ChemicalBook--->CAS DataBase List--->147-14-8

147-14-8

147-14-8 Structure

147-14-8 Structure
IdentificationBack Directory
[Name]

(29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32)copper
[CAS]

147-14-8
[Synonyms]

6430
lbx5
CUPC
AO404
BT 4651
blue15b
BLUEP5B
CI 74160
Blue GLA
Blue BGS
(sp-4-1)-)
helioblueb
phthaloblue
bermudablue
TACOMA BLUE
CI NO 74160
EM blue NCB
cyanine blue
ceresbluebhr
congoblueb-4
aqualineblue
bahamabluebc
bahamabluewd
fastoluxblue
cyaninebluec
fastogenblueb
isolfastblueb
heliogenblueb
indolenblue3g
bahamabluebnc
cyaninebluebb
ciingrainblue2
graphtolbluebl
Monastral blue
Blue D 6700T
IRGALITEBLUEBLP
MONASTRALBLUEBV
7201PHTHALOBLUE
Blue toner GTNF
PIGMENT BLUE 15
Smoke Dye, Blue
heliogenbluelbg
pigmentblue15:4
cipigmentblue15
chromatexbluebn
calcotonebluegp
cromophtalblue4g
Monastral blue B
graphtolblue2gls
fenalacbluebdisp
heliofastbluebrn
HeliogenBlue6480
cyanpeacockblueg
duratintblue1001
fastogenblue5110
IRGALITEBLUECPV2
HELIOGENBLUE7080
MONASTRALBLUEXBV
IRGALITEBLUELGLD
HELIOGENBLUE4BGO
Euvinyl blue 702
4352 Fast Blue B
4372 Fast Blue BS
Monastral Blue bf
15:3 C.I. NO.15:3
cyanbluegt55-3295
C.I.Pigmentblue15
arlocyanineblueps
bahamabluelakencnf
cyanbluebnc55-3745
cyanbluebnf55-3753
daltolitefastblueb
Pigment Blue 15:0
Pigment Blue 15:6
GRAPHTOLBLUE6825-2
Fastogen blue 5007
4382 Fast Blue BGS
Plasco blue 15:3
PERGANTINEBLUEGR-LA
Kupferphthalocyanin
Paintco blue 15:4
Cromofine blue 4950
PHTHALOCYANINE BLUE
turquoise blue base
franconiabluea-4431
copperphthalocyanin
C.I. Pigment Blue 15
accospersecyanbluegt
dainichicyanineblueb
HostapermBlueAFN,A3R
phthalocyanineblue15
PERGANTINE75%CRPASTE
Chromofine blue 4920
Cupric phthalocyanine
Fastolux peacock blue
PHTHALOCYANINE COPPER
COPPER PHTHALOCYANINE
IRGALITEBLUEGLSCPASTE
PIGMENT BLUE 15:3 EGW
MONASTRALFASTBLUEBNVS
Phthalocyanine Blue BN
Phthalocyanine Blue BS
Phthalocyanine Blue BX
Benzimidazolone yellow
C.I. Pigment Blue 15:1
C.I. Pigment Blue 15:2
C.I. Pigment Blue 15:3
dainichicyaninebluefpg
C.I. Pigment Yellow 151
Phthalocyanine Blue BGS
B PHTHALOCYANINE BLUE B
a-Copper phthalocyanine
Copper phthalocyaninato
(phthalocyaninato)-coppe
(phthalocyaninato)copper
IRGALITEBRILLIANTBLUEBLP
phthalocyanine blueB15:0
Copper(Ⅱ) phthalocyanine
C.I.PigmentBlue15(74160)
copperphthalocyanineblue
CyanineBlueBB,BF,GC,HB,LB
COPPER(II) PHTHALOCYANINE
PHTHALOCYANINE BLUE CRUDE
eta-Copper phthalocyanine
Phthalocyanine Copper(II)
Copper beta-phthalocyanine
PHTHALOCYANINE CRUDE, BLUE
Stable Phthalocyanine Blue
PB15:3 PHTHALOCYANINE BLUE
PigmentphthalocyanineblueB
PigmentphthalocyanineblueBN
PigmentphthalocyanineblueBS
PigmentphthalocyanineblueBX
irgalitefastbrilliantbluebl
Pigment Phthalocyanine Blue
PB 15:0 PHTHALOCYANINE BLUE
alpha-Copper phthalocyanine
phthalocyaninato(2-)copper 1
IRGALITEFASTBRILLIANTBLUEBNL
PigmentphthalocyanineblueFGX
(phthalocyaninato(2-))-coppe
(phthalocyaninato(2-))copper
CuPC , Copper phthalocyanine
Dhthalocynine Blue 3HB-706W
Copper tetrabenzoporphyrazine
Blue phthalocyanine alpha-form
PHTHALOCYANINE, COPPER COMPLEX
Copper phthalocyanine,CI 74160
PHTHALOCYANINE COPPER,BETA-FORM
Pigment Phthalocyanine Blue BGS
Pigment Phthalocyanine Blue NCF
Pigment Phthalocyanine Blue BRX
CuPc / Copper(II) phthalocyanine
Copper Phthalocyanine Blue (Cpc)
PHTHALOCYANINE COPPER, ALPHA-FORM
Pigment Phthalocyanine Blue 94617
29H,31H-Phthalocyanine copper salt
Copper(II) Phthalocyanine (β-forM)
PHTHALOCYANINE BLUE CRUDE ACTIVATED
C.I.Pigment Blue 15:1(Stable α-type)
Copper(II) Phthalocyanine (beta-form)
Copper(II) Phthalocyanine (alpha-form)
DRAGOCOLOR KOSMETIKFARBSTOFF PHTHALOBLAU
HelioFastBlueB,BB,BF,BRN,BT,GO,GOT,HB,HG
Copper phthalocyanine, dye content ca 95%
Pigment Blue 15 (purified by sublimation)
COPPER(II) PHTHALOCYANINE, DYE CONTENT 99+ %
COPPER(II) PHTHALOCYANINE, FOR FLUORESCE NCE
COPPER(II) PHTHALOCYANINE, SUBLIMATION GRADE
Copper phthalocyanine, dye content ca 95% 25GR
Phthalocyanine Blue Copper Phthalocyanine CuPc
CuPc, Phthalocyanine blue, Pigment Blue 15
Pigment Phthalocyanine Blue BX(Unstable α-type)
phthalocyaninebluepigment(pigmentblue15:3,15:4)
tetrabenzo-5,10,15,20-diazaporphyrinephthalocyanine
(29h,31h-phthalocyaninato(2-)-n29,n30,n31,n32)copper
Copper(II) phthalocyanine beta-forM, Dye content 90 %
Copper(II) phthalocyanine subliMed grade, Dye content 99 %
31h-phthalocyaninato(2-)-n29,n39,n31,n32]-[29(sp-4-1)-coppe
(SP-4-1)-(29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32)-Copper
[29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32]-(SP-4-1)-copper
31h-phthalocyaninato(2-)-n(29),n(30),n(31),n(32))-(29(sp-4-1)-coppe
Copper(II) phthalocyanine,CuPc, Phthalocyanine blue, Pigment Blue 15
copper,(29h,31h-phthalocyaninato(2-)-n(sup29),n(sup30),n(sup31),n(sup32)
Copper(II) phthalocyanine triple-subliMed grade, >99.95% trace Metals basis
Copper, [29H,31H-phthalocyaninato(2-)-N(29)-,N(30)-,N(31)-,N(32)-]-, (SP-4-1)-
Copper, 29H,31H-phthalocyaninato(2-)-.kappa.N29,.kappa.N30,.kappa.N31,.kappa.N32-, (SP-4-1)-
Copper, [29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32]-, (SP-4-1)- Copper, [phthalocyaninato(2-)]-
Copper,[29H,31H-phthalocyaninato(2(-))-N29,N30,N31,N32]-(SP-4-1)-
[EINECS(EC#)]

205-685-1
[Molecular Formula]

C32H16CuN8
[MDL Number]

MFCD00010719
[MOL File]

147-14-8.mol
[Molecular Weight]

576.07
Chemical PropertiesBack Directory
[Appearance]

dark blue fine crystalline powder
[Melting point ]

600°C (dec.)
[density ]

1.62[at 20℃]
[storage temp. ]

Inert atmosphere,Room Temperature
[solubility ]

insoluble in H2O, ethanol; soluble in concHSO 4
[Colour Index ]

74160
[form ]

Fine Crystalline Powder
[color ]

Dark blue
[Water Solubility ]

<0.1 g/100 mL at 20 ºC
[Hydrolytic Sensitivity]

4: no reaction with water under neutral conditions
[λmax]

602nm(CHCl3)(lit.)
[Merck ]

14,2520
[BRN ]

4121848
[Exposure limits]

ACGIH: TWA 1 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 1 mg/m3
[InChIKey]

XCJYREBRNVKWGJ-UHFFFAOYSA-N
[LogP]

-1 at 23℃
[NIST Chemistry Reference]

Copper phthalocyanine(147-14-8)
[EPA Substance Registry System]

Copper, [29H,31H-phthalocyaninato( 2-)-.kappa.N29,.kappa.N30,. kappa.N31,.kappa.N32]-, (SP-4-1)-(147-14-8)
[Absorption]

λmax 678 nm (DMF)
[Odor]

Blue-purple needles/powder
Hazard InformationBack Directory
[Description]

Copper(II) phthalocyanine, known as CuPc, has been used as an electron donor?with fullerene-C60 or phenyl-C61-butyric acid methyl ester (PCBM) in vacuum-deposited organic photovoltaics (OPV).?Power conversion efficiency of about 1% has been achieved [2] and improved efficiency of 4% with pentacene-doped CuPc layer . CuPc has also been used as a hole-injection material for light-emitting diodes. It has been reported that a thin CuPc layer may effectively enhance the hole injection from the anode to the emissive-polymer layer, resulting in a dramatic decrease of operating voltage of the device . Device stability was achieved by?depositing a copper phthalocyanine CuPc hole-injection layer?HIL on the ITO anode.
[Chemical Properties]

dark blue fine crystalline powder
[Uses]

Copper(II) phthalocyanine are involved in the study of photosensitizer chemistry for uniform polymerization, luminescence chemistry and spectrophotometric analysis, organic synthesis and polymerization. This pigment is used in enamels, linoleum, inks, plastics, and rubber goods. Photoisomerizable phthalocyanines are used in rewritable CD or DVD printing.Other applications in organic solar cells, biosensitizers and display devices such as OLED , OTFT, Wearable Display, and e-paper.
[Application]

Copper(II) phthalocyanine, known as CuPc, has been used as an electron donor with fullerene-C60 or phenyl-C61-butyric acid methyl ester (PCBM) in vacuum-deposited organic photovoltaics (OPV). Power conversion efficiency of about 1% has been achieved [2] and improved efficiency of 4% with pentacene-doped CuPc layer.
CuPc has also been used as a hole-injection material for light-emitting diodes. It has been reported that a thin CuPc layer may effectively enhance the hole injection from the anode to the emissive-polymer layer, resulting in a dramatic decrease of operating voltage of the device. Device stability was achieved by depositing a copper phthalocyanine CuPc hole-injection layer HIL on the ITO anode. The improved stability could be contributed to the good match of its highest-occupied molecular orbital (HOMO) level to the work function of ITO, and the improved wetting property of organic materials on ITO. Moreover, CuPc has very weak absorption of light, with wavelengths from 400 to 500 nm, making it suitable for use in blue and green OLEDs.
Effective electron-blocking was also observed for inorganic&ndash;organic hybrid perovskite solar cells when CuPc-doped spiro-OMeTAD was used as the hole-transporting layer.
[General Description]

Copper(II) phthalocynaine (CuPc) is a metal phthalocyanine dye that acts as a p-type semiconductor. It has a charge mobility of 10-4 cm2/Vs. It forms a chemically stable thin film that exhibits photoconductivity and catalytic activity.
[Flammability and Explosibility]

Notclassified
[Properties and Applications]

TEST ITEMS

SPECIFICATION

APPEARANCE

BLUE POWDER

SHADE

REDDISH

HEAT RESISTANCE

300 °C min

LIGHT FASTNESS

7-8

ACID RESISTANCE

5

ALKALI RESISTANCE

5

FASTNESS TO BLEEDING

5

OIL ABSORPTION

40-45%

SPECIFIC SURFACE

29 m 2 /g

DENSITY

1.60 g/cm 3

RESIDUE ON 80 MESH

5.0% max

WATER SOLUBLE

1.0% max

VOLATITE 105 °C

1.0% max

TINTING STRENGTH

100-105 %

[Purification Methods]

Precipitate it twice from conc H2SO4 by slow dilution with water. It has also been purified by two or three sublimations at 580o in an argon flow at 300-400Pa. [Beilstein 26 III/IV 4256.]
Safety DataBack Directory
[Safety Statements ]

22-24/25
[WGK Germany ]

-
[RTECS ]

GL8510000
[TSCA ]

Yes
[HS Code ]

32041300
[Hazardous Substances Data]

147-14-8(Hazardous Substances Data)
[Toxicity]

LD50 intraperitoneal in rat: > 3gm/kg
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Sodium hydroxide-->Hydrochloric acid-->Sulfuric acid-->Ammonium chloride-->Urea-->Chlorine-->FUMING SULFURIC ACID-->Xylene-->Calcium chloride-->Copper(I) chloride-->Phthalic anhydride-->Potassium iodide-->1,2,4-Trichlorobenzene-->Ammonium molybdate tetrahydrate-->Ammonium molybdate-->Copper(II) chloride dihydrate-->Copper(II) chloride dihydrate-->Zinc stearate
[Preparation Products]

Chromium(III) oxide-->Amino resin paint-->Pigment Geen 7-->Various color alkyd primer-->Various color amino baking enamel A04-9-->Alkyd enamel-->Various color nitrocellulose exterior enamel Q04-2-->POLYSULFONE-->Reactive Blue 14-->Direct Blue 86-->4923 Spirit Light Fast Ball-pen Blue GR-->Ferro phthalocyanine green-->Reactive Turquoise Blue Kn-G-->Reactive Blue 231-->Direct Blue 199-->Sulphur Green 14-->ACID BLUE 249-->REACTIVE BLUE 15
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

(29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32)copper(147-14-8).msds
Spectrum DetailBack Directory
[Spectrum Detail]

Copper(II) phthalocyanine(147-14-8)IR1
Copper(II) phthalocyanine(147-14-8)IR2
Copper(II) phthalocyanine(147-14-8)Raman
Copper(II) phthalocyanine(147-14-8)ESR
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