Ferrocenecarboxaldehyde synthesis
- Product Name:Ferrocenecarboxaldehyde
- CAS Number:12093-10-6
- Molecular formula:C11H10FeO10*
- Molecular Weight:214.04
Ferrocenecarboxaldehyde can be obtained from the reaction of ferrocene and N-methylformylaniline in phosphorus trichloride, treated with sodium bicarbonate. The product can also be obtained after a similar step with N,N-dimethylformamide involved in th
1273-86-5
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12093-10-6
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Yield:12093-10-6 92%
Reaction Conditions:
with ferrocene-labeled Merrifield resin-supported ionic liquid ([FemDMMerA]RuO4) in tetrahydrofuran for 4 h;Reflux;Green chemistry;
Steps:
General procedure for the oxidation of alcohols
General procedure: A mixture of aryl alcohol (1 mmol) and [FemDMMerA]Y (100 mg) in solvent(5 mL) was refluxed in oil bath. After completion of the reaction as monitored byTLC, the reaction mixture was filtered to remove insoluble SILP catalyst.Evaporation of solvent in vacuuo followed by column chromatography over silicagel using petroleum ether/ethyl acetate (95:5 v/v) afforded pure aldehydes.
References:
Kurane, Rajanikant;Bansode, Prakash;Khanapure, Sharanabasappa;Salunkhe, Rajashri;Rashinkar, Gajanan [Research on Chemical Intermediates,2016,vol. 42,# 12,p. 7807 - 7821]
102-54-5
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122-51-0
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12093-10-6
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$8.00/1g
102-54-5
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75-09-2
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12093-10-6
187 suppliers
$8.00/1g