15H20O
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Products Intro: Product Name:alpha-Hexylcinnamaldehyde
CAS:101-86-0
Purity:99% Package:1PCS;1USD

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alpha-Hexylcinnamaldehyde Basic information
Product Name:alpha-Hexylcinnamaldehyde
Synonyms:(2Z)-2-Hexyl-3-phenyl-2-propenal;.alpha.-hexylcinnamaldehyde(positivecontrolchemical);2-(phenylmethylene)-octana;2-(phenylmethylene)-Octanal;2-(Phenylmethylene)octanal,a-Hexyl-phenylacrolein;FEMA 2569;HCA;JASMONAL H
CAS:101-86-0
MF:C15H20O
MW:216.32
EINECS:202-983-3
Product Categories:Aldehydes;C10 to C21;Pharmaceutical Intermediates;aldehyde Flavor;Carbonyl Compounds;Alphabetical Listings;Flavors and Fragrances;G-H
Mol File:101-86-0.mol
alpha-Hexylcinnamaldehyde Structure
alpha-Hexylcinnamaldehyde Chemical Properties
Boiling point 174-176 °C/15 mmHg (lit.)
density 0.95 g/mL at 25 °C (lit.)
FEMA 2569 | ALPHA-HEXYLCINNAMALDEHYDE
refractive index n20/D 1.55(lit.)
Fp 200 °F
storage temp. -20°C
solubility water: soluble0.005g/L at 25°C
JECFA Number686
CAS DataBase Reference101-86-0(CAS DataBase Reference)
NIST Chemistry ReferenceOctanal, 2-(phenylmethylene)-(101-86-0)
EPA Substance Registry System.alpha.-Hexylcinnamaldehyde (101-86-0)
Safety Information
Hazard Codes C,Xi
Risk Statements 36/37/38-34-43-52/53
Safety Statements 26-36/37/39-45-36-36/37-61
RIDADR UN 3265 8/PG 3
WGK Germany 2
RTECS GD6560000
HS Code 29122990
toxicityThe acute oral LD50 value in rats was reported as 3.1 g/kg (2.45-3.75 g/kg) (Moreno, 1971). The acute dermal LD50 value in rabbits was reported as > 3 g/kg (Moreno, 1971).
MSDS Information
ProviderLanguage
SigmaAldrich English
alpha-Hexylcinnamaldehyde Usage And Synthesis
Descriptionα-Hexylcinnamaldehyde has a jasmine-like odor, particularly on dilution. May be synthesized by condensation of octylaldehyde with benzaldehyde.
Chemical PropertiesHexyl cinnamaldehyde has a jasmine-like odor, particularly on dilution.
Chemical Propertiesalpha-Hexylcinnamaldehyde is a yellow liquid with a mild, slightly fatty, floral, somewhat herbal odor, and a distinct jasmine note. Similarly to the ??-amyl homolog, ??-hexylcinnamaldehydemust be protected against oxidation by the addition of stabilizers. It is prepared in a manner similar to that of ??-amylcinnamaldehyde by alkaline condensation of excess benzaldehyde with octanal (instead of heptanal). ??-Hexylcinnamaldehyde is widely used in flower compositions (e.g., jasmine and gardenia) and, because of its stability to alkali, in soap perfumes.
Chemical PropertiesPale-yellow liquid; jasminelike odor, particularly on dilution. Soluble in most fixed oils and in mineral oil; insoluble in glycerol and in propylene glycol.
OccurrenceReported found in cooked, scented rice.
Useshexyl cinnamal is also known as hexyl cinnamic aldehyde. It is a fragrance that provides a floral, jasmine-like scent.
Usesα-Hexylcinnamaldehyde is characterized by a typical floral scent, which makes them suitable to be used as fragrances in personal care (perfumes, creams, shampoos, etc.) and household products. It has been also used as flavouring additive in food and pharmaceutical industry.
DefinitionChEBI: A member of the class of cinnamaldehydes carrying a hexyl substituent at the alpha-position.
PreparationBy condensation of octylaldehyde with benzaldehyde
Taste threshold valuesTaste characteristics at 5 ppm: sweet, waxy, floral, green, citrus and fruity nuances
HazardCombustible.
Contact allergensHexyl cinnamic aldehyde is a fragrance allergen. Its presence has to be mentioned by name in cosmetics within the EU.
alpha-Hexylcinnamaldehyde Preparation Products And Raw materials
Raw materialsBenzaldehyde-->alpha-Amylcinnamaldehyde-->Octanal
Tag:alpha-Hexylcinnamaldehyde(101-86-0) Related Product Information
Salicylic acid Glycerol TOSLAB 860369 TOSLAB 870962 TOSLAB 864086 TOSLAB 864094 TOSLAB 864097 2-(E)-BENZYLIDENE-6-(TRIFLUOROACETYL)CYCLOHEXANONE TOSLAB 860368 TOSLAB 864122 RARECHEM AL BE 0138 TOSLAB 860367 RARECHEM AL BI 0138 TOSLAB 864130 BENZAL CAMPHOR 3-(trifluoromethyl) Cinnamaldehyde 4-(Dimethylamino)cinnamaldehyde alpha-Hexylcinnamaldehyde