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Aluminium chloride hexahydrate

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Aluminium chloride hexahydrate manufacturers

Aluminium chloride hexahydrate Basic information
Physical Properties Uses Preparation Reactions
Product Name:Aluminium chloride hexahydrate
Synonyms:aluminum(iii)chloride,hexahydrate;Aluminumchloride(AlCl3)hexahydrate;chlorured’aluminium,hexahydrate;hydrousaluminumchloride;ALUMINIUM CHLORIDE 6H2O;ALUMINIUM CHLORIDE 6-HYDRATE;ALUMINIUM CHLORIDE HEXAHYDRATE;ALUMINIUM CHLORIDE HYDRATE
Product Categories:Aluminum;AluminumSynthetic Reagents;Catalysis and Inorganic Chemistry;Chemical Synthesis;Lewis Acids;Industrial/Fine Chemicals;metal halide
Mol File:7784-13-6.mol
Aluminium chloride hexahydrate Structure
Aluminium chloride hexahydrate Chemical Properties
Melting point 100°C (dec.)
density 2.39
vapor pressure 1 mm Hg ( 100 °C)
storage temp. Store at +15°C to +25°C.
solubility water: soluble0.5g/10 mL, clear, colorless
form Solid
Specific Gravity2.398
color White To Light Yellow
PH2.5 (50g/l, H2O, 20℃)
PH Range2.5 - 3.5
Water Solubility 477 g/L (20 ºC)
Sensitive Moisture Sensitive
Merck 14,337
Exposure limitsNIOSH: TWA 2 mg/m3
Stability:Stable, but may decompose upon exposure to moist air or water. Incompatible with acids.Note that decomposition of the anhydrous product, possibly caused by moisture leaking into the container or being trapped within it, may cause a pressure rise in a sealed container, potentially leading to explosive rupture.
LogP-1.380 (est)
CAS DataBase Reference7784-13-6(CAS DataBase Reference)
Safety Information
Hazard Codes Xi,C
Risk Statements 36/37/38-34-36/38-52
Safety Statements 26-45-36/37/39
RIDADR UN 3260 8/PG 3
WGK Germany 1
RTECS BD0530000
HazardClass 8
PackingGroup III
HS Code 28273200
ToxicityLD50 orally in Rabbit: 3311 mg/kg
MSDS Information
Aluminium chloride hexahydrate English
SigmaAldrich English
ACROS English
Aluminium chloride hexahydrate Usage And Synthesis
Physical PropertiesWhite or yellowish deliquescent powder; faint odor of HCl; density 2.40 g/cm3; soluble in water and polar organic solvents such as alcohol; aqueous solution acidic.
UsesThe Aluminium chloride hexahydrate is used in the preparation of deodorant and antiperspirant. Also, it is applied in textile finishing to improve the antistatic characteristics and flammability ratings of various textile materials. Commercially, it is sold as crystalline powder or as a 28% solution in water.
PreparationAluminum chloride hexahydrate is prepared by dissolving Al(OH)3 in conc. HCl and passing gaseous HCl through the solution at 0°C. The precipitate is washed with diethyl ether and dried. Alternatively, it is prepared by hydrolyzing anhydrous AlCl3 in cold dilute HCl.
ReactionsDecomposes to alumina when heated at 300°C;
2AlCl3 •6H2O →2Al2O3 + 6HCl + 9H2O
Reacts with caustic soda solution forming gelatinous precipitate of aluminum hydroxide (hydrous aluminum oxide); yields aluminum monobasic stearate, Al(OH)2[OOC(CH2)16CH3] when its solution is mixed with a solution of sodium stearate.
Chemical Propertieswhite to pale yellow crystalline solid
UsesPharmaceutical preparations of aluminum chloride hexahydrate are used to treat hyperhidrosis, a condition involving excessive sweating. It is also employed in deodorants, antiperspirant preparations, dyeing fabrics, refining crude oil, textile finishing, manufacturing parchment paper, preserving the wood and disinfecting stables. It also finds use as a reagent in organic synthesis. Aluminum chloride hexahydrate is also useful in water treatment process, medicine and cosmetic products.
UsesThe anhydrous form suitable as an acid catalyst, especially in Friedel-Crafts type reactions; in cracking of petroleum; in manufacture of rubbers, lubricants. The hexahydrate form used in preserving wood; disinfecting stables, slaughterhouses, etc.; in deodorants and antiperspirant preparations; refining crude oil; dyeing fabrics; manufacture of parchment paper.
Usesin preserving wood, disinfecting stables, etc.; in deodorants and antiperspirant preparations; in refining crude oil, and dyeing fabrics; in dental ceramics; in topical astringents
IndicationsAluminum chloride hexahydrate (6.25% Xerac A-C) is an effective antiperspirant that has also an antibacterial effect. It may be useful in cases of acne in which sweating is prominent or appears to be aggravating the disease, but its effects have not been well studied.
DefinitionChEBI: Aluminium trichloride hexahydrate is a hydrate. It contains an aluminium trichloride.
Aluminium chloride hexahydrate Preparation Products And Raw materials
Raw materialsHydrochloric acid-->Aluminum hydroxide-->ALUMINUM INGOTS-->Aluminium trichloride,solution
Preparation Products4-Chlorobenzhydrol-->Musk xylene-->SODIUM 3-4-ISOBUTYLPHENYL)-2,3-EPOXYBUTYURATE-->1,4,5,8-Naphthalenetetracarboxylic acid-->Vat Yellow 4-->1-(2,5-Dimethoxyphenyl)-2-oximino-1-propanone-->4-(4-Aminophenyl)butyric acid-->2-(4-isobutylphenyl)propionaldehyde oxime-->METHYL 4-(4-(BIS(2-CHLOROETHYL)AMINO)PHENYL)BUTYRATE-->KETAMINE RELATED COMPOUND A (50 MG) (1 -[(2-CHLOROPHENYL)(METHYLIMINO)METHYL]CYLCOPENTA-NOL)-->ETHYL 3-(6-METHOXY-2-NAPHTHYL)-3-METHYL GLYCIDATE-->4-Bromo-2,2-diphenylbutyric acid-->METHYL 3-(6-METHOXY-2-NAPHTHYL)-3-METHYL GLYCIDATE-->3-(o-chlorophenyl)-3-hydroxy-3-phenylpropiononitrile-->Ethyl(4-butyry-2,3-dichloro)phenoxyacetate-->1-(2,3-DICHLORO-4-HYDROXYPHENYL)BUTAN-1-ONE-->(2-Chlorophenyl)phenyl-methanone-->4-[2-(diethylamino)ethoxy]benzophenone-->BUCLIZINE-->METHYL 4-(4-(BIS(2-HYDROXYETHYL)AMINO)PHENYL)BUTYRATE-->ALPHA,ALPHA-DIPHENYL-GAMMA-BUTYROLACTONE-->8-ACETYL-7-HYDROXY-4-METHYLCOUMARIN-->1,5-DIHYDROXYANTHRAQUINONE-->3-BENZOYLPHENYLACETIC ACID-->ETHYL 3-(4-ISOBUTYLPHENYL)-3-METHYL GLYCIDATE-->3,3-Diphenylpropionic acid-->4-BROMO-2,2-DIPHENYLBUTYRONITRILE-->3,4-Dichlorobenzophenone-->water-proofing agnet AC-->5-(2-Carboxybenzoyl)-2-chlorobenzenesulfonyl chloride-->4-chloro-4'-methoxybenzophenone-->2-(4-Chlorobenzoyl)benzoic acid-->3-(4-ACETYLAMINOBENZOYL)PROPANOIC ACID-->3-BENZOYLPROPIONIC ACID-->1,4-Dibenzoylbutane-->2',5'-Dihydroxyacetophenone-->ALUMINUM CHLOROHYDRATE-->2-BENZOYLBENZOYL CHLORIDE-->TRANS-1,2-DIBENZOYLETHYLENE-->4-tert-Amylphenol
Tag:Aluminium chloride hexahydrate(7784-13-6) Related Product Information
Bicyclo[2.2.1]heptan-2-one, 1,7,7-trimethyl-, reaction products with aluminum chloride, sodium bromide and titanium trichloride ALUMINUM SESQUICHLOROHYDRATE ALUMINUM CHLORIDE FUNCTIONALIZED SILIC& ALUMINUM CHLORIDE-TETRAHYDROFURAN COMPL& Benzene, C10-13-alkyl derivs., aluminum chloride hydrolysis tars, distn. residues Aluminum chloride dihydroxide Aluminum chloride phosphate Benzene, dimethyl-, reaction products with aluminum chloride and 1,2-dichloroethane ALUMINIUM CHLORIDE HEXAHYDRATE PH. EUR (1.01084) Aluminum chloride hydroxide silicate Aluminium trichloride,solution ALUMINUM CHLORIDE HYDRATE,ALUMINUM CHLORIDE HYDRATE, 99.999% Aluminum chloride hydroxide sulfate SODIUM ALUMINUM CHLORIDE Ethyl(ethylmethylsilyloxy)aluminum chloride 3/4 BASIC ALUMINUM CHLORIDE ALUMINUM CHLORIDE, 6.0N STANDARDIZED SOLUTION Benzene, methyl-, reaction products with aluminum chloride and 1,2-dichloroethane