N-(cyclohexylmethyl)cyclohexanamine synthesis
- Product Name:N-(cyclohexylmethyl)cyclohexanamine
- CAS Number:87364-66-7
- Molecular formula:C13H25N
- Molecular Weight:195.34
3218-02-8
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$21.00/1mL
108-95-2
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$14.00/25g
87364-66-7
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$496.88/5MG
108-93-0
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$11.00/25g
Yield:87364-66-7 68 %Chromat.
Reaction Conditions:
with hydrogen at 40; under 3750.38 Torr; for 24 h;Autoclave;
Steps:
Generalprocedure for catalytic reductive amination of phenol
General procedure: Reductiveamination of phenols was carried out in a 10-mL autoclave reactor equipped witha glass tube. In a typical experiment, the reactor was charged with 1 mmol ofsubstrate, 1.2-3 mmol of ammonia (28 % aqueous ammonia)/amines and catalyst (2mol %). For the reactions of CHP, 1 mol% (calculated on metal amount) of 5 wt%Rh-PVP-5 wt% Sn/TiO2 catalyst was used. The reactor was purged,pressurized to 5-20 bar of hydrogen and heated to 40-100 °C. The conversion andyield of product were obtained by GC analysis using dodocane an internalstandard. The products were confirmed by GC-MS analysis.
References:
Chaudhari, Chandan;Nagaoka, Katsutoshi;Nishida, Yoshihide;Rumi, Saeki;Sato, Katsutoshi;Shiraishi, Masaya [Chemistry Letters,2022,vol. 51,# 1,p. 81 - 84] Location in patent:supporting information
56037-75-3
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87364-66-7
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$496.88/5MG
626-62-0
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3218-02-8
156 suppliers
$21.00/1mL
87364-66-7
10 suppliers
$496.88/5MG
108-91-8
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1192-37-6
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87364-66-7
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$496.88/5MG