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Phenol

CAS No. 108-95-2
Chemical Name: Phenol
Synonyms: Izal;PhOH;Fenol;PHENOL;Fenolo;NA 2821;Paoscle;Phenole;BENZENOL;PhenolGr
CBNumber: CB4362168
Molecular Formula: C6H6O
Formula Weight: 94.11
MOL File: 108-95-2.mol
Phenol Property
Melting point : 40-42 °C(lit.)
Boiling point : 182 °C(lit.)
density : 1.071 g/mL at 25 °C(lit.)
vapor density : 3.24 (vs air)
vapor pressure : 0.09 psi ( 55 °C)
refractive index : n20/D 1.53
FEMA : 3223
Fp : 175 °F
storage temp. : 2-8°C
solubility : H2O: 50 mg/mL at 20 °C, clear, colorless
form : liquid
pka: 9.89(at 20℃)
color : faintly yellow
PH: 3.0-6.0 (25℃, 0.5M in H2O)
Water Solubility : 8 g/100 mL
FreezingPoint : 41℃
Sensitive : Air & Light Sensitive
Merck : 14,7241
BRN : 969616
CAS DataBase Reference: 108-95-2(CAS DataBase Reference)
NIST Chemistry Reference: Phenol(108-95-2)
EPA Substance Registry System: Phenol(108-95-2)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
Hazard Codes : T,C,F,Xn
Risk Statements : 23/24/25-34-48/20/21/22-68-40-39/23/24/25-11-36-20/21/22-24/25
Safety Statements : 26-36/37/39-45-36/37-28A-28-24/25-1/2-36-16-7
RIDADR : UN 2821 6.1/PG 2
WGK Germany : 2
RTECS : SJ3325000
F : 8-23
TSCA : Yes
HazardClass : 6.1
PackingGroup : II
HS Code : 29071100
Hazardous Substances Data: 108-95-2(Hazardous Substances Data)
Symbol(GHS):
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H225 Highly Flammable liquid and vapour Flammable liquids Category 2 Danger P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H227 Combustible liquid Flammable liquids Category 4 Warning P210, P280, P370+P378, P403+P235,P501
H301 Toxic if swalloed Acute toxicity,oral Category 3 Danger P264, P270, P301+P310, P321, P330,P405, P501
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning P264, P270, P301+P312, P330, P501
H311 Toxic in contact with skin Acute toxicity,dermal Category 3 Danger P280, P302+P352, P312, P322, P361,P363, P405, P501
H312 Harmful in contact with skin Acute toxicity,dermal Category 4 Warning P280,P302+P352, P312, P322, P363,P501
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H318 Causes serious eye damage Serious eye damage/eye irritation Category 1 Danger P280, P305+P351+P338, P310
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning P264, P280, P305+P351+P338,P337+P313P
H331 Toxic if inhaled Acute toxicity,inhalation Category 3 Danger P261, P271, P304+P340, P311, P321,P403+P233, P405, P501
H332 Harmful if inhaled Acute toxicity,inhalation Category 4 Warning P261, P271, P304+P340, P312
H340 May cause genetic defects Germ cell mutagenicity Category 1A, 1B Danger
H341 Suspected of causing genetic defects Germ cell mutagenicity Category 2 Warning P201,P202, P281, P308+P313, P405,P501
H360 May damage fertility or the unborn child Reproductive toxicity Category 1A, 1B Danger
H370 Causes damage to organs Specific target organ toxicity, single exposure Category 1 Danger P260, P264, P270, P307+P311, P321,P405, P501
H372 Causes damage to organs through prolonged or repeated exposure Specific target organ toxicity, repeated exposure Category 1 Danger P260, P264, P270, P314, P501
H373 May cause damage to organs through prolonged or repeated exposure Specific target organ toxicity, repeated exposure Category 2 Warning P260, P314, P501
H401 Toxic to aquatic life Hazardous to the aquatic environment, acute hazard Category 2 P273, P501
H411 Toxic to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 2
Precautionary statements:
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P310 Immediately call a POISON CENTER or doctor/physician.
P311 Call a POISON CENTER or doctor/physician.
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P307+P311 IF exposed: call a POISON CENTER or doctor/physician.
P405 Store locked up.
P501 Dispose of contents/container to..…

Phenol Chemical Properties,Usage,Production

Chemical Properties
White solid
Uses
Purified for molecular genetics applications
Definition
ChEBI: An organic hydroxy compound that consists of benzene bearing a single hydroxy substituent. The parent of the class of phenols.
General Description
A solid melting at 110°F. Colorless if pure, otherwise pink or red. Flash point 175°F. Density 9.9 lb / gal. Vapors are heavier than air Corrosive to the skin (turning skin white) but because of its anesthetic quality numbs rather than burn. Lethal amounts can be absorbed through the skin. Used to make plastics and adhesives.
Air & Water Reactions
Decomposes slowly in air. Mixtures of 9-10% phenol in air are explosive. Soluble in water
Reactivity Profile
PHENOL is a weak acid. Reacts exothermically with bases. Reacts with strong oxidizing agents. Emits acrid smoke and irritating fumes when heated to decomposition. Undergoes, in the presence of aluminum chloride, potentially explosive reactions with nitromethane, butadiene, formaldehyde, peroxodisulfuric acid, peroxosulfuric acid, and sodium nitrite . Reacts violently with sodium nitrate in the presence of trifluoroacetic acid [Bretherick, 5th ed., 1995, p. 770]. May corrode lead, aluminum and its alloys, certain plastics, and rubber. Phenol may explode in contact with peroxodisulfuric acid (Dns, J. Ber., 1910, 43, 1880; Z. Anorg. Chem., 1911, 73, 1911.) or peroxomonosulfuric acid. (Sidgwick, 1950, 939)
Health Hazard
Toxic hazard rating is very toxic: probable oral lethal dose (human) is 50-500 mg/kg. Ingestion of 1 gram has been lethal to humans. Lethal amounts may be absorbed through skin or inhaled. Industrial contact can cause chronic poisoning with kidney and liver damage. Persons affected with hepatic or kidney diseases are at a greater risk.
Fire Hazard
Flammable vapors when heated. Runoff from fire control water may give off poisonous gases and cause pollution. Mixtures of 9-10% phenol in air are explosive. Avoid aluminum chloride/nitrobenzene mixture, peroxodisulfuric acid, peroxomonosulfuric acid and strong oxidizing agents. Decomposes slowly on air contact. Avoid contact with strong oxidizing agents.
Phenol Preparation Products And Raw materials
Raw materials
4-Isopropylaniline Liquefied petroleum ges Isoproturon CUMENE Phenol crude PROPYLENE Sodium sulfate Sodium sulfite Sulfur dioxide Benzenesulfonic acid sodium salt Sulfur trioxide COAL TAR Benzene Cumyl hydroperoxide Sodium hydroxide Fiber Glass Wool PETROLEUM ETHER Sulfuric acid
Preparation Products
2-Methyl-4-chlorophenoxyacetic acid 3-CHLORO-4-PHENOXYANILINE SODIUM PHENOLATE TRIHYDRATE Tetrabromophenol Blue Bisacodyl 3-Phenoxypropionic acid 2,4,6-Tri-tert-butylphenol Dispersing agent S BISPHENOL A DIMETHACRYLATE 4-NITROPHENYL PHENYL ETHER 2,4,6-Trichlorophenol DIPHENYL PHTHALATE 4-Phenoxybutanoic acid 4-Chromanone 2-Phenoxypropionic acid Tri(4-isopropylphenyl) phosphate Octadecyl 3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate 2,4-Di-tert-butylphenol Tris(2,4-ditert-butylphenyl) phosphite 3-PHENOXYANILINE 4'-Phenoxyacetophenone Sodium pentachlorophenolate High temperature levelling agent BOF 4-Hydroxycinnamic acid 6-PHENOXYNICOTINONITRILE Roxatidine acetate Fenpropathrin ALKYLPHENOL DISULFIDE Sulphur Indanthrene Blue RNX 3-AMINO-1-PHENOXY-2-PROPANOL HYDROCHLORIDE Acid Red 111 4-Hydroxyvalerophenone Antioxidant T502 synthetic tanning agent No.28 Seratrodast DL-4-HYDROXYMANDELIC ACID MONOHYDRATE Xanthene NITROFEN Adhesive 706
Phenol Suppliers      Global( 356)Suppliers     
Supplier Tel Fax Email Country ProdList Advantage
Shenzhen Sendi Biotechnology Co.Ltd. 0755-23311925 18102838259
0755-23311925 Abel@chembj.com CHINA 3230 55
Lianyungang Kangcheng Bio Technology Co. 15161374028 0518-80775626
0518-80775626 chuchaosen@126.com China 94 58
Shanghai Macklin Biochemical Co.,Ltd. 15221275939
021-51821727 shenlinxing@macklin.cn China 13254 55
Shanghai Aladdin Bio-Chem Technology Co.,LTD 021-20337333/400-620-6333
021-50323701 sale@aladdin-e.com China 28587 65
J & K SCIENTIFIC LTD. 400-666-7788 +86-10-82848833
+86-10-82849933 jkinfo@jkchemical.com;market6@jkchemical.com China 96832 76
Meryer (Shanghai) Chemical Technology Co., Ltd. +86-(0)21-61259100(Shanghai) +86-(0)755-86170099(ShenZhen) +86-(0)10-62670440(Beijing)
+86-(0)21-61259102(Shanghai) +86-(0)755-86170066(ShenZhen) +86-(0)10-88580358(Beijing) sh@meryer.com China 40403 62
3B Pharmachem (Wuhan) International Co.,Ltd. 86-21-50328103 * 801、802、803、804 Mobile:18930552037
86-21-50328109 3bsc@sina.com China 15950 69
Alfa Aesar 400-610-6006; 021-67582000
021-67582001/03/05 saleschina@alfa-asia.com China 30315 84
TCI (Shanghai) Development Co., Ltd. 800-988-0390
021-67121385 sales@tcishanghai.com.cn China 22833 81
Beijing dtftchem Technology Co., Ltd. 13651141086; 86(10)60275028、60275820
86 (10) 60270825 dtftchem@sina.com China 1443 62
 
108-95-2(Phenol)Related Search:
Hydroquinone Sodium benzenolate Benzene 2-BROMO-2',4'-DIMETHOXYACETOPHENONE 2-BROMO-2',5'-DIMETHOXYACETOPHENONE Decabromodiphenyl oxide 4-Bromophenetole 4-Bromophenoxybenzene 3-Bromoanisole SALCOMINE 2-Bromo-4'-methoxyacetophenone 2-BROMO-2'-METHOXYACETOPHENONE 1-(4'-Bromophenoxy)-1-ethoxyethane 2,4-DIBROMOANISOLE 4-Chlorophenol 2-Aminophenol 3-Aminophenol 4-Nitrophenol
OXYBENZENE PHENIC ACID PHENOL PHENOL, LIQUEFIED PHENOL LIQUIFIED PHENOL REAGENT PHENOL SATURATED, PH 4.5 PHENOL SINGLE PHASE BUFFER, SATURATED PHENOL STANDARD PHENOL SOLUTION PHENYL HYDROXIDE PHENYLIC ACID Organic Building Blocks Oxygen Compounds Molecular Biology Puriss p.a. Reagents Phenols PEM - POLA General Use DNA & RNA Purification Denaturation a13-01814 Acide carbolique acidecarbolique acidecarbolique(french) baker’spandsliquidandointment Baker's P & S liquid & Ointment Baker's P and S Liquid and Ointment Benzene, hydroxy- Benzophenol Carbolsaure caswellno.649 coaltaracids component of Anbesol component of Campho-phenique gel Fenol fenol(dutch,polish) Fenolo Hydroxybenaene Izal Monohydroxybenzene Monophenol NA 2821 NCI-C50124 Paoscle Phenic alcohol Phenol alcohol Phenol, molten phenol,liquid phenol,molten phenol,pure phenol,pure** phenol,solid phenolalcohol Phenole Phenyl alcohol Phenyl hydrate
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