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tert-Butyl bromoacetate

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Company Name: Kingfirst chemical (nanjing) co.,ltd
Tel: 86-25-84522992
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Products Intro: Product Name:Tert-butyl bromoacetate
CAS:5292-43-3
Purity:99%min Package:1KG;5KG;200KG
Company Name: Henan DaKen Chemical CO.,LTD.
Tel: +86-371-55531817
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Products Intro: Product Name:tert-Butyl bromoacetate
CAS:5292-43-3
Purity:99% Package:100g,500g,1KG,10KG,100KG
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Products Intro: Product Name:tert-Butyl bromoacetate
CAS:5292-43-3
Purity:98.5% Package:depends on the quantity
Company Name: Henan Tianfu Chemical Co.,Ltd.
Tel: 0371-55170693
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Products Intro: CAS:5292-43-3
Purity:99% Package:500G;1KG;5KG;25KG
Company Name: Shanghai Time Chemicals CO., Ltd.
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Products Intro: Product Name:tert-Butyl bromoacetate
CAS:5292-43-3

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  • About tert-Butyl bromoacetate
  • The invention relates to a synthesis method of tert-butyl bromoacetate, and the synthesis method comprises the following steps....
  • Aug 19,2019
tert-Butyl bromoacetate Basic information
Product Name:tert-Butyl bromoacetate
Synonyms:1-Butylbromoacetate;Acetic acid, bromo-, tert-butyl ester;aceticacid,bromo-,1,1-dimethylethylester;BrCH2C(O)OC(CH3)3;2-BROMOACETIC ACID-TERT-BUTYL ESTER;BROMOACETIC ACID TERT-BUTYL ESTER;BUTYLBROMOACETATE-TERT;TERT-BUTYL 2-BROMOACETATE
CAS:5292-43-3
MF:C6H11BrO2
MW:195.05
EINECS:226-133-6
Product Categories:ACID BASED BROMO COMPOUNDS;C6 to C7;Carbonyl Compounds;Esters;organic chemical;Building Blocks;C6 to C7;Carbonyl Compounds;Chemical Synthesis;Organic Building Blocks;Pharmaceutical intermediates
Mol File:5292-43-3.mol
tert-Butyl bromoacetate Structure
tert-Butyl bromoacetate Chemical Properties
Boiling point 50 °C10 mm Hg(lit.)
density 1.338
refractive index n20/D 1.445(lit.)
Fp 121 °F
storage temp. 0-6°C
form Liquid
Specific Gravity1.333 (20/4℃)
color Clear colorless to yellow
Water Solubility Miscible with ethanol, chloroform and ethyl acetate. Immiscible with water.
Sensitive Lachrymatory
BRN 1753010
InChIKeyBNWCETAHAJSBFG-UHFFFAOYSA-N
CAS DataBase Reference5292-43-3(CAS DataBase Reference)
NIST Chemistry ReferenceAcetic acid, bromo-, 1,1-dimethylethyl ester(5292-43-3)
EPA Substance Registry SystemAcetic acid, bromo-, 1,1-dimethylethyl ester(5292-43-3)
Safety Information
Hazard Codes Xi,F
Risk Statements 10-36/37/38
Safety Statements 26-24/25-16
RIDADR UN 1993 3/PG 3
WGK Germany 3
19
Hazard Note Irritant/Flammable/Lachrymatory
TSCA T
HazardClass 3
PackingGroup III
HS Code 29159080
MSDS Information
ProviderLanguage
t-Butyl 2-bromo acetate English
SigmaAldrich English
ACROS English
ALFA English
tert-Butyl bromoacetate Usage And Synthesis
Chemical Propertiesclear colorless to yellow liquid
Usestert-Butyl Bromoacetate is a halogenated t-butyl acetate commonly used as an alkylating agent. tert-Butyl Bromoacetate is used in the synthesis of collagenase inhibitors.
Purification MethodsDissolve the ester in Et2O, wash it well with ice cold 10% aqueous K2CO3, dry it over CaCl2, filter and evaporate the Et2O, then fractionate it through a Vigreux column (p 11) in a vacuum. LACHRYMATORY. [Abramovitch et al. J Am Chem Soc 64 2274 1942, Abramovitch & Hauser J Am Chem Soc 65 986 1943, Beilstein 2 III 482.]
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