2-METHYL-1,3-BENZOXAZOLE-5-CARBOXYLIC ACID

2-METHYL-1,3-BENZOXAZOLE-5-CARBOXYLIC ACID Suppliers list
Company Name: Capot Chemical Co.,Ltd.
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Products Intro: Product Name:2-methylbenzo[d]oxazole-5-carboxylic acid
CAS:90322-32-0
Purity:95% Min. Package:1G;1KG;100KG
Company Name: Guangzhou Yuheng Pharmaceutical Technology Co., Ltd
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Products Intro: Product Name:2-methyl-1,3-benzoxazole-5-carboxylic acid
CAS:90322-32-0
Purity:0.97 Package:1KG;25KG
Company Name: Shanghai UCHEM Inc.
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Products Intro: Product Name:2-Methyl-1,3-benzoxazole-5-carboxylic acid
CAS:90322-32-0
Purity:0.98 Package:5G;1G
Company Name: Hefei TNJ Chemical Industry Co.,Ltd.
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Products Intro: Product Name:5-Benzoxazolecarboxylic acid, 2-methyl-
CAS:90322-32-0
Company Name: Coresyn Pharmatech Co., Ltd.
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Products Intro: Product Name:2-methylbenzo[d]oxazole-5-carboxylic acid
CAS:90322-32-0
Purity:NLT 98% Package:1G;1KG;100KG Remarks:CM30370
2-METHYL-1,3-BENZOXAZOLE-5-CARBOXYLIC ACID Basic information
Product Name:2-METHYL-1,3-BENZOXAZOLE-5-CARBOXYLIC ACID
Synonyms:2-METHYL-1,3-BENZOXAZOLE-5-CARBOXYLIC ACID;2-METHYL-BENZOOXAZOLE-5-CARBOXYLIC ACID;OTAVA-BB 1136981;2-Methylbenzo[d]oxazole-5-carboxylic acid;2-Methyl-5-Benzoxazolecarboxylic acid;5-Benzoxazolecarboxylic acid, 2-Methyl-;2-Methylbenzoxazole-5-carboxylic Acid;2-Methyl-benzooxazole-6-carboxylic acid
CAS:90322-32-0
MF:C9H7NO3
MW:177.16
EINECS:
Product Categories:
Mol File:90322-32-0.mol
2-METHYL-1,3-BENZOXAZOLE-5-CARBOXYLIC ACID Structure
2-METHYL-1,3-BENZOXAZOLE-5-CARBOXYLIC ACID Chemical Properties
Melting point 186-188℃
Boiling point 353.5±15.0 °C(Predicted)
density 1.38
storage temp. Sealed in dry,Room Temperature
pka3.53±0.30(Predicted)
AppearanceLight brown to off-white Solid
Safety Information
HS Code 2934999090
MSDS Information
2-METHYL-1,3-BENZOXAZOLE-5-CARBOXYLIC ACID Usage And Synthesis
Synthesis
METHYL 2-METHYL-1,3-BENZOXAZOLE-5-CARBOXYLATE

136663-21-3

2-METHYL-1,3-BENZOXAZOLE-5-CARBOXYLIC ACID

90322-32-0

). The reaction mixture was stirred at 25 °C for 3 hours. Upon completion of the reaction, the mixture was acidified to pH < 7 with dilute hydrochloric acid and a white solid was precipitated. The solid product was collected by filtration, washed with deionized water and subsequently dried under vacuum. Finally, the crude product was purified by silica gel column chromatography (eluent: petroleum ether/ethyl acetate=1:1, v/v) to afford the target compound 2-methyl-5-benzoxazolecarboxylic acid (0.30 g, 65% yield) as a white solid.

References[1] Patent: WO2016/100184, 2016, A1. Location in patent: Paragraph 00321-00322
2-METHYL-1,3-BENZOXAZOLE-5-CARBOXYLIC ACID Preparation Products And Raw materials
Raw materialsTrimethyl orthoacetate-->METHYL 2-METHYL-1,3-BENZOXAZOLE-5-CARBOXYLATE-->3-Amino-4-hydroxybenzoic acid-->Tetrahydrofuran-->Lithium hydroxide monohydrate-->Methanol-->Hydrochloric acid-->Water
Tag:2-METHYL-1,3-BENZOXAZOLE-5-CARBOXYLIC ACID(90322-32-0) Related Product Information
1,3-BENZOXAZOLE-5-CARBOXYLIC ACID METHYL 2-PROPYL-1,3-BENZOXAZOLE-5-CARBOXYLATE METHYL 2-(CHLOROMETHYL)-1,3-BENZOXAZOLE-5-CARBOXYLATE 5-BENZOXAZOLECARBOXYLIC ACID, 7-AMINO-2-(PHENYLMETHYL)-, METHYL ESTER 2-PHENYL-BENZOOXAZOLE-5-CARBOXYLIC ACID 2-BUTYL-1,3-BENZOXAZOLE-5-CARBOXYLIC ACID 5-BENZOXAZOLECARBOXYLIC ACID, 7-AMINO-2-METHYL-, METHYL ESTER METHYL 2-ETHYL-1,3-BENZOXAZOLE-5-CARBOXYLATE BUTTPARK 121\16-97 METHYL 2-METHYL-1,3-BENZOXAZOLE-5-CARBOXYLATE 2-METHYL-1,3-BENZOXAZOLE-5-CARBOXYLIC ACID

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