ChemicalBook--->CAS DataBase List--->26412-87-3

26412-87-3

26412-87-3 Structure

26412-87-3 Structure
IdentificationMore
[Name]

Pyridine sulfur trioxide
[CAS]

26412-87-3
[Synonyms]

(DIMETHYLAMINOMETHYL)STYRENE
N-(4-VINYLBENZYL)-N,N-DIMETHYL AMINE
N,N-DIMETHYLVINYLBENZYLAMINE
POLY(4-VINYLPYRIDINE) SULFUR TRIOXIDE COMPLEX
PYRIDINE SULFUR TRIOXIDE
PYRIDINE SULFUR TRIOXIDE COMPLEX
PYRIDINE SULFUR TRIOXIDE COMPLEX POLYMER BOUND
PYRIDINE-SULPHURTRIOXIDECOMPLEX
SULFUR TRIOXIDE PYRIDINE COMPLEX
SULFUR TRIOXIDE PYRIDINE COMPLEX POLYMER BOUND
SULPHUR TRIOXIDE-PYRIDINE COMPLEX
VINYLBENZYLDIMETHYLAMINE
Pyridine,compd.withsulfurtrioxide(1:1)
Salfurtrioxidepyri-dinecomplex
Sulfurtrioxide,compd.withpyridine(1:1)
sulphur trioxide--pyridine (1:1)
Sulfur trioxide-pyridine complex, tech., 80%
Sulfurtrioxide-pyridinecomplex,98%
Sulfur trioxide pyridine complex, tech. (48.8-50.3% active SO3)
Pyridine, compd. with sulfur trioxide
[EINECS(EC#)]

247-683-3
[Molecular Formula]

C5H6NO3S
[MDL Number]

MFCD00078270
[Molecular Weight]

160.17
[MOL File]

26412-87-3.mol
Chemical PropertiesBack Directory
[Appearance]

white solid
[Melting point ]

~160 °C
[storage temp. ]

Store below +30°C.
[solubility ]

Soluble in polar organic solvents.
[form ]

Powder
[color ]

White to beige
[Water Solubility ]

reacts
[Sensitive ]

Moisture Sensitive
[BRN ]

3704116
[CAS DataBase Reference]

26412-87-3(CAS DataBase Reference)
[Storage Precautions]

Moisture sensitive
[EPA Substance Registry System]

26412-87-3(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

C
[Risk Statements ]

R22:Harmful if swallowed.
R34:Causes burns.
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
[RIDADR ]

UN 3261 8/PG 2
[WGK Germany ]

3
[F ]

3-10-21
[Autoignition Temperature]

>350 °C
[TSCA ]

Yes
[HazardClass ]

8
[PackingGroup ]

II
[HS Code ]

29420000
[Toxicity]

LD50 orally in Rabbit: 500 - 2000 mg/kg
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Ethyl acetate-->Sulfuric acid-->Pyridine-->Chlorosulfonic acid-->Chlorotrimethylsilane
[Preparation Products]

3-(pyridin-3-yl)propanal-->3-(3-CHLORO-PHENYL)-PROPIONALDEHYDE-->3-(4-CHLORO-PHENYL)-PROPIONALDEHYDE-->3-O-TOLYL-PROPIONALDEHYDE-->3-(4-NITRO-PHENYL)-PROPIONALDEHYDE-->ALPHA-KETOBUTYRIC ACID SODIUM SALT-->Sulfuric acid, anhydride with acetic acid-->4-METHYLUMBELLIFERYL SULFATE POTASSIUM SALT-->Dextran Sulfate Sodium Salt
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

Pyridine sulfur trioxide(26412-87-3).msds
Hazard InformationBack Directory
[Chemical Properties]

white solid
[Uses]

Pyridine-Sulfur Trioxide Complex is used in the sulfation of squid ink polysaccharides (SIPs) as a potential candidate compound for the prevention of tumor metastasis. Pyridine-Sulfur Trioxide Complex is also used in the preparation and anticoagulation test of sulfated silk fibroin.
[Uses]

Usually used for sulfations of alcohols, sulfonations, deoxygenations and other reductions, oxidations with DMSO.
[Purification Methods]

Wash the solid with a little CCl4, then H2O to remove traces of pyridine sulfate, and dry it over P2O5. [Baumgarten Chem Ber 59 1166 1926, Olah et al. Synthesis 59 1979, Beilstein 20/5 V 184].
Spectrum DetailBack Directory
[Spectrum Detail]

Pyridine sulfur trioxide(26412-87-3)MS
Pyridine sulfur trioxide(26412-87-3)13CNMR
Pyridine sulfur trioxide(26412-87-3)Raman
Pyridine sulfur trioxide(26412-87-3)FT-IR
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Sulfur trioxide pyridine complex, tech. (48.8-50.3% active SO3)(26412-87-3)
[Alfa Aesar]

Sulfur trioxide-pyridine complex, 98%, active SO3 ca 48-50%(26412-87-3)
[Sigma Aldrich]

26412-87-3(sigmaaldrich)
[TCI AMERICA]

Pyridine-Sulfur Trioxide Complex,>92.0%(T)(26412-87-3)
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