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Hexazinone

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Company Name: Henan DaKen Chemical CO.,LTD.
Tel: +86-371-66670886
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Products Intro: Product Name:Hexazinone
CAS:51235-04-2
Purity:99% Package:100g,500g,1KG,10KG,100KG
Company Name: Henan Tianfu Chemical Co.,Ltd.
Tel: 0371-55170693
Email: info@tianfuchem.com
Products Intro: Product Name:51235-04-2
CAS:51235-04-2
Purity:0.99 Package:25KG,5KG;1KG;500G
Company Name: Hubei Jusheng Technology Co.,Ltd.
Tel: 86-18871470254
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Products Intro: Product Name:hexazinone
CAS:51235-04-2
Purity:99% Package:5KG;1KG Remarks:C12H20N4O2
Company Name: Xiamen AmoyChem Co., Ltd
Tel: +86 592-605 1114
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Products Intro: Product Name:Hexazinone
CAS:51235-04-2
Company Name: CONIER CHEM AND PHARMA LIMITED
Tel: 86-18523575427
Email: sales@conier.com
Products Intro: Product Name:hexazinone
CAS:51235-04-2
Purity:0.99 Package:1kg

Lastest Price from Hexazinone manufacturers

  • Hexazinone
  • US $1.00 / g
  • 2020-01-10
  • CAS:51235-04-2
  • Min. Order: 1g
  • Purity: 99.0%
  • Supply Ability: 100kg
Hexazinone Basic information
Chemical Properties Uses Mechanism of action Toxicity Preparation method
Product Name:Hexazinone
Synonyms:VELPAR;HEXAZINONE;3-CYCLOHEXYL-6-(DIMETHYLAMINO)-1-METHYL-1,3,5-TRIAZINE-2,4-(1H,3H)-DIONE;3-CYCLOHEXYL-6-DIMETHYLAMINO-1-METHYL-1,3,5-TRIAZINE-2,4-DIONE;5-triazine-2,4(1h,3h)-dione,3-cyclohexyl-6-(dimethylamino)-1-methyl-3;brushkiller;DPX 3674;dpx3674
CAS:51235-04-2
MF:C12H20N4O2
MW:252.31
EINECS:257-074-4
Product Categories:Pesticides&Metabolites;Triazinone structure;Alphabetic;Analytical Standards;V;Alpha sort;HERBICIDE;H;HA -HTPesticides&Metabolites;Herbicides;H-MAlphabetic
Mol File:51235-04-2.mol
Hexazinone Structure
Hexazinone Chemical Properties
Melting point 97-100.5°
Boiling point 395.49°C (rough estimate)
density 1.2500
refractive index 1.6120 (estimate)
Fp 11℃
storage temp. APPROX 4°C
form Powder
pka2.05±0.70(Predicted)
color Beige
Water Solubility 33g/L(25 ºC)
BRN 618801
CAS DataBase Reference51235-04-2(CAS DataBase Reference)
NIST Chemistry Reference1,3,5-Triazine-2,4(1h,3h)-dione, 3-cyclohexyl-6-(dimethylamino)-1-methyl-(51235-04-2)
EPA Substance Registry SystemHexazinone (51235-04-2)
Safety Information
Hazard Codes Xn,N,T,F
Risk Statements 22-36-50/53-39/23/24/25-23/24/25-11
Safety Statements 60-61-45-36/37-16-7
RIDADR UN3077 9/PG 3
WGK Germany 3
RTECS XY7850000
HS Code 29336990
Hazardous Substances Data51235-04-2(Hazardous Substances Data)
ToxicityLD50 orally in rats: 1690 mg/kg (Neary)
MSDS Information
ProviderLanguage
Hexazinone English
Hexazinone Usage And Synthesis
Chemical PropertiesThe pure product is white crystalline solid. m.p.115~117℃. Vapour pressure is 2.7×10-3Pa (25℃)、8.5×10-3Pa (86℃). Relative density is 1.25. The solubility at 25 ℃: 3880g/kg in chloroform, 2650g/kg in methanol, 836g/kg in dimethylformamide,790g/kg in acetone, 940g/kg in benzene, 386g/kg in toluene, 3g/kg in hexane and 33g/kg in water. In the water solution with pH value of 5~9, it is stable at normal temperature and will be decomposed by microbes in the soil.
UsesPost bud contact killing herbicide and the inhibitor of photosynthesis in plants. Its weed killing spectrum and killing shrub spectrum are wide, and its toxicity is strong and effective. It is used for tending young forests of evergreen coniferous forests, such as Pinus koraiensis, Pinus sylvestris, Picea spruce, Pinus massoniana and so on. Before the afforestation, it is applied to weeding and extinguishing irrigation, maintaining and opening forest fire prevention and forest soil improvement etc...It can also be used for weeding and irrigation on both sides of the oil depot, airport and road. It can prevent green bristlegrass, filipendula palmate, angelica dahurica,sedge, herba elsholtziae, reed, deyeuxia angustifolia, fern, clematis, veronica spuria, cephalanoplos segetum, wild oats, quinoa, millet, etc.. The woody plants it can can control include yellow lonicera japonica, pearl, hazel wood, spiraea salicifolia, acanthopanax senticosus, acanthopanax, winged elm, aspen, birch, quercus mongolica, linden, oak, linden, ashtree, phellodendron amurense rupr, juglans mandshurica etc.. It can control annual weed and biennial weed. A dose of 2~5kg/hm2 control weeds for a short term. Most perennial weeds can be prevented by the dose of 6~12kg/hm2. Nonionic surfactants can be added to this product.
Mechanism of actionIt mainly inhibits the photosynthesis of plants and causes the disordered generation of plants and causes death. Both plant root and leaf surface can absorb the cyclohexanone, which is transported mainly through the xylem. It has great mobility in the soil and can be decomposed by soil microbes after entering the soil. It has no harm to the root of the pine tree. 7 days after the weeds have been treated, the leaves will have necrosis until the whole leaf has withered. The whole process including the upper part above ground (about 2 weeks) and the rotting of the root lasts for 1 month. It will last for 1 month from the appearance of necrosison the new leaves to rotting roots of the shrubs lasts for about 2 months. The first defoliation of non - objective arbor takes place 20~30 days after the injury. In the future, the new born leaves will be molted again, repeating 3~5 times in a row. From the spot to the formation of shrub leaf rot lasted for about 2 months. The upper part of the ground dies in 60~120 days. The roots rot in the fall of second.
ToxicityThe drug is of toxicity when acute oral LD50 is 1690mg/kg in rats, acute percutaneous is LD50>5278mg/kg in rabbits, acute transdermal is LD50>2000mg/kg in rats. It has a stimulating effect on the eyes of rabbits. The accumulative coefficient K value is >5, which belongs to the mild accumulative pesticide.There is no teratogenic, carcinogenic and mutagenic effects on animals within the range of experiments. No abnormality is found in the three generation reproduction test and neurotoxicity test. The non-cation dose for two years of feeding test: 200mg/kg for rats,LC50388mg/L for rainbow trout, LD50>5000mg/kg for quail, LD50>10000mg/kg for wild duck and, LC5060μg for per bee.
Preparation method
UsesHerbicide.
UsesHexazinone is a triazine compound used as a preemergence or postemergence herbicide to control many annual grasses and broad-leaved weeds in noncropped land and certain crops such as alfalfa, blueberries, coffee, pecans and sugarcane
Production MethodsHexazinone is a postemergence contact herbicide effective against many annual and biennial weeds and, except for Johnson grass, most perennial weeds. Human contact is likely at the use stage, and dermal contact and inhalation are of most concern.
General DescriptionWhite crystalline solid. Corrosive eye irritant. Used as an herbicide.
Air & Water ReactionsWater soluble. Rapidly decomposed in solution by strong acids and bases.
Reactivity ProfileA triazine.
CarcinogenicityNo carcinogenicity was detected among pups of rats fed up to 5000 ppm for 2 years. Similarly, no increase in tumors was produced by feeding up to 10,000 ppm hexazinone to mice.
Environmental FateSoil/Plant. Biodegrades in soil and natural waters releasing carbon dioxide. The reported half-life in soil is 1 to 6 months (Hartley and Kidd, 1987). Rhodes (1980a) found that the persistence of hexazinone varied from 4 weeks in a Delaware sandy loam to 24 weeks in a Mississippi silt loam.
Hexazinone is subject to microbial degradation (Rhodes, 1980a; Feng, 1987). Metabolites identified in soils, alfalfa and/or sugarcane include 3-(4-hydroxycyclohexyl)-6(dimethylamino)-1-methyl-1,3,5-triazine-2,4(1H,3H)-dione, 3-cyclohexyl-6-(methylamino)-1
Feng (1987) monitored the persistence and degradation of hexazinone in a silt loam soil 104 days after treatment of the herbicide. After 104 days, 66% of the hexazinone degraded via hydroxylation to form the major metabolite 3-(4-hydroxycyclohexyl)-6(dime
No traces of hexazinone or its metabolites were detected on treated blueberries (Jenson and Kimball, 1985).
Photolytic. Photodegradation products identified in aqueous hexazinone solutions following exposure to UV light (λ = 300–400 nm) were 3-(4-hydroxycyclohexyl)-6-(dimethylamino)-1-methyl-1,3,5-triazine-2,4(1H,3H)-dione, 3-cyclohexyl-6-(methylamino)
Metabolic pathwayIn clay and sand soils, hexazinone is metabolized by hydroxylation at the 4-position of the cyclohexane ring and mono-N-demethylation to give [3-(4- hydroxycyclohexyl)-6-(dimethylamino)-1-methyl-1,3,5- triazine-2,4-(1H,3H )-dione], and [3-cyclohexyl-6- (methylamino)-1-methyl-1,3,5-triazine-2,4-(1H,3H )- dione, respectively. N-Demethylated metabolite is found in a comparatively higher percentage than the hydroxylated metabolite in both clay and sand soils.
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