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(R)-(-)-Citramalic acid

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Company Name: Meryer (Shanghai) Chemical Technology Co., Ltd.  
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Company Name: Shanghai Macklin Biochemical Co.,Ltd.  
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(R)-(-)-Citramalic acid manufacturers

(R)-(-)-Citramalic acid Basic information
Product Name:(R)-(-)-Citramalic acid
Synonyms:(-)-2-METHYLMALIC ACID;2-METHYLMALIC ACID;(-)-2-HYDROXY-2-METHYLBUTANEDIOIC ACID;2-HYDROXY-2-METHYLBUTANEDIOIC ACID;(R)-(-)-2-HYDROXY-2-METHYLBUTANEDIOIC ACID;(R)-2-HYDROXY-2-METHYLSUCCINIC ACID;(R)-(-)-Citramalic acid, 98+%;Butanedioic acid, 2-hydroxy-2-methyl-, (2R)-
CAS:6236-10-8
MF:C5H8O5
MW:148.11
EINECS:
Product Categories:Carboxylic Acids (Chiral);Chiral Building Blocks;Synthetic Organic Chemistry
Mol File:6236-10-8.mol
(R)-(-)-Citramalic acid Structure
(R)-(-)-Citramalic acid Chemical Properties
Melting point 108-110 °C(lit.)
Boiling point 188.68°C (rough estimate)
density 1.2336 (rough estimate)
refractive index 1.3920 (estimate)
storage temp. 2-8°C
solubility PBS (pH 7.2): 10 mg/ml
form powder or crystals
pka3.65±0.28(Predicted)
Optical Rotation[α]/D -19.0±1.0°, c = 0.5 in 1 M HCl
Merck 2323
BRN 1723818
InChI1S/C5H8O5/c1-5(10,4(8)9)2-3(6)7/h10H,2H2,1H3,(H,6,7)(H,8,9)/t5-/m1/s1
InChIKeyXFTRTWQBIOMVPK-RXMQYKEDSA-N
SMILESC[C@@](O)(CC(O)=O)C(O)=O || C[C@@](O)(CC(O)=O)C(O)=O
CAS DataBase Reference6236-10-8(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 3
F 3-10
Storage Class11 - Combustible Solids
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
(R)-(-)-Citramalic acid Usage And Synthesis
Chemical Propertieswhite fine crystalline powder
DefinitionChEBI: D-citramalic acid is the D-enantiomer of citramalic acid. It is a conjugate acid of a D-citramalate(2-).
Biological ActivityCitramalate is a biochemical intermediate known to be involved in several aspects of bacterial metabolism, including, among others, the anaerobic metabolism of glutamate via the methylaspartate pathway of Clostridium tetanomorphum.
References[1] D M HOWELL  R H W  H Xu. (R)-citramalate synthase in methanogenic archaea.[J]. Journal of Bacteriology, 1999, 181 1: 331-333. DOI: 10.1128/jb.181.1.331-333.1999
[2] W BUCKEL  H A B. Two pathways of glutamate fermentation by anaerobic bacteria.[J]. Journal of Bacteriology, 1974, 117 3: 1248-1260. DOI: 10.1128/jb.117.3.1248-1260.1974
[3] SILKE FRIEDMANN  Georg F  Birgit E Alber. Properties of succinyl-coenzyme A:D-citramalate coenzyme A transferase and its role in the autotrophic 3-hydroxypropionate cycle of Chloroflexus aurantiacus.[J]. Journal of Bacteriology, 2006, 188 18: 6460-6468. DOI: 10.1128/jb.00659-06
(R)-(-)-Citramalic acid Preparation Products And Raw materials
Tag:(R)-(-)-Citramalic acid(6236-10-8) Related Product Information
AMMONIUM BISMUTH CITRATE Sodium citrate Ammonium citrate dibasic Triethyl citrate oxeladin 1,2,3-Propanetricarboxylicacid,2-hydroxy-,potassiumsalt Alverine citrate CAFFEINE CITRATED FERRIC CITRATE Phenyltoloxamine citrate Acetyl tributyl citrate Ammonium citrate tribasic Piperazine citrate Tributyl citrate Citric acid Trimethyl citrate Diethylcarbamazine citrate (S)-(+)-Citramalic acid