ChemicalBook CAS DataBase List METHOXYBENZOQUINONE

METHOXYBENZOQUINONE synthesis

15synthesis methods

Product Name:METHOXYBENZOQUINONE
CAS Number:2880-58-2
Molecular formula:C7H6O3
Molecular Weight:138.12

90-05-1 Synthesis

90-05-1
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$5.00/1g

2880-58-2
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$90.00/250mg

Yield: 95%

Reaction Conditions:

with 1-(4-sulfonylbutyl)-3-methylimidazolium trifluoroacetate;5,10,15,20-tetra(2',6'-dichlorophenyl)porphyrinatoiron(III) chloride;dihydrogen peroxide in dichloromethaneReagent/catalyst;

Steps:

Reaction of phenols with hydrogen peroxide catalysed by iron(III) porphyrins in binary mixture of acidic ILs (2a-2f) and dichloromethane
Table 1
).
The reaction of 3a in 3:
1 binary mixture of DCM and IL 2a possessing viscosity of about 69 cP gave 4a in 89% yield (entry 6,

References:

Ahmad, Sohail;Gautam, Renu;Singhal, Anchal;Chauhan [Journal of Molecular Liquids,2018,vol. 260,p. 292 - 303]