2-(TRIMETHYLSILYLOXY)FURAN
- CAS No.
- 61550-02-5
- Chemical Name:
- 2-(TRIMETHYLSILYLOXY)FURAN
- Synonyms
- TRIMETHYLSILYLOXYFURAN;2-(TRIMETHYLSILOXY)FURAN;2-Furyloxytrimethylsilane;2-(TRIMETHYLSILYLOXY)FURAN;(2-Furyloxy)trimethylsilane;2-(Trimethylsilyloxy)furane;2-(TriMethylsiloxy)furan 97%;Trimethyl(2-furanyloxy)silane;(2-FURANYLOXY)TRIMETHYLSILANE;2-Furyl(trimethylsilyl) ether
- CBNumber:
- CB0749048
- Molecular Formula:
- C7H12O2Si
- Molecular Weight:
- 156.25
- MDL Number:
- MFCD00011729
- MOL File:
- 61550-02-5.mol
- MSDS File:
- SDS
| Boiling point | 34-35 °C/9 mmHg (lit.) |
|---|---|
| Density | 0.929 g/mL at 25 °C (lit.) |
| refractive index |
n |
| Flash point | 76 °F |
| storage temp. | -20°C |
| solubility | sol most organic solvents, e.g. CH2Cl2, Et2O, benzene, THF, MeCN. |
| form | clear liquid |
| color | Colorless to Light orange to Yellow |
| Specific Gravity | 0.950 |
| Hydrolytic Sensitivity | 7: reacts slowly with moisture/water |
| BRN | 1423066 |
| CAS DataBase Reference | 61550-02-5(CAS DataBase Reference) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |   GHS02,GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H225-H315-H319-H335 | |||||||||
| Precautionary statements | P210-P302+P352-P305+P351+P338 | |||||||||
| Hazard Codes | F,Xi | |||||||||
| Risk Statements | 11-36/37/38 | |||||||||
| Safety Statements | 26 | |||||||||
| RIDADR | UN 1993 3/PG 2 | |||||||||
| WGK Germany | 3 | |||||||||
| F | 10-21 | |||||||||
| TSCA | No | |||||||||
| HS Code | 2932.19.5100 | |||||||||
| HazardClass | 3.2 | |||||||||
| PackingGroup | III | |||||||||
| NFPA 704 |
|
2-(TRIMETHYLSILYLOXY)FURAN price More Price(9)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 308064 | 2-(Trimethylsiloxy)furan 97% | 61550-02-5 | 5g | $176.4 | 2024-03-01 | Buy |
| Sigma-Aldrich | 308064 | 2-(Trimethylsiloxy)furan 97% | 61550-02-5 | 1g | $187 | 2024-03-01 | Buy |
| TCI Chemical | T1536 | 2-(Trimethylsilyloxy)furan >96.0%(GC) | 61550-02-5 | 5g | $280 | 2024-03-01 | Buy |
| TCI Chemical | T1536 | 2-(Trimethylsilyloxy)furan >96.0%(GC) | 61550-02-5 | 25g | $876 | 2024-03-01 | Buy |
| TRC | T896600 | 2-(Trimethylsilyloxy)furan | 61550-02-5 | 100mg | $60 | 2021-12-16 | Buy |
2-(TRIMETHYLSILYLOXY)FURAN Chemical Properties,Uses,Production
Physical properties
bp 44–46 °C/17 mmHg; d 0.93 gmL?1.
Uses
2-Trimethylsilyloxyfuran provides 5-substituted 2(5H)-furanones by alkylation, aldolization, 3 and conjugate addition; transforms quinones into furo-[3,2-b]benzofurans; useful for the four-carbon elongation of sugars. It is used in Synthetic Applications, Carbon–Heteroatom Bond Formation, Alkylation, Aldol-Type Reactions, Conjugate Addition, and Diels–Alder Reaction.
Uses
2-(Trimethylsilyloxy)furan is a useful reagent for the preparation of natural and synthetic furanones with anticancer activity.
Preparation
Accessible by silylation of 2(5H)-furanone, which is obtained at very low cost by oxidation of furfural.
Purification Methods
Fractionally distil it using a short path column. 1H NMR in CCl4 has : 4.90 (dd, J 1.3Hz, 3H), 6.00 (t, J 3Hz, 4H) and 6.60 (m, 5H). [Yoshii et al. Heterocycles 4 1663 1976.] 4-Trimethylsilyloxy-3-penten-2-one (cis) (acetylacetone enol trimethylsilyl ether) [13257-81-3] M 172.3, b 66-68o/4mm, 61-63o/5mm, d 4 0.917, n D 1.452. Fractionally distil it and store it in glass ampoules which are sealed under N2. It hydrolyses readily in contact with moisture giving, as likely impurities, hexamethyldisiloxane and 2,4-pentanedione. [West J Am Chem Soc 80 3246 1958, Beilstein 4 IV 4003.]
2-(TRIMETHYLSILYLOXY)FURAN Preparation Products And Raw materials
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 15932 | 58 |
| Chongqing Chemdad Co., Ltd | +86-023-61398051 +8613650506873 | sales@chemdad.com | China | 39916 | 58 |
| career henan chemical co | +86-0371-86658258 15093356674; | factory@coreychem.com | China | 29826 | 58 |
| Hefei TNJ Chemical Industry Co.,Ltd. | 0551-65418671 | sales@tnjchem.com | China | 34572 | 58 |
| Henan Alfa Chemical Co., Ltd | +8618339805032 | alfa4@alfachem.cn | China | 12755 | 58 |
| Hebei Guanlang Biotechnology Co., Ltd. | +86-19930503259 +86-19930503259 | cherry@crovellbio.com | China | 18455 | 58 |
| LEAPCHEM CO., LTD. | +86-852-30606658 | market18@leapchem.com | China | 43348 | 58 |
| Aladdin Scientific | +1-833-552-7181 | sales@aladdinsci.com | United States | 52927 | 58 |
| Amadis Chemical Company Limited | 571-89925085 | sales@amadischem.com | China | 131981 | 58 |
| Mainchem Co., Ltd. | +86-0592-6210733 | sale@mainchem.com | China | 32360 | 55 |
View Lastest Price from 2-(TRIMETHYLSILYLOXY)FURAN manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2021-08-12 | 2-(TRIMETHYLSILYLOXY)FURAN
61550-02-5
|
US $15.00-10.00 / KG | 1KG | 99%+ HPLC | Monthly supply of 1 ton | Zhuozhou Wenxi import and Export Co., Ltd | |
 |
2020-01-10 | 2-(TRIMETHYLSILYLOXY)FURAN
61550-02-5
|
US $1.00 / KG | 1KG | 98% HPLC | 10 tons/month | Career Henan Chemical Co |
-
- 2-(TRIMETHYLSILYLOXY)FURAN
61550-02-5
- US $15.00-10.00 / KG
- 99%+ HPLC
- Zhuozhou Wenxi import and Export Co., Ltd
-
- 2-(TRIMETHYLSILYLOXY)FURAN
61550-02-5
- US $1.00 / KG
- 98% HPLC
- Career Henan Chemical Co