| Identification | More | [Name]
tert-Butyl peroxyacetate | [CAS]
107-71-1 | [Synonyms]
LUPEROX 7M50
LUPEROX 7M75
T-BUTYL PERACETATE
TERT-BUTYL PERACETATE
TERT-BUTYL PEROXYACETATE
Ethaneperoxoicacid,1,1-dimethylethylester
lupersol70
peroxyaceticacid,tert-butylester
t-Butylethaneperoxoicacid
t-butylperoxyacetate
tert-butyl
trigonoxf-c50
Butylperacetate
tert-Butyl peracetate solution
Trigonox?F
TERT-BUTYL PERACETATE 75 WT. % SOLUTIO&
TERT-BUTYL PERACETATE 50 WT. % SOLUTIO&
TERT-BUTYL PERACETATE, 50 WT. % SOLUTION IN ALIPHATIC HC (LUPEROX 7M50)
50%inmineralspirit
Peracetic acid, tert-butyl ester | [EINECS(EC#)]
203-514-5 | [Molecular Formula]
C6H12O3 | [MDL Number]
MFCD00048240 | [Molecular Weight]
132.16 | [MOL File]
107-71-1.mol |
| Chemical Properties | Back Directory | [Appearance]
clear solution | [Melting point ]
-20 °C | [Boiling point ]
184.08°C (rough estimate) | [density ]
0.828 g/mL at 25 °C
| [vapor pressure ]
1.966Pa at 25℃ | [refractive index ]
n20/D 1.412
| [Fp ]
99 °F
| [storage temp. ]
Refrigerator (+4°C) + Flammables area | [form ]
Solution | [color ]
Clear | [Water Solubility ]
3.878g/L at 25℃ | [Uses]
Polymerization initiator for vinyl monomers,
manufacture of polyethylene and polystyrene.
| [CAS DataBase Reference]
107-71-1(CAS DataBase Reference) | [EPA Substance Registry System]
tert-Butyl peroxyacetate (107-71-1) |
| Safety Data | Back Directory | [Hazard Codes ]
F,T,O,Xi | [Risk Statements ]
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed .
R36/37/38:Irritating to eyes, respiratory system and skin .
R40:Limited evidence of a carcinogenic effect.
R65:Harmful: May cause lung damage if swallowed.
R22:Harmful if swallowed.
R10:Flammable.
R7:May cause fire.
R45:May cause cancer. | [Safety Statements ]
S16:Keep away from sources of ignition-No smoking .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S62:If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label .
S47:Keep at temperature not exceeding ... E C (to be specified by the manufacturer) .
S14:Keep away from ... (incompatible materials to be indicated by the manufacturer) .
S7:Keep container tightly closed .
S53:Avoid exposure-obtain special instruction before use .
S3/7:Keep container tightly closed in a cool place . | [RIDADR ]
UN 3103 5.2
| [WGK Germany ]
2
| [RTECS ]
SD8925000
| [HazardClass ]
5.2 | [PackingGroup ]
II | [HS Code ]
29159000 | [Safety Profile]
Moderately toxic by
ingestion. Mildly toxic by inhalation.
Moderate skin and eye irritant. A shockand
heat-sensitive explosive. Dangerous fire
hazard when exposed to heat, flame,
reducing agents. To fight fire, use dry
chemical, alcohol foam, spray and mist.
When heated to decomposition it emits
acrid smoke and fumes. See also
PEROXIDES, ORGANIC; and ESTERS |
| Hazard Information | Back Directory | [General Description]
This liquid peroxide is sensitive to heat. Storage of this material must be done so with stringent temperature control measures. It's explosion hazard is also mitigated by mixing the peroxide with an inert solid. | [Reactivity Profile]
TERT-BUTYL PEROXYACETATE explodes with great violence when rapidly heated to a critical temperature; pure form is shock sensitive and detonable [Bretherick 1979 p. 602]. Upon contact with organic matter, t-butyl peroxyacetate can ignite or give rise to an explosion [Haz. Chem. Data 1973 p. 77]. | [Hazard]
Flammable, dangerous fire risk. Oxidizer.
| [Chemical Properties]
clear solution | [Health Hazard]
Mild skin and eye irritant. Its toxicity is low,both via inhalation and ingestion routes.
LD50 value, oral (rats): 675 mg/kg. | [Fire Hazard]
The pure compound is highly reactive and
oxidizing, and sensitive to heat and shock.
A 75% solution in benzene or mineral
spirits is the maximum assay that is
sold commercially. Its benzene solution at
this concentration is reactive, oxidizing, and
flammable. The flash point varies depending
on the solvent; the autoignition temperature
not reported; the self-accelerating decomposition
temperature is 93°C (199.4°F).
t-Butyl peroxyacetate forms an explosive
mixture with air, explosive range not
reported. It can ignite or explode when
in contact with combustible organic compounds.
Fire-extinguishing agent: water from
a sprinkler from an explosion-resistant location;
keep the containers cool. | [Flammability and Explosibility]
Flammable | [storage]
Store in a cool and well-ventilated placeisolated from other chemicals; protect fromphysical damage. It is shipped in glass andearthenware containers not exceeding 7 lb,inside a wooden or fiberboard box. | [Purification Methods]
Wash the ester with NaHCO3 from a *benzene solution, then redistil to remove *benzene [Kochi J Am Chem Soc 84 774 1962]. Handle with adequate protection due to possible EXPLOSIVE nature. [Beilstein 2 IV 391.] |
|
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Maya High Purity Chemicals
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