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(+)-1,2-BIS((2S,5S)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM (I) TRIFLUOROMETHANESULFONATE

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(+)-1,2-BIS((2S,5S)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM (I) TRIFLUOROMETHANESULFONATE Suppliers list
Company Name: Shenzhen Nexconn Pharmatechs Ltd
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Products Intro: Product Name:1,2-Bis[(2S,5S)-2,5-diethylphospholano]benzene(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate
CAS:142184-30-3
Purity:98% Package:1KG;10KG;50KG
Company Name: BOC Sciences
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Products Intro: Product Name:1,2-Bis[(2S,5S)-2,5-diethylphospholano]benzene(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate
CAS:142184-30-3
Package:500mg Remarks:BOC Sciences also provides custom synthesis services for 1,2-Bis[(2S,5S)-2,5-diethylphospholano]benzene(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate.
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Products Intro: Product Name:2-amino-5-bromo-4-methylpridine
CAS:142184-30-3
Purity:＞98% Package:1KG;9.8USD
Company Name: Henan Alfa Chemical Co., Ltd
Tel: +8618339805032
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Products Intro: CAS:142184-30-3
Purity:97%Min. Package:100g 500g 1kg 25kg:bulk package
Company Name: Labnetwork lnc.
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Products Intro: Product Name:1,2-Bis[(2S,5S)-2,5-diethylphospholano]benzene(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate
CAS:142184-30-3
Purity:95% Package:1kg+

(+)-1,2-BIS((2S,5S)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM (I) TRIFLUOROMETHANESULFONATE manufacturers
(+)-1,2-BIS((2S,5S)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM (I) TRIFLUOROMETHANESULFONATE Basic information
Reaction
Product Name:(+)-1,2-BIS((2S,5S)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM (I) TRIFLUOROMETHANESULFONATE
Synonyms:(+)-1,2-Bis[(2S,5S)-diethylphospholano)benzene(cyclooctadiene]rhodium(I) triflate,98%;(+)-1,2-Bis((2S,5S)-2,5-diethylphospholano)benzene(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate, 98+% (S,S)-Et-DUPHOS-Rh;(+)-1,2-Bis((2S,5S)-2,5-diethylphospholano)benzene(1,5-cyclooctadiene)rhodiuM(I) trifluoroMethanesulfonate (S,S)-Et-DUPHOS-Rh;(+)-1,2-BIS((2S,5S)-2,5-DIETHYLPHOSPHOLANO)BENZENE(1,5-CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE,98+%(S,S)-ET-DUPHOS-RH;(+)-1,2-BIS((2S,5S)-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I) TRIFLATE;(+)-1,2-BIS((2S,5S)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM (I) TRIFLUOROMETHANESULFONATE;(+)-1,2-BIS(2S,5S)-2,5-(DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANSULFONATE;(+)-1,2-Bis((2S,5S)-2,5-diethylphospholano)benzene(cyclooctadiene)rhodium(I)trifluoromethanesulfonate
CAS:142184-30-3
MF:C31H48F3O3P2RhS
MW:722.62
EINECS:
Product Categories:organometallic complex
Mol File:142184-30-3.mol
(+)-1,2-BIS((2S,5S)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM (I) TRIFLUOROMETHANESULFONATE Structure
(+)-1,2-BIS((2S,5S)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM (I) TRIFLUOROMETHANESULFONATE Chemical Properties
storage temp. Inert atmosphere,2-8°C
form crystal
color orange
Sensitive Air & Moisture Sensitive
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 24/25-26
WGK Germany 3
HS Code 29310099
MSDS Information
ProviderLanguage
ACROS English
ALFA English
(+)-1,2-BIS((2S,5S)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM (I) TRIFLUOROMETHANESULFONATE Usage And Synthesis
Reaction
  1. The DUPHOS family of catalysts is highly efficient for the asymmetric hydrogenation of various substituted acetamidoacrylates and enol acetates yielding products of high enantiomeric excesses. Efficient ligand for the asymmetric hydrogenation of tetrasubstituted enamides.
  2. Forms superior catalysts for asymmetric reductive aminations.
  3. Catalyst used for the asymmetric hydrogenation of enol phosphonates.
  4. A novel enantioselective synthesis of β-amino alcohols and 1,2-diamines.
  5. Ligand for the catalytic asymmetric [4+1] cycloaddition of vinylallenes with CO.
  6. Ligand for the Rh-catalyzed asymmetric enyne cycloisomerization.
  7. Catalytic enantioselective addition of dialkylzinc to N-Diphenylphosphinoylimines.
  8. Palladium catalyzed asymmetric phosphination.
Reactions of 142184-30-3_1
Reactions of 142184-30-3_2
Chemical Propertiesorange to red-orange crystals
Uses(S,S)-Et-DUPHOS-Rh may be used as an efficient catalyst in the synthesis of (S)-2-quinolylalanine via asymmetric hydrogenation.
General Description1,2-Bis[(2S,5S)-2,5-diethylphospholano]benzene(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate is an electron-rich C2 symmetric bis(phospholane) ligand for enantioselective catalytic reactions.
(+)-1,2-BIS((2S,5S)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM (I) TRIFLUOROMETHANESULFONATE Preparation Products And Raw materials
Tag:(+)-1,2-BIS((2S,5S)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM (I) TRIFLUOROMETHANESULFONATE(142184-30-3) Related Product Information
(+)-1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO)ETHANE(CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE (-)-1,2-Bis[(2R,5R)-dimethylphospholano]benzene(cyclooctadiene)rhodium(I) tetrafluoroborate (-)-1,2-BIS((2R,5R)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(L)TETRAFLUOROBORATE Rhodium ETHYLPHOSPHONIC ACID (+)-1,2-BIS[(2S,5S)-2,5-DIETHYLPHOSPHOLANO]BENZENE 1,3-CYCLOOCTADIENE Trifluoromethanesulfonic acid Benzene (-)-1,2-Bis((2R,5R)-2,5-diethylphospholano)benzene(cyclooctadiene)rhodium(I) trifluoromethanesulfonate (-)-1,2-BIS((2R,5R)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE