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Poly(ethylene glycol) diacrylate

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CAS:26570-48-9
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Poly(ethylene glycol) diacrylate Basic information
Product Name:Poly(ethylene glycol) diacrylate
Synonyms:Poly(ethylene glycol) diacrylate average Mn 1,000, contains MEHQ as inhibitor;Poly(ethylene glycol) diacrylate average Mn 20,000, contains <=100 ppm MEHQ as inhibitor;Poly(ethylene glycol) diacrylate average Mn 6,000, contains <=1500 ppm MEHQ as inhibitor;Poly(ethylene glycol) diacrylate (Mn 2000);1,2-Ethanediyl bisacrylate;2-ethanediyl),.alpha.-(1-oxo-2-propenyl)-.omega.-[(1-oxo-2-propenyl)oxy]-Poly(oxy-1;poly(oxy-1,2-ethanediyl),alpha-(1-oxo-2-propenyl)-omega-[(1-oxo-2-propenyl)o;xy]-
CAS:26570-48-9
MF:C5H10O4
MW:134.1305
EINECS:251-228-4
Product Categories:Polydispersed PEG;Acrylate;Biomaterials;Crosslinking Agents;Homobifunctional PEGs;Materials Science;Homobifunctional PEGsMaterials Science;Biocompatible/Biodegradable Materials;Homobifunctional PEGs;Materials Science;Poly(ethylene glycol) and Poly(ethylene oxide);Polymer Science;Polymers;PEG;Homobifunctional PEG BiomaterialsPolymer Science;New Products for Materials Research and Engineering;PEG Based Polymers;Poly(ethylene glycol) and Poly(ethylene oxide);Polymer Science;Crosslinking AgentsBiocompatible/Biodegradable Materials
Mol File:26570-48-9.mol
Poly(ethylene glycol) diacrylate Structure
Poly(ethylene glycol) diacrylate Chemical Properties
Melting point 12-17 °C
density 1.12 g/mL at 25 °C
refractive index n20/D 1.47
Fp 347 °F
storage temp. -20°C
solubility H2O: soluble
form Granular Solid
color White to off-white
Water Solubility Soluble in water.
Sensitive Light Sensitive
α-endacrylate
Ω-endacrylate
InChIInChI=1S/C3H4O2.C2H6O2/c1-2-3(4)5;3-1-2-4/h2H,1H2,(H,4,5);3-4H,1-2H2
InChIKeyFCDZZFLRLVQGEH-UHFFFAOYSA-N
SMILESO([H])C([H])([H])C([H])([H])O[H].O([H])C(C([H])=C([H])[H])=O
EPA Substance Registry SystemPoly(oxy-1,2-ethanediyl), .alpha.-(1-oxo-2-propenyl)-.omega.-[(1-oxo-2-propenyl)oxy]- (26570-48-9)
Safety Information
Hazard Codes Xi
Risk Statements 41-43-38
Safety Statements 26-36/37/39
WGK Germany 1
TSCA TSCA listed
HS Code 2916.12.5050
Storage Class11 - Combustible Solids
Hazard ClassificationsEye Dam. 1
Skin Irrit. 2
Skin Sens. 1
MSDS Information
ProviderLanguage
SigmaAldrich English
Poly(ethylene glycol) diacrylate Usage And Synthesis
DescriptionPoly(ethylene glycol) diacrylate (PEGDA) is a blank slate hydrogel that gels rapidly at room temperature in the presence of a photoinitiator and light. PEGDA hydrogels are potent tools for uncovering basic cellular biology because they are considered biologically inert (“blank slate”), and their mechanical properties can be varied over an extensive range of moduli.PEGDA is an emerging scaffold for tissue engineering and regenerative medicine since polymerization can occur rapidly at room temperature, requires low energy input, has high water content, is elastic, and can be customized to include a variety of biological molecules.
UsesPEGDA is used in dental compounds, offset inks, varnishes and flexible coatings.
DefinitionChEBI: Poly(ethylene glycol diacrylate) is a poly(ethylene glycol) compound terminated with acrylate groups.
General DescriptionPoly(ethylene glycol) diacrylate (PEGDA) is a polyethylene glycol (PEG) based material that is used as a prepolymer solution that can be used in the formation of a cross-linked polymeric system.
reaction suitabilityreagent type: cross-linking reagent
reaction type: Polymerization Reactions
Synthesis

S1, polyethylene glycol (PEG) was dried in vacuum at 50C overnight, and K2CO3 was ground and dried in vacuum at 100C overnight, and cooled in vacuum;

S2, 50g of PEG was dissolved in 100mL of anhydrous dichloromethane in a three-necked flask of 500mL, and K2CO3 was added in accordance with the amount of additions shown in Table 2, and stirred well to disperse;

S3, according to the addition amount shown in Table 2, acryloyl chloride was dissolved in anhydrous dichloromethane (1:10v/v), and slowly added drop by drop to the three-necked flask, and the reaction was carried out for 24h at room temperature under the protection of nitrogen;

S4, the mixture was filtered to remove the solids, and the supernatant was rotary evaporated at 37 to remove most of the solvent and then fully precipitated with ether and washed by ether for 3-5 times, and finally the product was completely dried in a vacuum. The product, polyethylene glycol diacrylate (PEGDA), was completely dried in vacuum.

Poly(ethylene glycol) diacrylate Preparation Products And Raw materials
Tag:Poly(ethylene glycol) diacrylate(26570-48-9) Related Product Information
2-(2-Butoxyethoxy)ethyl acetate ETHYLENE DIACRYLATE ETHYLENE OXIDE Ethylene carbonate Polyethylene glycol monooleate POLY(ETHYLENE GLYCOL) ACRYLATE Neopentyl glycol diacrylate POLY(ETHYLENE GLYCOL) (N) MONOMETHACRYLATE POLY(1,4-BUTANEDIOL SUCCINATE) [LIQUID PHASE FOR GC] Diethylene glycol diacrylate Poly(methyl methacrylate) ETHYLENE Hexamethylene diacrylate Oxybis(methyl-2,1-ethanediyl) diacrylate Ethylene glycol diacetate Ethylene glycol 1,2-Dibromoethane Polyethylene Glycol