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ChemicalBook >> CAS DataBase List >> Benzyl (2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate

Benzyl (2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate

Benzyl (2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate price.
  • $17 - $1139.99
  • Product name: Benzyl (2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate
  • CAS: 105228-46-4
  • MF: C24H21NO4
  • MW: 387.43
  • EINECS:
  • MDL Number:MFCD00074956
  • Synonyms:BENZYL (2S,3R)-(+)-6-OXO-2,3-DIPHENYL-4-MORPHOLINECARBOXYLATE;(2S,3R)-benzyl 6-oxo-2,3- diphenylmorpholine-4-carboxylate;4-Morpholinecarboxylic acid, 6-oxo-2,3-diphenyl-, phenylmethyl ester, (2S,3R)-;3-diphenyl-;4-Morpholinecarboxylicacid;6-oxo-2;(2S,3R)-(+)-N-Z-6-oxo-2,3-diphenylMorpholine;(5S,6R)-(+)-4-Benzyloxycarbonyl-5,6-diphenyl-2-Morpholinone
18 prices
Selected condition:
Brand
  • AK Scientific
  • Alichem
  • Ambeed
  • American Custom Chemicals Corporation
  • Chem-Impex
  • ChemScene
  • Crysdot
  • Sigma-Aldrich
  • TRC
Package
  • 100mg
  • 250mg
  • 500mg
  • 1g
  • 5g
  • 10g
  • 25g
  • ManufacturerAK Scientific
  • Product number1194AA
  • Product description(2S,3R)-Benzyl6-oxo-2,3-diphenylmorpholine-4-carboxylate
  • Packaging250mg
  • Price$92
  • Updated2021-12-16
  • Buy
  • ManufacturerAlichem
  • Product number105228464
  • Product descriptionBenzyl(2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate
  • Packaging10g
  • Price$507
  • Updated2021-12-16
  • Buy
  • ManufacturerAlichem
  • Product number105228464
  • Product descriptionBenzyl(2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate
  • Packaging25g
  • Price$975
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA180131
  • Product description(2S,3R)-Benzyl6-oxo-2,3-diphenylmorpholine-4-carboxylate 95+%
  • Packaging100mg
  • Price$17
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA180131
  • Product description(2S,3R)-Benzyl6-oxo-2,3-diphenylmorpholine-4-carboxylate 95+%
  • Packaging250mg
  • Price$24
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA180131
  • Product description(2S,3R)-Benzyl6-oxo-2,3-diphenylmorpholine-4-carboxylate 95+%
  • Packaging1g
  • Price$47
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA180131
  • Product description(2S,3R)-Benzyl6-oxo-2,3-diphenylmorpholine-4-carboxylate 95+%
  • Packaging5g
  • Price$143
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA180131
  • Product description(2S,3R)-Benzyl6-oxo-2,3-diphenylmorpholine-4-carboxylate 95+%
  • Packaging10g
  • Price$233
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA180131
  • Product description(2S,3R)-Benzyl6-oxo-2,3-diphenylmorpholine-4-carboxylate 95+%
  • Packaging25g
  • Price$487
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberCHM0013853
  • Product descriptionBENZYL (2S,3R)-(+)-6-OXO-2,3-DIPHENYL-4-MORPHOLINECARBOXYLATE 95.00%
  • Packaging5G
  • Price$1139.99
  • Updated2021-12-16
  • Buy
  • ManufacturerChem-Impex
  • Product number41476
  • Product description(2S,3R)-(+)-N-Z-6-oxo-2,3-diphenylmorpholine,≥98.5%(HPLC) ≥98.5%(HPLC)
  • Packaging1G
  • Price$88.52
  • Updated2021-12-16
  • Buy
  • ManufacturerChemScene
  • Product numberCS-B0131
  • Product description4-Morpholinecarboxylicacid,6-oxo-2,3-diphenyl-,phenylmethylester,(2S,3R)-
  • Packaging1g
  • Price$78
  • Updated2021-12-16
  • Buy
  • ManufacturerChemScene
  • Product numberCS-B0131
  • Product description4-Morpholinecarboxylicacid,6-oxo-2,3-diphenyl-,phenylmethylester,(2S,3R)-
  • Packaging5g
  • Price$242
  • Updated2021-12-16
  • Buy
  • ManufacturerCrysdot
  • Product numberCD11359475
  • Product description(2S,3R)-Benzyl6-oxo-2,3-diphenylmorpholine-4-carboxylate 95+%
  • Packaging5g
  • Price$248
  • Updated2021-12-16
  • Buy
  • ManufacturerCrysdot
  • Product numberCD11359475
  • Product description(2S,3R)-Benzyl6-oxo-2,3-diphenylmorpholine-4-carboxylate 95+%
  • Packaging10g
  • Price$386
  • Updated2021-12-16
  • Buy
  • ManufacturerCrysdot
  • Product numberCD11359475
  • Product description(2S,3R)-Benzyl6-oxo-2,3-diphenylmorpholine-4-carboxylate 95+%
  • Packaging25g
  • Price$743
  • Updated2021-12-16
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
AK Scientific 1194AA (2S,3R)-Benzyl6-oxo-2,3-diphenylmorpholine-4-carboxylate 250mg $92 2021-12-16 Buy
Alichem 105228464 Benzyl(2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate 10g $507 2021-12-16 Buy
Alichem 105228464 Benzyl(2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate 25g $975 2021-12-16 Buy
Ambeed A180131 (2S,3R)-Benzyl6-oxo-2,3-diphenylmorpholine-4-carboxylate 95+% 100mg $17 2021-12-16 Buy
Ambeed A180131 (2S,3R)-Benzyl6-oxo-2,3-diphenylmorpholine-4-carboxylate 95+% 250mg $24 2021-12-16 Buy
Ambeed A180131 (2S,3R)-Benzyl6-oxo-2,3-diphenylmorpholine-4-carboxylate 95+% 1g $47 2021-12-16 Buy
Ambeed A180131 (2S,3R)-Benzyl6-oxo-2,3-diphenylmorpholine-4-carboxylate 95+% 5g $143 2021-12-16 Buy
Ambeed A180131 (2S,3R)-Benzyl6-oxo-2,3-diphenylmorpholine-4-carboxylate 95+% 10g $233 2021-12-16 Buy
Ambeed A180131 (2S,3R)-Benzyl6-oxo-2,3-diphenylmorpholine-4-carboxylate 95+% 25g $487 2021-12-16 Buy
American Custom Chemicals Corporation CHM0013853 BENZYL (2S,3R)-(+)-6-OXO-2,3-DIPHENYL-4-MORPHOLINECARBOXYLATE 95.00% 5G $1139.99 2021-12-16 Buy
Chem-Impex 41476 (2S,3R)-(+)-N-Z-6-oxo-2,3-diphenylmorpholine,≥98.5%(HPLC) ≥98.5%(HPLC) 1G $88.52 2021-12-16 Buy
ChemScene CS-B0131 4-Morpholinecarboxylicacid,6-oxo-2,3-diphenyl-,phenylmethylester,(2S,3R)- 1g $78 2021-12-16 Buy
ChemScene CS-B0131 4-Morpholinecarboxylicacid,6-oxo-2,3-diphenyl-,phenylmethylester,(2S,3R)- 5g $242 2021-12-16 Buy
Crysdot CD11359475 (2S,3R)-Benzyl6-oxo-2,3-diphenylmorpholine-4-carboxylate 95+% 5g $248 2021-12-16 Buy
Crysdot CD11359475 (2S,3R)-Benzyl6-oxo-2,3-diphenylmorpholine-4-carboxylate 95+% 10g $386 2021-12-16 Buy
Crysdot CD11359475 (2S,3R)-Benzyl6-oxo-2,3-diphenylmorpholine-4-carboxylate 95+% 25g $743 2021-12-16 Buy

Properties

Melting point :205-207 °C(lit.)
alpha :66 º (c=5.5 in methylene chloride)
Boiling point :583.5±50.0 °C(Predicted)
Density :1.242±0.06 g/cm3(Predicted)
storage temp. :2-8°C
pka :-3.33±0.60(Predicted)
optical activity :[α]25/D +66°, c = 5.5 in methylene chloride

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

(2S,3R)-(+)-N-Z-6-oxo-2,3-diphenylmorpholine can be used as a starting material for the synthesis of:
  • α-Amino-β-silyloxy-ester, a key intermediate for the preparation of antimalarial drug quinine and its analogs.
  • R, R-Formylglycine dimethylacetal, a key intermediate for the preparation of tuberculostatic compound capreomycin IB.
  • 2R,5R,6S-2-(Methoxycarbonylmethyl)-5,6-diphenylmorpholine hydrochloride, a key intermediate for the preparation of an antibiotic (+)-negamycin.


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