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ChemicalBook > Product Catalog >Organic Chemistry >Organometallic compounds >Rare-Earth Metal >(R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-COBALT(II)

(R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-COBALT(II)

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(R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-COBALT(II) Suppliers list
Company Name: Shanghai UCHEM Inc.
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Products Intro: Product Name:(1R,2R)-(-)-N,N-Bis(3,5-di-t-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II)
CAS:176763-62-5
Purity:0.98 Package:5g;170USD|10g;260USD|25g;500USD
Company Name: Henan Tianfu Chemical Co.,Ltd.
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Products Intro: Product Name:TIANFU CHEM (R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-COBALT(II)
CAS:176763-62-5
Purity:99% Package:25KG;5KG;1KG
Company Name: Shanghai Time Chemicals CO., Ltd.
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Products Intro: Product Name:(R,R)-(-)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II)
CAS:176763-62-5
Company Name: ATK CHEMICAL COMPANY LIMITED
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Products Intro: Product Name:(R,R)-(-)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II)
CAS:176763-62-5
Purity:98% Package:10MG;50MG;100MG,1G,5G,10G
Company Name: Shanxi Naipu Import and Export Co.,Ltd
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Products Intro: Product Name:bis(3,5-di-t-butylsalicylidene)cobalt (II)
CAS:176763-62-5
Purity:99 Package:1bag;100USD

(R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-COBALT(II) manufacturers
(R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-COBALT(II) Basic information
Reaction
Product Name:(R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-COBALT(II)
Synonyms:(1R,2R)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2- cyclohexanediaminocobalt(II),99%e.e.;(1R,2R)-(-)-N,N'-BIS(3,5-DI-T-BUTYLSALICYDENE)-1,2-CYCLOHEXANEDIAMINOCOBALT(II);(1R,2R)-(-)-1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)COBALT(II);(1R,2R)-(-)-N,N-Bis(3,5-di-t-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II);CyclohexanediaminoNNbisditbutylsalicylidene;(R,R)-(-)-N,N'-BIS(3,5-DI-T-BUTYLSALICYL ID -ENE)-1,2-CYCLOHEXANEDIAMINOCOBALT(II;(1R,2R)-(-)-1,2-Cyclohexanediamino-N,N'-bis(3,5-di-tert-butylsalicylidene)cobalt(II);(1r,2r)-(-)-1,2-cyclohexanediamino-n,n'-bis(3,5- di-t-butylsalicylidene)cobalt
CAS:176763-62-5
MF:C36H52CoN2O2
MW:603.74
EINECS:
Product Categories:Jacobsen Metal;Co;fine chemicals, specialty chemicals, intermediates, electronic chemical, organic synthesis;Kinetic ResolutionChiral Catalysts, Ligands, and Reagents;Asymmetric Synthesis;Chiral Catalysts, Ligands, and Reagents;Privileged Ligands and Complexes;SALENs
Mol File:176763-62-5.mol
(R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-COBALT(II) Structure
(R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-COBALT(II) Chemical Properties
Melting point >350 °C(lit.)
storage temp. Keep in dark place,Inert atmosphere,Room temperature
form Powder
color Orange to red to brown
Safety Information
Hazard Codes Xn
Risk Statements 20/21/22-36/37/38
Safety Statements 36/37/39-26
WGK Germany 3
HS Code 29349990
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
(R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-COBALT(II) Usage And Synthesis
Reaction
  1. Catalyst used in the kinetic resolution of racemic, terminal epoxides yielding a chiral diol and the unreacted enantiomer of the epoxide.
  2. Precursor to a Co(III) catalyst for the kinetic resolution of terminal epoxides with alcohols.
  3. Desymmetrization of meso-epoxides with carboxylic acids and fluoride.
  4. Catalyst for asymmetric cyclopropanation of styrene.
  5. Catalyst for copolymerization of CO2 and epoxides.
  6. Enantioselective intramolecular openings of oxetanes.
Reactions of 176763-62-5_1
Reactions of 176763-62-5_2
Chemical PropertiesOrange to red-brown powder
UsesCatalyst for the hydrolytic kinetic resolution of terminal epoxides and the enantioselective ring opening of meso epoxides.
(R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-COBALT(II) Preparation Products And Raw materials
Raw materialsPhenol, 2,2'-[(1R,2R)-1,2-cyclohexanediylbis(nitrilomethylidyne)]bis[4,6-bis(1,1-dimethylethyl)--->Cobalt(II) acetate tetrahydrate-->Dimethyl fumarate
Tag:(R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-COBALT(II)(176763-62-5) Related Product Information
1,4-Bis(diphenylphosphino)butane-palladium(II) chloride BIS(3 5 3' 5'-DIMETHOXYDIBENZYLIDENEACE& SPhos Pd G2 ALLYLCHLORO[1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOL-2-YLIDENE]PALLADIUM (II), 98 DICHLORO(N,N,N',N'-TETRAMETHYLETHYLENEDIAMINE)PALLADIUM(II) RuPhos Pd G2 Cobalt (S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-COBALT(II) N,N'-BIS(SALICYLIDENE)ETHYLENEDIAMINE (1R,2R)-(-)-1,2-Diaminocyclohexane (R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-COBALT(II) (R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINE SALCOMINE N,N'-BIS(SALICYLIDENE)-1,2-PROPANEDIAMINE DIBENZYLIDENE ETHYLENEDIAMINE N-benzylidenecyclohexylamine N,N'-BIS(SALICYLIDENE)-1,6-HEXANEDIAMINE CIS/TRANS-DISALYCYLIDENE-1,2-CYCLOHEXYLIDENEDIAMINE