THORIUM CHLORIDE

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CAS:10026-08-1
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THORIUM CHLORIDE Basic information
Product Name:THORIUM CHLORIDE
Synonyms:THORIUM CHLORIDE;Tetrachlorothorium;ThCl4;Thorium chloride (ThCl4);Thorium(IV)chloride;thoriumchloride(thcl4);thorium tetrachloride;Thorium(IV) tetrachloride
CAS:10026-08-1
MF:Cl4Th
MW:373.85
EINECS:233-056-1
Product Categories:1
Mol File:10026-08-1.mol
THORIUM CHLORIDE Structure
THORIUM CHLORIDE Chemical Properties
Melting point 770°
Boiling point bp 921°
density 4.59
solubility soluble in H2O, ethanol
form gray-white tetragonal needles
color gray-white tetragonal needles; hygroscopic
Water Solubility soluble H2O, alcohol [MER06]
InChIInChI=1S/4ClH.Th/h4*1H;/q;;;;+4/p-4
InChIKeyWEQHQGJDZLDFID-UHFFFAOYSA-J
SMILES[Th](Cl)(Cl)(Cl)Cl
EPA Substance Registry SystemThorium chloride (ThCl4) (10026-08-1)
Safety Information
RIDADR 2912
TSCA TSCA listed
HazardClass 7
Toxicitymouse,LD50,intraperitoneal,332mg/kg (332mg/kg),Comptes Rendus Hebdomadaires des Seances, Academie des Sciences. Vol. 256, Pg. 1043, 1963.
MSDS Information
THORIUM CHLORIDE Usage And Synthesis
Chemical PropertiesThorium chloride is colorless or white, lustrous needles (light-yellow color caused by iron trace); hygroscopic; partially volatile; crystallizes with variable water of crystallization. 
Deliquescent in moist air, readily soluble in water and alcohol. Soluble in ethylenediamine.
UsesIncandescent lighting.
PreparationA solution of thorium hydroxide in excess hydrochloric acid is evaporated until sirupy and is then allowed to cool and crystallize.
Further purification, in particular, removal of Fe and SiO2, is best achieved by shaking with an ether-aqueous hydrochloric acid mixture.
Safety ProfilePoison by intravenous route. Moderately toxic by intraperitoneal and subcutaneous routes. When heated to decomposition it emits toxic fumes of Cl-. See also THORIUM.
Purification MethodsIt is freed from anionic impurities by passing a 2M solution of ThCl4 in 3M HCl through a Dowex-1 anion-resin column. The eluate is partially evaporated to give crystals which are filtered off, washed with Et2O and stored in a desiccator over H2SO4 to dry. Alternatively, a saturated solution of ThCl4 in 6M HCl is filtered through quartz wool and extracted twice with ethyl, or isopropyl ether (to remove iron), then evaporated to a small volume on a hot plate. (Excess silica precipitates and is filtered off. The filtrate is cooled to 0o and saturated with dry HCl gas.) It is shaken with an equal volume of Et2O, shaken with HCl gas, until the mixture becomes homogeneous. On standing, ThCl4.8H2O precipitates out and is filtered off, washed with Et2O and dried [Kremer J Am Chem Soc 64 1009 1942].
THORIUM CHLORIDE Preparation Products And Raw materials
Tag:THORIUM CHLORIDE(10026-08-1) Related Product Information
Cerium dioxide Yttrium oxide Cesium RHENIUM Cobalt(II) hydroxide GERMANIUM(IV) CHLORIDE Cobalt hydroxide URANIUM(IV) OXIDE Thorium dioxide Thorium(Ⅳ)chloride nonahydrate THORIUM CHLORIDE THORIUM

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