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Cupric bromide

Cupric bromide Suppliers list
Company Name: Shanghai Bojing Chemical Co.,Ltd.
Tel: +86-21-37122233
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Products Intro: Product Name:Copper(II) bromide, anhydrous
CAS:7789-45-9
Purity:99% Package:1kg;25kg;200kg Cardboard barrels Remarks:crystalline
Company Name: Nanjing Finetech Chemical Co., Ltd.
Tel: 025-85710122 17714198479
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Products Intro: Product Name:Copper(II) bromide
CAS:7789-45-9
Purity:99%min Package:1KG;10KG;100KG;500KG;100g Remarks:ISO certified
Company Name: Zjartschem
Tel: +86-571-8723 8903 jocelynpan@zjarts.com
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Products Intro: Product Name:Copper(II) bromide
CAS:7789-45-9
Purity:98% Package:10kg;55USD|1kg;10USD|5 kg;30USD
Company Name: Shanghai Zheyan Biotech Co., Ltd.
Tel: 18017610038
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Products Intro: Product Name:Cupric bromide
CAS:7789-45-9
Purity:AR,98.5% Package:250g
Company Name: Hubei Jusheng Technology Co.,Ltd.
Tel: 86-18871470254
Email: linda@hubeijusheng.com
Products Intro: Product Name:Copper(II) bromide
CAS:7789-45-9
Purity:99% Package:5KG;1KG Remarks:Br2Cu

Cupric bromide manufacturers

  • Cupric bromide
  • $10.00 / KG
  • 2021-10-29
  • CAS:7789-45-9
  • Min. Order: 100KG
  • Purity: 99%
  • Supply Ability: 100 mt
Cupric bromide Basic information
Description Chemical Properties Uses Preparation References
Product Name:Cupric bromide
Synonyms:copperbromide(cubr2);copperdibromide;CUPRIC BROMIDE;COPPER(II) BROMIDE;COPPER BROMIDE;COPPER(+2)BROMIDE;Copperic bromide ;Copper(Ⅱ) bromide
CAS:7789-45-9
MF:Br2Cu
MW:223.35
EINECS:232-167-2
Product Categories:metal halide;Inorganics
Mol File:7789-45-9.mol
Cupric bromide Structure
Cupric bromide Chemical Properties
Melting point 498 °C(lit.)
Boiling point 900 °C
density 4.77 g/mL at 25 °C(lit.)
Fp 900°C
storage temp. Store below +30°C.
solubility 1200g/l
form Crystalline Powder
Specific Gravity4.77
color Gray-blue
Water Solubility soluble
Sensitive Hygroscopic
Merck 14,2629
Stability:Stable. Incompatible with alkali metals, moisture. Reacts violently with potassium.
CAS DataBase Reference7789-45-9(CAS DataBase Reference)
NIST Chemistry Referencecopper(II) dibromide(7789-45-9)
EPA Substance Registry SystemCopper bromide (CuBr2) (7789-45-9)
Safety Information
Hazard Codes C,Xi
Risk Statements 22-34-36/37/38
Safety Statements 26-36/37/39-45-24/25
RIDADR UN 3260 8/PG 3
WGK Germany 3
TSCA Yes
HS Code 2827 59 00
HazardClass 8
PackingGroup III
Hazardous Substances Data7789-45-9(Hazardous Substances Data)
ToxicityLD50 orally in Rabbit: 536 mg/kg
MSDS Information
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Cupric bromide English
SigmaAldrich English
ACROS English
ALFA English
Cupric bromide Usage And Synthesis
DescriptionCupric bromide is a kind of inorganic compound obtained through the reaction between copper oxide and hydrobromic acid. It can be used in laser, generating pulse yellow and green light. The cupric bromide laser is an important technology used in dermatology for the treatment of pigmented lesion and vascular lesions. It can also be used in living radical polymerization and as an intensifier in photographic processing. It is also a brominating agent used in organic synthesis. In addition, it is a kind of highly efficient catalyst in the direct alkynylation of azoles.
Chemical PropertiesCopper(II) bromide, CuBr2, [7789-45-9], MW 223.36, MP 498°C, d 4.77, is a black, deliquescent, monoclinic, crystalline material that obtains from warm aqueous solution. At temperatures below 29°C, the green tetrahydrate is produced. Copper(II) bromide is very soluble in water and soluble in alcohol and acetone.
UsesCopper(II) bromide is used as a catalyst in organic reactions, as an intensifier in photography, and as a brominating agent.
PreparationCopper(II) bromide is most easily prepared by neutralization of copper(II) oxide, carbonate, or hydroxide with hydrobromic acid. It can also be produced by oxidation of copper metal with bromine water or by reaction of bromine solutions in alcohol with copper powder.
ReferencesShen, Youqing, Shiping Zhu, and Robert Pelton. Macromolecules 34.10 (2001): 3182-3185.
Rothfleisch, Jeremy E., et al. Dermatologic clinics 20.1 (2002): 1- 18.
Huang, Jianhui, Simon JF Macdonald, and Joseph PA Harrity. Chemical Communications 4 (2009): 436-438.
Besselièvre, François, and Sandrine Piguel. Angewandte Chemie International Edition 48.50 (2009): 9553-9556.
Chemical PropertiesBlack crystal
UsesAs intensifier in photography; as brominating agent in organic synthesis; as humidity indicator; as wood preservative; in solid-electrolyte battery; as stabilizer for acetylated polyformaldehyde.
UsesCopper(II) bromide is used in photographic processing as an intensifier and as a brominating agent in organic synthesis. It is also used in the coupling of o-iodophenols and aryl acetylenes avoiding the use of palladium. It finds application in the preparation of NK1/NK2 receptor antagonists used in the regulation of tachykinin.
General DescriptionOdorless black solid. Sinks and mixes with water.
Air & Water ReactionsDeliquescent. Water soluble.
Reactivity ProfileAcidic inorganic salts, such as Cupric bromide, are generally soluble in water. The resulting solutions contain moderate concentrations of hydrogen ions and have pH's of less than 7.0. They react as acids to neutralize bases. These neutralizations generate heat, but less or far less than is generated by neutralization of inorganic acids, inorganic oxoacids, and carboxylic acid. They usually do not react as either oxidizing agents or reducing agents but such behavior is not impossible. Many of these compounds catalyze organic reactions.
Health HazardInhalation of dust causes irritation of throat and lungs. Ingestion of large amounts causes violent vomiting and purging, intense pain, collapse, coma, convulsions, and paralysis. Contact with solutions causes eye irritation; contact with solid causes severe eye surface injury and skin irritation.
Fire HazardSpecial Hazards of Combustion Products: Irritating hydrogen bromide gas may form in fire.
Purification MethodsCrystallise it twice by dissolving it in water (140mL/g), filtering to remove any Cu2Br2, and concentrating under vacuum at 30o until crystals appear. The cupric bromide is then allowed to crystallise by leaving the solution in a vacuum desiccator containing P2O5 [Hope et al. J Chem Soc 5226 1960, Glemser & Sauer in Handbook of Preparative Inorganic Chemistry (Ed. Brauer) Academic Press Vol II p 1009 1965].
Tag:Cupric bromide(7789-45-9) Related Product Information
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