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Chromyl chloride

Chromyl chloride Suppliers list
Company Name: Mainchem Co., Ltd.
Tel: +86-0592-6210733
Products Intro: Product Name:Chromyl chloride
Company Name: J & K SCIENTIFIC LTD.  
Tel: 400-666-7788 +86-10-82848833
Products Intro: Product Name:Chromyl chloride, 99.5%
Purity:99.5% Package:25g;5g
Company Name: Meryer (Shanghai) Chemical Technology Co., Ltd.  
Tel: +86-(0)21-61259100(Shanghai) +86-(0)755-86170099(ShenZhen) +86-(0)10-62670440(Beijing)
Products Intro: Product Name:ChroMyl chloride
Purity:99.5% Remarks:AAM134907
Company Name: Alfa Aesar  
Tel: 400-610-6006; 021-67582000
Products Intro: Product Name:ChroMyl chloride, 99.99% (Metals basis)
Package:2g Remarks:040517
Company Name: Energy Chemical  
Tel: 021-58432009 / 400-005-6266
Products Intro: Product Name:ChroMyl chloride
Purity:99.99%(Metalsbasis) Package:10g,2g,50g
Chromyl chloride Basic information
Product Name:Chromyl chloride
Synonyms:dichlorodioxo-chromiu;Dichlorodioxochromium;Dioxodichlorochromium;dioxodichlorochromium[qr];Oxychlorure chromique;oxychlorurechromique;oxychlorurechromique(french)[qr];Chromylchlorideredliq
Product Categories:inorganic compound
Mol File:14977-61-8.mol
Chromyl chloride Structure
Chromyl chloride Chemical Properties
Melting point -96.5 °C
Boiling point 117 °C(lit.)
density 1.911 g/mL at 25 °C(lit.)
Fp 117°C
form liquid
Specific Gravity1.911
color red
Water Solubility Soluble in carbon tetrachloride, carbon disulfide, benzene, nitrobenzene, chloroform, and POCL3. Insoluble in water(Reacts).
Sensitive Moisture Sensitive
Merck 14,2248
CAS DataBase Reference14977-61-8(CAS DataBase Reference)
Safety Information
Hazard Codes O,T,C,N
Risk Statements 49-46-8-35-43-50/53-34-23/24/25-45
Safety Statements 53-45-60-61-36/37/39-27-26-17
RIDADR UN 3244 8/PG 2
WGK Germany 3
RTECS GB5775000
HazardClass 8
PackingGroup I
MSDS Information
ACROS English
SigmaAldrich English
ALFA English
Chromyl chloride Usage And Synthesis
Chemical PropertiesDEEP RED LIQUID
Chemical PropertiesChromyl chloride is a dark red fuming liquid with a musty, burning odor.
UsesCatalyst for polymerization of olefins; oxidation of hydrocarbons; in the Etard reaction for production of aldehydes and ketones; in the preparation of various coordination complexes of Cr.
General DescriptionA dark red fuming liquid with a pungent odor. Corrosive to tissue.
Reactivity ProfileChromyl chloride is a powerful and often violent oxidizing agent. Reacts readily with many inorganic and organic materials in the absence of a dilutent. Contact with hydrogen sulfide or phosphine can cause ignition. Contact with phosphorus tribromide, acetone, ethanol, ether, and turpentine causes ignition. Contact with moist phosphorus or with phosphorus trichloride leads to explosive reaction. Contact with ammonia causes incandescence. Reacts with sodium azide to form chromyl azide, which is explosive in the absence of a dilutent. Causes ignition of flowers of sulfur and of urea on contact. [Bretherick, 1979, p. 822-823].
HazardCorrosive to tissue. Strong oxidizing agent. Skin and upper respiratory tract irritant. Probable carcinogen.
Health HazardInhalation causes severe irritation of upper respiratory system. Contact with eyes or skin causes irritation and burning. Ingestion causes burning of mouth and stomach.
Fire HazardBehavior in Fire: Vapors are very irritating to eyes and mucous membranes. May increase severity of fire.
Safety ProfileSuspected carcinogen. Probably a poison by various routes. Mutation data reported. Corrosive. A strong irritant. Hydrolyzes to form chromic and hydrochloric acids. A strong oxidner and chlorinating agent. Violent reaction with water. Reacts violently with alcohol, ether, acetone, turpentine. Ignites or explodes on contact with nonmetal halides (e.g., disulfur dichloride, phosphorus trichloride, and phosphorus tribromide), nonmetal hydrides (e.g., hydrogen sulfide and hydrogen phosphide), flowers of sulfur, moist phosphorus, sodium azide, and urea. During preparation can violently explode. Incompatible with ammonia, disulfur dichloride, organic solvents, phosphorus, phosphorus trichloride, sodium azide, and sulfur. When heated to decomposition it emits toxic fumes of Cl-. See also CHROMIUM COMPOUNDS.
Potential ExposureChromium oxychloride is used in making chromium complexes and dyes; and used in various organic oxidation and chlorination reactions
First aidIf this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 30 minutes, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a Medical facility. When this chemical has been swallowed, get medical attention. If victim is conscious, administer water or milk. Do not induce vomiting
ShippingUN1758 Chromium oxychloride, Hazard class: 8; Labels: 8-Corrosive material.
Purification MethodsPurify it by distillation under reduced pressure. It hydrolyses violently with H2O and is a powerful oxidant which explodes with P, and ignites in contact with S, NH3, EtOH and many organic compounds. TOXIC.
IncompatibilitiesContact with water is violent and forms hydrochloric and chromic acids, and chlorine gas. A powerful oxidizer. Reacts violently with acetone, alcohol, ammonia, ether, fuels, organic solvents, moist phosphorus, phosphorus trichloride; sodium azide; sulfur, reducing agents; turpentine. Contact with nonmetal halides, such as disulfur dichloride, phosphorus trichloride; and phosphorus tribromide; nonmetal hydrides, such as hydrogen sulfide; hydrogen phosphide, and urea, causes a danger fire and explosion hazard
Chromyl chloride Preparation Products And Raw materials
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