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[1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II)

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Company Name: Henan Tianfu Chemical Co.,Ltd.
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Products Intro: Product Name:[1,1’-Bis(diphenylphosphino)ferrocene]dichloronickel
CAS:67292-34-6
Purity:99% Package:25KG;5KG;1KG
Company Name: AB PharmaTech,LLC
Tel: 323-480-4688
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Products Intro: Product Name:[1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II)
CAS:67292-34-6
Purity:98% Package:10kg,25kg,100kg
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Tel: +86-0371-86658258 +8613203830695
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Products Intro: Product Name:[1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II)
CAS:67292-34-6
Purity:98% Package:1KG;1USD
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Products Intro: Product Name:[1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II)
CAS:67292-34-6
Purity:98% Package:5g,50g,100g,250g,500g,1kg,5kg
Company Name: CONIER CHEM AND PHARMA LIMITED
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Products Intro: Product Name:(1,1'-bis(diphenylphosphino)ferrocene)dichloronickel(ii)
CAS:67292-34-6
Purity:99% Package:1kg

[1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II) manufacturers
[1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II) Basic information
Product Name:[1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II)
Synonyms:DPPF·NICL2;1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE NICKEL DICHLORIDE;[1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE]NICKEL(II) DICHLORIDE;DICHLORO[1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE]NICKEL(II);(1,1'-bis(diphenylphosphino)ferrocene)-dichloroni;[1, 1’-Bis(diphenyphosphino)ferrocene]dichloronickel(II);Dichlorobisdiphenylphosphinoferrocenenickel;Dichloro[1,1'-bis(diphenylphosphino)ferrocene]nickel(II),98%
CAS:67292-34-6
MF:C34H22Cl2FeNiP2
MW:677.94
EINECS:
Product Categories:Metal Compounds;pharmacetical;Synthetic Organic Chemistry;Transition Metal Compounds;Catalysis and Inorganic Chemistry;Chemical Synthesis;Catalysts for Organic Synthesis;Classes of Metal Compounds;Fe (Iron) Compounds;Ferrocenes;Homogeneous Catalysts;Metal Complexes;Metallocenes;Ni (Nickel) Compounds;Ni
Mol File:67292-34-6.mol
[1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II) Structure
[1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II) Chemical Properties
Melting point 285 °C (dec.)(lit.)
storage temp. Inert atmosphere,Room Temperature
form crystal
color green micro
Water Solubility Insoluble in water.
Exposure limitsNIOSH: IDLH 10 mg/m3; TWA 0.015 mg/m3
InChIInChI=1S/2C17H11P.2ClH.Fe.Ni/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;;;;/h2*1-6,9-12,18H;2*1H;;/q;;;;+2;/p-2
InChIKeyYLRDSVJNPNAGLK-UHFFFAOYSA-L
SMILES[Cl-][Ni+2]1(P(C2C=CC=CC=2)(C2C=CC=CC=2)[C-]23C4=C5C6=C2[Fe+2]27893456C3C2=C7[C-]8(C9=3)P1(C1C=CC=CC=1)C1C=CC=CC=1)[Cl-]
Safety Information
Hazard Codes T
Risk Statements 45-42/43
Safety Statements 53-22-36/37/39-45
RIDADR 2811
WGK Germany 3
HS Code 29319090
Storage Class6.1C - Combustible acute toxic Cat.3
toxic compounds or compounds which causing chronic effects
Hazard ClassificationsCarc. 1B
Resp. Sens. 1
Skin Sens. 1
MSDS Information
ProviderLanguage
SigmaAldrich English
[1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II) Usage And Synthesis
Chemical PropertiesYellow powder
Usesdiphosphine 1,1'-bis(diphenylphosphino)ferrocene (dppf) are used in transition metal-catalyzed reactions to synthesize pharmaceuticals and agrochemicals.
Usessuzuki reaction
Uses(1,1''-Bis(diphenylphosphino)ferrocene)dichloronickel(II) is an organometallic catalyst used in a variety of synthetic applications, such as the gem-difluoropropargylation of alkylzinc reagents, or cross coupling reactions to form 2,3,5,6-tetrasubstituted dehydropiperidines.
reaction suitabilitycore: nickel
reagent type: catalyst
[1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II) Preparation Products And Raw materials
Raw materialsEthanol-->Dichloromethane-->Nickel(II) chloride hexahydrate-->1,1'-Bis(diphenylphosphino)ferrocene
Tag:[1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II)(67292-34-6) Related Product Information
Ferrocene Chlorodiphenylphosphine Diphenylphosphine N-(Carboxymethyl)-N-(phosphonomethyl)-glycine 1,1'-Bis (di-t-butylphosphino)ferrocene palladium dichloride, 1,1μ-Bis(di-cyclohexylphosphino)ferrocene palladium dichloride Nickle chloride Benzylidene-bis(tricyclohexylphosphine)dichlororuthenium [1,3-Bis(diphenylphosphino)propane]nickel(II) chloride [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) Silane,[1,1'-biphenyl]-3-yltrimethyl- 1,1'-Bis(diphenylphosphino)ferrocene DICHLOROBIS(TRIMETHYLPHOSPHINE)NICKEL(II) NICKELOCENE Nickel Iron (80:20wt%) in cone shaped (refer to drawing) Nickel chloride ALLYL(CYCLOPENTADIENYL)NICKEL(II) 97 [1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II)