(S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL
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- CAS-Nr.
- 100165-88-6
- Englisch Name:
- (S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL
- Synonyma:
- (S)-T-BINAP;(S)-(−(R)-TOL-BINAP;(S)-TOL-BINAP;(S)-4-Me-BINAP;98% (S)-TolBINAP;(S)-(-)-2,2'-Bis(di-p-toL;BisdiptolylphosphinobinaphthylSTolBI;(S)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-&;5-Bromo-37-fluorobenzylamine&hydrochloride
- CBNumber:
- CB0334534
- Summenformel:
- C48H40P2
- Molgewicht:
- 678.78
- MOL-Datei:
- 100165-88-6.mol
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(S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL Eigenschaften
- Schmelzpunkt:
- 252-256 °C
- alpha
- -160° (c 0.5, C6H6)
- Siedepunkt:
- 754.4±60.0 °C(Predicted)
- storage temp.
- Inert atmosphere,Room Temperature
- Aggregatzustand
- Powder
- Farbe
- White
- Optische Aktivität
- [α]20/D -156°, c = 0.5 in benzene
- Wasserlöslichkeit
- Insoluble in water.
- InChIKey
- IOPQYDKQISFMJI-UHFFFAOYSA-N
- CAS Datenbank
- 100165-88-6(CAS DataBase Reference)
(S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL Chemische Eigenschaften,Einsatz,Produktion Methoden
R-Sätze Betriebsanweisung:
R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.
S-Sätze Betriebsanweisung:
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S36/37/39:Bei der Arbeit geeignete Schutzkleidung,Schutzhandschuhe und Schutzbrille/Gesichtsschutz tragen.
Chemische Eigenschaften
White powder
Verwenden
(S)-(-)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl is chiral ligand widely used in asymmetric synthesis. It also used as excellent catalysts for asymmetric hydrogenation of alkenes and some cyclic anhydrides. BINAP is used in organic synthesis for enantioselective transformations catalyzed by its complexes of ruthenium, rhodium, and palladium
(S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
(S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL Anbieter Lieferant Produzent Hersteller Vertrieb Händler.
Global( 155)Lieferanten
100165-88-6()Verwandte Suche:
- (S)-TOL-BINAP
- (R)-TOL-BINAP
- (S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL
- (R)-(+)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)1,1-BINAPHTHYL
- (S)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-&
- (S)-(-)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl, 98+%
- (S)-(-)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl,98%(S)-Tol-BINAP
- (S)-(-)-2,2''-BIS(DI-P-TOLYLPHOSPHINO)-1,1''-BINAPHTHYL (S)-TOL-BINAP
- (S)-(-)-2,2''-Bis-[bis-(p-tolylphosphino)]-1,1''-binaphthyl
- PHOSPHINE, 1,1''-(1S)-[1,1''-BINAPHTHALENE]-2,2''-DIYLBIS[1,1-BIS(4-METHYLPHENYL)-
- (S)-T-BINAP
- (S)-Tol-BINAP, (S)-(-)-2,2μ-p-tolyl-phosphino)-1,1μ-binaphthyl
- BisdiptolylphosphinobinaphthylSTolBI
- (S)-(-)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl, (S)-p-Tol-BINAP
- (S)-(-)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl, 99% (S)-p-Tol-BINAP
- (S)-2,2'-Bis[bis(4-methylphenyl)phosphino]-1,1'-binaphthyl
- (S)-4-Me-BINAP
- 1,1'-(1S)-[1,1'-Binaphthalene]-2,2'-diylbis[1,1-bis(4-methylphenyl)phosphine
- 98% (S)-TolBINAP
- (S)-(-)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl 97%
- (R)-2,2,-bis(di-p-tolylphosphino)-1,1,-binaphthalene
- 1,1'-(1S)-[1,1'-Binaphthalene]-2,2'-diylbis[bis(4-
methylphenyl)phosphine]
- (S)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthalene
- (S)-(-)-2,2'-Bis(di-p-toL
- Phosphine, (1S)-[1,1'-binaphthalene]-2,2'-diylbis[bis(4-methylphenyl)-
- High purity CAS 100165-88-6 (S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL in stock
- 5-Bromo-37-fluorobenzylamine&hydrochloride
- (S)-(−
- )-2,2′-Bis(di-p-tolylphosphino)-1,1′-binaphthyl
- (S)-(-)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl
- 100165-88-6
- BINAPs
- Asymmetric Synthesis
- Privileged Ligands
- Chiral Catalysts, Ligands, and Reagents
- BINAP Series
- Chiral Phosphine
