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2524-04-1

2524-04-1 Structure

2524-04-1 Structure
IdentificationMore
[Name]

Diethyl chlorothiophosphate
[CAS]

2524-04-1
[Synonyms]

0,0-Diethylthiophosphoryl chloride
DECTP
DEPCT
DIETHYL CHLOROTHIOPHOSPHATE
DIETHYL PHOSPHOROCHLORIDOTHIONATE
DIETHYL PHOSPHOROCHLOROTHIOATE
DIETHYLTHIOPHOSPHORIL CHLORIDE
DIETHYL THIOPHOSPHORYLCHLORIDE
ETHYL INTERMEDIARY EP-1
ETHYL PCT
O,O'-DIETHYL PHOSPHOROCHLORIDOTHIOATE
O,O-DIETHYL PHOSPHOROCHLORIDOTHIOATE
O,O′-Diethyl phosphorochlorido-thionate
O,O-DIETHYLPHOSPHOROCHLOROTHIOATE
O,O'-DIETHYL PHOSPHOROTHIOCHLORIDATE
O,O'-DIETHYLTHIOPHOSPHORYL CHLORIDE
U.N. 2751
Diethoxythiophosphoryl chloride
diethoxythiophosphorylchloride
Diethyl phosphorochloridothioate
[EINECS(EC#)]

219-755-4
[Molecular Formula]

C4H10ClO2PS
[MDL Number]

MFCD00009088
[Molecular Weight]

188.61
[MOL File]

2524-04-1.mol
Chemical PropertiesBack Directory
[Appearance]

CLEAR COLORLESS TO LIGHT YELLOW LIQUID
[Melting point ]

-75℃
[Boiling point ]

96 °C
[density ]

1.2 g/mL at 25 °C(lit.)
[vapor pressure ]

1.4 mm Hg ( 50 °C)
[refractive index ]

n20/D 1.472(lit.)
[Fp ]

>230 °F
[solubility ]

Chloroform (Slightly), Ethyl Acetate (Slightly)
[form ]

liquid
[color ]

Colorless to Red to Green
[Water Solubility ]

hydrolyzes, immiscible
[CAS DataBase Reference]

2524-04-1(CAS DataBase Reference)
[NIST Chemistry Reference]

Phosphorochloridothioic acid, o,o'-diethyl ester(2524-04-1)
[EPA Substance Registry System]

2524-04-1(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

T,T+
[Risk Statements ]

R23/24/25:Toxic by inhalation, in contact with skin and if swallowed .
R34:Causes burns.
R26:Very Toxic by inhalation.
R21/22:Harmful in contact with skin and if swallowed .
[Safety Statements ]

S23:Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer) .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
[RIDADR ]

UN 2751 8/PG 2
[WGK Germany ]

3
[RTECS ]

TD1780000
[HazardClass ]

8
[PackingGroup ]

II
[HS Code ]

29309099
[Hazardous Substances Data]

2524-04-1(Hazardous Substances Data)
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Ethanol-->Sodium hydroxide-->Sodium carbonate-->Chlorine-->Sodium sulfite-->Sodium ethoxide-->Sodium sulfide-->Phosphorus pentoxide-->CARBON MONOXIDE-->Phosphorus pentasulfide-->Hydrogen Sulfide-->THIOPHOSPHORYL CHLORIDE-->Disulfur dichloride
[Preparation Products]

Triazophos-->Quinalphos-->Phoxim-->Chlorpyrifos-->Profenofos-->Triazophos E.C.-->Diazinon-->Parathion-->O,O-dialkyl thiophosphoryl chloride-->QUINTIOPHOS-->O,O-diethyl-O-(2-chloro-4-bromophenyl)thiophosphate-->Coumaphos-->DIETHYL CHLOROPHOSPHITE
Hazard InformationBack Directory
[General Description]

A colorless to light amber liquid with a disagreeable odor. Density 1.196 g/cm3. Boiling point 120°F.Flash point below 100°F. Insoluble in water but soluble in most organic solvents. May be highly toxic and irritating to the eyes and lungs. Used as an intermediate for pesticides, as an oil and gasoline additive, and as a flame retardant.
[Reactivity Profile]

DIETHYLTHIOPHOSPHORYL CHLORIDE(2524-04-1) is incompatible with bases (including amines), with strong oxidizing agents, and with alcohols. May react vigorously or explosively if mixed with diisopropyl ether or other ethers in the presence of trace amounts of metal salts [J. Haz. Mat., 1981, 4, 291].
[Air & Water Reactions]

Highly flammable. Insoluble in water but soluble in most organic solvents. Contact with moisture in the air produces highly corrosive and toxic fumes containing hydrogen chloride. Decomposes in water producing acidic products.
[Health Hazard]

TOXIC; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns or death. Bromoacetates and chloroacetates are extremely irritating/lachrymators. Reaction with water or moist air will release toxic, corrosive or flammable gases. Reaction with water may generate much heat that will increase the concentration of fumes in the air. Fire will produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.
[Fire Hazard]

HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors form explosive mixtures with air: indoors, outdoors and sewers explosion hazards. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapors may travel to source of ignition and flash back. Substance will react with water (some violently) releasing flammable, toxic or corrosive gases and runoff. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated or if contaminated with water.
[Chemical Properties]

CLEAR COLORLESS TO LIGHT YELLOW LIQUID
[Uses]

Diethyl Chlorothiophosphate is used in the preparation of various organophosporus insecticide including Flupyrazofos (F598620) and Chlorpyrifos (C425300).
[Flammability and Explosibility]

Nonflammable
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

Diethyl chlorothiophosphate(2524-04-1).msds
Spectrum DetailBack Directory
[Spectrum Detail]

Diethyl chlorothiophosphate(2524-04-1)MS
Diethyl chlorothiophosphate(2524-04-1)1HNMR
Diethyl chlorothiophosphate(2524-04-1)13CNMR
Diethyl chlorothiophosphate(2524-04-1)IR1
Diethyl chlorothiophosphate(2524-04-1)Raman
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